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ChemicalBook >> CAS DataBase List >>1,4-Diiodobenzene

1,4-Diiodobenzene

CAS No.
624-38-4
Chemical Name:
1,4-Diiodobenzene
Synonyms
diiodobenzene;P-DIIODOBENZENE;4-DIIODOBENZENE;1,4-Diiobenzene;1,4-Diiodobenze;1,4-diiodbenzene;1,4-Diodobenzene;1,4-Diidobenzene;1,4-diiodo-benzen;1,4-DIIODOBENZENE
CBNumber:
CB0293970
Molecular Formula:
C6H4I2
Molecular Weight:
329.9
MDL Number:
MFCD00001054
MOL File:
624-38-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-15 22:31:22
Product description Number Pack Size Price
1,4-Diiodobenzene 99% 193526 10g $77.8
1,4-Diiodobenzene 99% 193526 50g $143
1,4-Diiodobenzene >98.0%(GC) D0608 5g $22
1,4-Diiodobenzene >98.0%(GC) D0608 25g $81
1,4-Diiodobenzene Asreported 273161 100g $347
More product size

1,4-Diiodobenzene Properties

Melting point 131-133 °C (lit.)
Boiling point 285 °C (lit.)
Density 2.350
refractive index 1.6212
Flash point 285°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystalline Powder
color White to beige
Water Solubility Soluble in ether and ethanol. Insoluble in water.
Sensitive Light Sensitive
BRN 1904546
Dielectric constant 2.8799999999999999
InChI 1S/C6H4I2/c7-5-1-2-6(8)4-3-5/h1-4H
InChIKey LFMWZTSOMGDDJU-UHFFFAOYSA-N
SMILES Ic1ccc(I)cc1
CAS DataBase Reference 624-38-4(CAS DataBase Reference)
FDA UNII I9XCF83VAV
NIST Chemistry Reference Benzene, 1,4-diiodo-(624-38-4)
EPA Substance Registry System Benzene, 1,4-diiodo- (624-38-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  3
8
TSCA  TSCA listed
HS Code  29036990
Storage Class 11 - Combustible Solids
NFPA 704
1
2 0

1,4-Diiodobenzene price More Price(105)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 193526 1,4-Diiodobenzene 99% 624-38-4 10g $77.8 2026-04-30 Buy
Sigma-Aldrich 193526 1,4-Diiodobenzene 99% 624-38-4 50g $143 2026-04-30 Buy
TCI Chemical D0608 1,4-Diiodobenzene >98.0%(GC) 624-38-4 5g $22 2026-04-30 Buy
TCI Chemical D0608 1,4-Diiodobenzene >98.0%(GC) 624-38-4 25g $81 2026-04-30 Buy
Usbiological 273161 1,4-Diiodobenzene Asreported 624-38-4 100g $347 2026-06-03 Buy
Product number Packaging Price Buy
193526 10g $77.8 Buy
193526 50g $143 Buy
D0608 5g $22 Buy
D0608 25g $81 Buy
273161 100g $347 Buy

1,4-Diiodobenzene Chemical Properties,Uses,Production

Chemical Properties

1,4-Diiodobenzene appears as white to light orange crystals or powder. Its melting point is 131–132 °C, and it boils at 285 °C (sublimes). The compound is readily soluble in ether and ethanol, but insoluble in water.

Uses

1,4-Diiodobenzene is used in Suzuki reaction. It is used as a precursor in the preparation of martinellic acid and 1,4-bis(p-R-phenylethynyl)benzenes. Further, it is employed in the preparation of 1,4-diiodo-2,5-didodecylbenzene , which is a starting reagent for the synthesis of oligo(1,4-phenylene ethynylene). It is also used in human and animal nutrition products including antiseptics and disinfectants. In addition to this, it used in polarizing films for liquid crystal display chemicals.

Preparation

1,4-Diiodobenzene is obtained by diazotising p-iodoaniline followed by substitution. An alternative preparation method involves diazotising p-phenylenediamine hydrochloride, followed by substitution with potassium iodide.

Purification Methods

Crystallise it from EtOH or boiling MeOH, then dry it in air. [Beilstein 5 IV 700.]

References

[1] JENS CARDINALE  Heinz H C  Johannes Ermert. Convenient preparation of (4-iodophenyl)aryliodonium salts[J]. Tetrahedron, 2012, 68 22: Pages 4112-4116. DOI:10.1016/j.tet.2012.03.113.
[2] ROEL S. SáNCHEZ-CARRERA. Charge-Transport Properties of the 1,4-Diiodobenzene Crystal: A Quantum-Mechanical Study[J]. Chemistry of Materials, 2008, 20 18: 5832-5838. DOI:10.1021/cm801108c.
[3] DU ZONG-DA   Yang C X  Cui Yuan Yuan. Synthesis of silica amino-functionalized microporous organic network composites for efficient on-line solid phase extraction of trace phenols from water.[J]. Journal of Chromatography A, 2020, 1616: 460791. DOI:10.1016/j.chroma.2019.460791.

589-87-7
624-38-4
Synthesis of 1,4-Diiodobenzene from 1-Bromo-4-iodobenzene
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View Lastest Price from 1,4-Diiodobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,4-Diiodobenze pictures 2026-08-04 1,4-Diiodobenze
624-38-4
$20.00 1KG 98% 20 tons Speranza Chemical Co., Ltd.
1,4-Diiodobenzene pictures 2026-08-04 1,4-Diiodobenzene
624-38-4
1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1,4-Diiodobenzene pictures 2026-07-09 1,4-Diiodobenzene
624-38-4
$1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
1,4-DIIODOBENZENE 4-DIIODOBENZENE P-DIIODOBENZENE 1,4-diiodbenzene 1,4-diiodo-benzen Benzene, 1,4-iodo- Benzene, p-diiodo- Benzene,1,4-diiode- Benzene,1,4-diiodo- p-Benzene diiodide 1,4-Phenylene diiodide p-Phenylene diiodide 1,4-Diiobenzene 1,4-Diodobenzene 1,4-Diiodobenzene98% Of two iodobenzene 1,4-Diiodobenzene, 98% 50GR 1,4-two iodobenzene 4,7-diiodobenzo[c][1,2,5]thiadiazole 1,4-Diidobenzene 1,4-Diiodobenze 1,4-Diiodobenzene > 1,4-diodiodobenzene 1,4-Diiodobenzene ISO 9001:2015 REACH 624-38-4 1,4-Diiodobenzene 13C6]-1,4-Diiodobenzene Diiodobenzene (1,4-Diiodobenzene) diiodobenzene 624-38-4 124-38-4 Halogenated Hydrocarbons Organic Building Blocks Aryl Building Blocks C6 Building Blocks Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks Iodine Compounds Aryl Halogenated Hydrocarbons bc0001 C6
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