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5-Bromo-2-methylphenol

5-Bromo-2-methylphenol structure

CAS No.: 36138-76-8

Chemical Name:: 5-Bromo-2-methylphenol

Synonyms: Phenol, 5-bromo-2-methyl-;5-Bromo-2-methylphenol 95%;4-Bromo-2-hydroxytoluene, 5-Bromo-o-cresol

CBNumber:: CB01216088

Molecular Formula:: C7H7BrO

Molecular Weight:: 187.03

MDL Number:: MFCD08061906

MOL File:: 36138-76-8.mol

MSDS File:: SDS

Last updated:2026-05-27 17:17:37

Product description	Number	Pack Size	Price
5-Bromo-2-methylphenol 95%	722480	10g	$242
5-Bromo-2-methylphenol 95%	722480	1g	$27
5-Bromo-2-methylphenol Asreported	266938	5g	$305
5-Bromo-2-methylphenol Asreported	266938	10g	$418
5-Bromo-2-methylphenol Asreported	266938	25g	$566
More product size

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5-Bromo-2-methylphenol Properties

Melting point	75-80 °C
Boiling point	144-146 °C(Press: 1.1 Torr)
Density	1.554±0.06 g/cm3(Predicted)
storage temp.	Inert atmosphere,Room Temperature
pka	9.35±0.10(Predicted)
form	crystals
color	Brown
InChI	1S/C7H7BrO/c1-5-2-3-6(8)4-7(5)9/h2-4,9H,1H3
InChIKey	OONJCAWRVJDVBB-UHFFFAOYSA-N
SMILES	Cc1ccc(Br)cc1O
CAS DataBase Reference	36138-76-8
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

target organs

Respiratory system

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36/37/39

WGK Germany

HazardClass

IRRITANT

HS Code

29081990

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	1
2		0

5-Bromo-2-methylphenol price More Price(57)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	722480	5-Bromo-2-methylphenol 95%	36138-76-8	10g	$242	2026-04-30	Buy
Sigma-Aldrich	722480	5-Bromo-2-methylphenol 95%	36138-76-8	1g	$27	2023-06-20	Buy
Usbiological	266938	5-Bromo-2-methylphenol Asreported	36138-76-8	5g	$305	2026-06-03	Buy
Usbiological	266938	5-Bromo-2-methylphenol Asreported	36138-76-8	10g	$418	2026-06-03	Buy
Usbiological	266938	5-Bromo-2-methylphenol Asreported	36138-76-8	25g	$566	2026-06-03	Buy

Product number	Packaging	Price	Buy
722480	10g	$242	Buy
722480	1g	$27	Buy
266938	5g	$305	Buy
266938	10g	$418	Buy
266938	25g	$566	Buy

5-Bromo-2-methylphenol Chemical Properties,Uses,Production

Chemical Properties

Light yellow solid

Synthesis

39478-78-9

36138-76-8

General procedure for the synthesis of 5-bromo-2-methylphenol from 2-amino-4-bromotoluene: A solution of concentrated sulfuric acid (6 mL) in distilled water (75 mL) was added to 5-bromo-2-methylaniline (1 g, 5.38 mmol). The resulting suspension was heated to 90 °C and stirred for 4.5 hours. Subsequently, the reaction mixture was cooled to 0 °C using an ice bath and a solution of sodium nitrite (384 mg, 5.57 mmol) in water (5 mL) was slowly added at this temperature. After addition, the reaction mixture was allowed to gradually warm up to room temperature. Next, the reaction mixture was poured into a solution of concentrated sulfuric acid (6 mL) in water (75 mL) preheated to 90°C. Stirring of the reaction mixture was continued at 90 °C for 1 hour, then the heating was stopped and it was allowed to cool naturally and stand overnight. A precipitate was observed to form from the reaction mixture. The precipitate was collected by filtration, washed with water and dried in a vacuum oven to give 5-bromo-2-methylphenol as a final brown solid (510 mg, 2.73 mmol, 51% yield). The mass spectrum (ESI) showed m/z of 185 and 187 [M-H]

References

[1] Patent: US2007/185156, 2007, A1. Location in patent: Page/Page column 8-9
[2] Patent: WO2007/63071, 2007, A1. Location in patent: Page/Page column 19
[3] Justus Liebigs Annalen der Chemie, 1913, vol. 398, p. 366
[4] Dissertation , S. 21,
[5] Journal of the Chemical Society, 1926, p. 2038

5-Bromo-2-methylphenol Preparation Products And Raw materials

Raw materials

3-BROMO-2-METHYLPHENOL o-Cresol 5-Bromo-2-methylaniline 5-Amino-o-cresol Sulfuric acid

Sodium nitrite

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Preparation Products

3-Methoxy-4-methylbenzoic acid

5-Bromo-2-methylphenol Suppliers

Global( 192)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-13017695106 +86-13676922317	jiuyitime@fdachem.com	China	16512	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13901	58
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3009	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29815	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	52513593@qq.com	CHINA	2972	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88298848	info@edengenechem.com	China	2165	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58

Supplier	Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Nanjing ChemLin Chemical Industry Co., Ltd.	60
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Accela ChemBio Inc.	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58

View Lastest Price from 5-Bromo-2-methylphenol manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-04-17	5-Bromo-2-methylphenol 36138-76-8	$1.10-9.90	1KG	99% min	100kg	ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2021-07-13	5-Bromo-2-methylphenol 36138-76-8	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10	5-Bromo-2-methylphenol 36138-76-8	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd

5-Bromo-2-methylphenol
36138-76-8
$1.10-9.90
99% min
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

5-Bromo-2-methylphenol
36138-76-8
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

5-Bromo-2-methylphenol
36138-76-8
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

5-Bromo-2-methylphenol Spectrum

5-Bromo-2-methylphenol(36138-76-8)¹HNMR

36138-76-8(5-Bromo-2-methylphenol)Related Search:

4-BROMO-2,5-DIMETHOXYTOLUENE 4-Bromo-2,5-dimethoxybenzaldehyde Disperse Blue 56 3,4,5,6-TETRABROMO-O-CRESOL 1-Amino-2-bromo-4-hydroxy-9,10-anthraquinone

Disperse Blue 81 4-BROMO-2,5-DIMETHOXYPHENETHYLAMINE HCL (+/-)-2,5-DIMETHOXY-4-BROMO-AMPHETAMINE HYDROBROMIDE 7-bromo-4-methyl-2H-chromen-2-one 5-BROMO-25,26,27,28-TETRAPROPOXYCALIX[4]ARENE

AKOS BBS-00001986 RARECHEM AL BO 2066 2,5-DIMETHOXY-4-BROMAMPHETAMIN N-(4-BROMO-2-METHOXYBENZYL)-5-FLUORO-2-METHYLANILINE AKOS BBS-00001989

2,4-DIBROMO-6-HYDROXYBENZONITRILE N-(4-BROMO-2-METHOXYBENZYL)-4-(TRIFLUOROMETHOXY)ANILINE (+/-)DOB, [PROPYL-1,2-3H]-

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5-Bromo-2-methylphenol 95% 4-Bromo-2-hydroxytoluene, 5-Bromo-o-cresol Phenol, 5-bromo-2-methyl- 36138-76-8 Aromatic Phenols Building Blocks C6 to C8 alcohol| alkyl bromide Oxygen Compounds Phenols Chemical Synthesis Organic Building Blocks

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