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ChemicalBook >> CAS DataBase List >>Difluoroamine

Difluoroamine

CAS No.
10405-27-3
Chemical Name:
Difluoroamine
Synonyms
Difluoroamine;Fluorimide (6CI,8CI,9CI)
CBNumber:
CB02279693
Molecular Formula:
F2HN
Lewis structure
hnf2 lewis structure
Molecular Weight:
53.01
MDL Number:
MOL File:
10405-27-3.mol
Last updated:2026-07-21 15:40:27

Difluoroamine Properties

Boiling point -23°C
Density 1.098±0.06 g/cm3(Predicted)
pka -12.58±0.70(Predicted)
form colorless gas
color colorless
Specific Heat Capacity Cp(gas): 0.82 J/(g·K), at 25℃

Difluoroamine Chemical Properties,Uses,Production

Uses

Difluoroamine is used as a reagent for introducing difluoroamine groups into organic molecules; synthesis of diazirines; deamination of primary amines.

Preparation

Difluoramine can be generated from tetrafluorohydrazine, which is made by reaction of NF3 with various metals at 375 °C.[1] Conversion into difluoramine is accomplished by heating tetrafluorohydrazine with Thiophenol in an evacuated bulb.[2] Difluoramine is also generated by heating N,N-difluorourea with conc. Sulfuric Acid.[3]

storage

Difluoroamine is shock sensitive. Reactions should be carried out in a fume hood.

References

1. Colburn, C. B.; Kennedy, A. JACS 1958, 80, 5004.
2. Freeman, J. P.; Kennedy, A.; Colburn, C. B. JACS 1960, 82, 5304.
3. Mueller, K. F.; Cziesla, M. J. JOC 1969, 34, 917.

Difluoroamine Preparation Products And Raw materials

Raw materials

Preparation Products

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Difluoroamine Fluorimide (6CI,8CI,9CI) 10405-27-3
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