1-(4-Bromophenyl)hexane
- CAS No.
- 23703-22-2
- Chemical Name:
- 1-(4-Bromophenyl)hexane
- Synonyms
- 1-BROMO-4-HEXYLBENZENE;EA180;1-Bromo-4-hexyL;4-BROMOHEXYLBENZENE;P-BROMOHEXYLBENZENE;4-HEXYLBROMOBENZENE;4-n-Hexylbromobenzene;-4-has1- broMobenzene;1-(4-BROMOPHENYL)HEXANE;1-BROMO-4-N-HEXYLBENZENE
- CBNumber:
- CB0378079
- Molecular Formula:
- C12H17Br
- Molecular Weight:
- 241.17
- MDL Number:
- MFCD00061114
- MOL File:
- 23703-22-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 1-Bromo-4-hexylbenzene >90.0%(GC) | B1606 | 5g | $140 |
| 1-Bromo-4-hexylbenzene >90.0%(GC) | B1606 | 25g | $309 |
| 1-Bromo-4-hexylbenzene 97% | AS24112 | 1g | $20 |
| 1-Bromo-4-(hex-1-yl)benzene >98% | OR21925 | 5g | $21 |
| 1-Bromo-4-hexylbenzene 97% | AS24112 | 5g | $43 |
| More product size | |||
| Boiling point | 280°C |
|---|---|
| Density | 1,18 g/cm3 |
| refractive index | 1.52-1.522 |
| Flash point | 280°C |
| storage temp. | Store at room temperature |
| form | clear liquid |
| Specific Gravity | 1.18 |
| color | Colorless to Light yellow |
| InChI | InChI=1S/C12H17Br/c1-2-3-4-5-6-11-7-9-12(13)10-8-11/h7-10H,2-6H2,1H3 |
| InChIKey | MXHOLIARBWJKCR-UHFFFAOYSA-N |
| SMILES | C1(Br)=CC=C(CCCCCC)C=C1 |
| CAS DataBase Reference | 23703-22-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P271-P280 | |||||||||
| Safety Statements | 24/25 | |||||||||
| HS Code | 29039990 | |||||||||
| NFPA 704 |
|
1-(4-Bromophenyl)hexane price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B1606 | 1-Bromo-4-hexylbenzene >90.0%(GC) | 23703-22-2 | 5g | $140 | 2026-04-30 | Buy |
| TCI Chemical | B1606 | 1-Bromo-4-hexylbenzene >90.0%(GC) | 23703-22-2 | 25g | $309 | 2026-04-30 | Buy |
| Activate Scientific | AS24112 | 1-Bromo-4-hexylbenzene 97% | 23703-22-2 | 1g | $20 | 2026-06-04 | Buy |
| Apolloscientific | OR21925 | 1-Bromo-4-(hex-1-yl)benzene >98% | 23703-22-2 | 5g | $21 | 2026-06-04 | Buy |
| Activate Scientific | AS24112 | 1-Bromo-4-hexylbenzene 97% | 23703-22-2 | 5g | $43 | 2026-06-04 | Buy |
1-(4-Bromophenyl)hexane Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
1-Bromo-4-hexylbenzene is a chemical reagent used in the preparation of conjugated nanoloops that display optoelectronic properties. Also used in the preparation of indacenodithiophene-benzothiadiazole copolymers.
Synthesis
1746-28-7
693-04-9
23703-22-2
General procedure for the synthesis of 1-bromo-4-(2-bromoethyl)benzene with n-butylmagnesium chloride as a raw material for the synthesis of 1-bromo-4-hexylbenzene: coupling reaction of alkyl halides with t-BuMgCl. Step 1 (P1): alkyl halides (1.0 mmol), decane (63 mg, as an internal standard) and LiI (5.3 mg, 0.04 mmol) were added to a reaction tube equipped with a rubber septum and a magnetic stirrer under a dry nitrogen atmosphere. THF (0.8 mL) was then added and the solution was cooled to -78 °C using a dry ice/EtOH bath. Slowly t-BuMgCl(2a) (1.5 mL, 0.81 M of THF solution, 1.2 mmol) was added, followed by isoprene (136.2 mg, 2.0 mmol). To this mixture was added CoCl2 [2.6 mg, 0.02 mmol, as a powder or as a THF solution (0.5 mL, 0.04 M)]. (Note 1: CoCl2 should be added immediately after isoprene addition or the catalytic efficiency will be significantly reduced.) Remove the cold bath, warm the mixture slowly to room temperature (about 10 min), and then heat the reaction vessel in a 50°C oil bath for 5 hr. (Note 2: If the reaction mixture is heated at 30 °C at this stage, unidentified side reactions can occur, resulting in lower yields of coupling products.) Upon completion of the reaction, the mixture is cooled to 0 °C in an ice bath and the reaction is quenched with 1 M aqueous HCl (5 mL). The product was extracted with Et2O (3 x 20 mL). The organic layers were combined, dried with Na2SO4, concentrated and analyzed by gas chromatography to determine the GC yield. The residue was purified by silica gel column chromatography or GPC. Under standard conditions, 1.0 mmol of 1-bromo-4-(2-bromoethyl)benzene was reacted with n-BuMgCl(2j) (1.0 M in THF, 1.2 mmol) in 94% yield (determined by GC using decane as an internal standard).
References
[1] Journal of the American Chemical Society, 2002, vol. 124, # 16, p. 4222 - 4223
[2] Journal of the American Chemical Society, 2013, vol. 135, # 26, p. 9604 - 9607
[3] Synthesis (Germany), 2014, vol. 46, # 12, p. 1583 - 1592
[4] Journal of Organic Chemistry, 2014, vol. 79, # 18, p. 8522 - 8532
1-(4-Bromophenyl)hexane Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 9542 | 58 |
| TCI Europe | 320-37350700 | sales@tcieurope.eu | Europe | 23671 | 75 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8738 | 58 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| NINGBO INNO PHARMCHEM CO., LTD. | 13867897135 | sales@nbinno.com | CHINA | 923 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10403 | 58 |
| Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd. | 0431-80514535 13634302652 | Extension@chemextension.com | CHINA | 967 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
View Lastest Price from 1-(4-Bromophenyl)hexane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-03-20 | 1-(4-Bromophenyl)hexane
23703-22-2
|
$10.00 | 1kg | 99% | 100 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2022-01-27 | 1-(4-Bromophenyl)hexane
23703-22-2
|
1KG | 97.8% | 100 tons | Honest Joy Holdings Limited
|
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 |
2021-08-12 | 1-(4-Bromophenyl)hexane
23703-22-2
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- 1-(4-Bromophenyl)hexane
23703-22-2
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 1-(4-Bromophenyl)hexane
23703-22-2
- $0.00
- 97.8%
- Honest Joy Holdings Limited
-
- 1-(4-Bromophenyl)hexane
23703-22-2
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
