2-(2-BROMOPHENYL)-1,3-DIOXOLANE
- CAS No.
- 34824-58-3
- Chemical Name:
- 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
- Synonyms
- ene acetaL;dehyde ethyL;2-BromobenzaL;RARECHEM AL BP 0014;2-Bromophenyldioxolane;2-bromo-2-phenyl-1,3-dioxolane;2-(2-bromophenyl)-1,3-dioxolan;2-(2-BROMOPHENYL)-1,3-DIOXOLANE;2-BROMOBENZALDEHYDE ETHYLENACETAL;1,3-Dioxolane, 2-(2-bromophenyl)-
- CBNumber:
- CB0429722
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD00155124
- MOL File:
- 34824-58-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Bromobenzaldehyde ethylene acetal 96% | 652652 | 5g | $63.7 |
| 2-Bromobenzaldehyde ethylene acetal 96% | 652652 | 25g | $246 |
| 2-(2-Bromophenyl)-1,3-dioxolane >97.0%(GC) | B2084 | 5g | $22 |
| 2-(2-Bromophenyl)-1,3-dioxolane >97.0%(GC) | B2084 | 25g | $67 |
| 2-(2-Bromophenyl)-1,3-dioxolane 98% | OR4329 | 25g | $32 |
| Boiling point | 126-127°C 5mm |
|---|---|
| Density | 1.535 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | Liquid |
| color | Clear colorless to pale yellow |
| Water Solubility | Difficult to mix in water. |
| BRN | 1284374 |
| InChI | 1S/C9H9BrO2/c10-8-4-2-1-3-7(8)9-11-5-6-12-9/h1-4,9H,5-6H2 |
| InChIKey | IWSGKSUCFVOWQU-UHFFFAOYSA-N |
| SMILES | Brc1ccccc1C2OCCO2 |
| CAS DataBase Reference | 34824-58-3(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H412 | |||||||||
| Precautionary statements | P264-P270-P273-P301+P312-P501 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22 | |||||||||
| Safety Statements | 24/25 | |||||||||
| WGK Germany | 2 | |||||||||
| HS Code | 29329900 | |||||||||
| Storage Class | 10 - Combustible liquids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Aquatic Chronic 3 |
|||||||||
| NFPA 704 |
|
2-(2-BROMOPHENYL)-1,3-DIOXOLANE price More Price(84)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 652652 | 2-Bromobenzaldehyde ethylene acetal 96% | 34824-58-3 | 5g | $63.7 | 2026-04-30 | Buy |
| Sigma-Aldrich | 652652 | 2-Bromobenzaldehyde ethylene acetal 96% | 34824-58-3 | 25g | $246 | 2026-04-30 | Buy |
| TCI Chemical | B2084 | 2-(2-Bromophenyl)-1,3-dioxolane >97.0%(GC) | 34824-58-3 | 5g | $22 | 2026-04-30 | Buy |
| TCI Chemical | B2084 | 2-(2-Bromophenyl)-1,3-dioxolane >97.0%(GC) | 34824-58-3 | 25g | $67 | 2026-04-30 | Buy |
| Apolloscientific | OR4329 | 2-(2-Bromophenyl)-1,3-dioxolane 98% | 34824-58-3 | 25g | $32 | 2026-06-04 | Buy |
2-(2-BROMOPHENYL)-1,3-DIOXOLANE Chemical Properties,Uses,Production
Chemical Properties
Clear colorless to pale yellow liquid
Uses
It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.
Synthesis
107-21-1
6630-33-7
34824-58-3
The general procedure for the synthesis of 2-bromobenzaldehyde vinyl aldehyde from ethylene glycol and o-bromobenzaldehyde was as follows: to a solution of benzene (40 mL) containing 2-bromobenzaldehyde (5.30 mmol) was added ethylene glycol (1.26 mL, 22.6 mmol, 4.3 eq.) and p-toluenesulfonic acid (70 mg, 0.37 mmol, 0.07 eq.) in sequence. The reaction mixture was placed in a Dean-Stark apparatus and heated to reflux. After 4 hours of reaction, the reaction was cooled to room temperature and quenched with triethylamine, followed by concentration of the reaction solution under reduced pressure. Finally, purification by silica gel column chromatography afforded the target product 2-bromobenzaldehyde vinyl aldehyde in quantitative yield.
References
[1] Patent: US2004/147401, 2004, A1. Location in patent: Page 33
[2] Organic and Biomolecular Chemistry, 2009, vol. 7, # 6, p. 1106 - 1114
[3] Organic Letters, 2013, vol. 15, # 18, p. 4718 - 4721
[4] European Journal of Organic Chemistry, 2014, vol. 2014, # 10, p. 2084 - 2091
[5] Organic Process Research and Development, 2016, vol. 20, # 2, p. 253 - 261
2-(2-BROMOPHENYL)-1,3-DIOXOLANE Preparation Products And Raw materials
Raw materials
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Preparation Products
2-(2-BROMOPHENYL)-1,3-DIOXOLANE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 3957 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14026 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49979 | 58 | |
| career henan chemical co | +86-0371-86658258 | factory@coreychem.com | China | 29792 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 | contact@fuxinpharm.com | China | 9976 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 | marketing1@neostarunited.com | China | 8828 | 58 |
| Longyan Tianhua Biological Technology Co., Ltd | 0086 18039857276 18039857276 | CHINA | 2783 | 58 | |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +86-189 4982 3763 | sales@tnjchem.com | China | 34563 | 58 |
View Lastest Price from 2-(2-BROMOPHENYL)-1,3-DIOXOLANE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2024-07-31 | 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
34824-58-3
|
$1.00 | 1KG | 99% | 20T | Shaanxi Dideu Medichem Co. Ltd | |
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2021-08-12 | 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
34824-58-3
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
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2020-11-16 | 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
34824-58-3
|
$430.00 | 1KG | 99 | 10000KG | Longyan Tianhua Biological Technology Co., Ltd |
-

- 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
34824-58-3
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-

- 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
34824-58-3
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- 2-(2-BROMOPHENYL)-1,3-DIOXOLANE
34824-58-3
- $430.00
- 99
- Longyan Tianhua Biological Technology Co., Ltd
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