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ChemicalBook >> CAS DataBase List >>6-Acetyl-1,4-benzodioxane

6-Acetyl-1,4-benzodioxane

CAS No.
2879-20-1
Chemical Name:
6-Acetyl-1,4-benzodioxane
Synonyms
(E)-5-(4-hydroxystyryl)benzene-1,3-diol;AURORA 18707;ASISCHEM D29259;AKOS BBS-00006494;6-Acetylbenzodioxane;6-Acetyl-1,4-benzodixane;6-ACETYL-1,4-BENZODIOXANE;6-Acetyl-1,4-benzodioxane >6-Acetyl-1,4-benzodioxane-98%;3',4'-ETHYLENEDIOXYACETOPHENONE
CBNumber:
CB2315948
Molecular Formula:
C10H10O3
Molecular Weight:
178.18
MDL Number:
MFCD00006823
MOL File:
2879-20-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 00:12:59
Product description Number Pack Size Price
1,4-Benzodioxan-6-yl methyl ketone 98% 179027 10g $128
6-Acetyl-1,4-benzodioxane >98.0%(GC) A1629 5g $36
1,4-Benzodioxan-6-yl methyl ketone Asreported 266240 10g $380
1,4-Benzodioxan-6-yl methyl ketone Asreported 266240 25g $623
1,4-Benzodioxan-6-yl methyl ketone Asreported 266240 50g $878
More product size

6-Acetyl-1,4-benzodioxane Properties

Melting point 80-82 °C (lit.)
Boiling point 270.41°C (rough estimate)
Density 1.1601 (rough estimate)
refractive index 1.5370 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Fine Crystalline Needles
color Almost white to slightly blue
BRN 164125
InChI 1S/C10H10O3/c1-7(11)8-2-3-9-10(6-8)13-5-4-12-9/h2-3,6H,4-5H2,1H3
InChIKey HGVWMTAIIYNQSI-UHFFFAOYSA-N
SMILES CC(=O)c1ccc2OCCOc2c1
CAS DataBase Reference 2879-20-1(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS02,GHS05,GHS06
Signal word  Warning
Hazard statements  H260-H303-H313-H314-H317-H331
Precautionary statements  P264b-P271-P280-P301+P330+P331-P302+P335+P334-P304+P340-P305+P351+P338-P310-P363-P370+P378r-P402+P404-P501c
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi
Safety Statements  24/25-25-24
WGK Germany  3
HazardClass  IRRITANT
HS Code  29145090
Storage Class 11 - Combustible Solids
NFPA 704
1
0 0

6-Acetyl-1,4-benzodioxane price More Price(88)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 179027 1,4-Benzodioxan-6-yl methyl ketone 98% 2879-20-1 10g $128 2026-04-30 Buy
TCI Chemical A1629 6-Acetyl-1,4-benzodioxane >98.0%(GC) 2879-20-1 5g $36 2026-04-30 Buy
Usbiological 266240 1,4-Benzodioxan-6-yl methyl ketone Asreported 2879-20-1 10g $380 2026-06-03 Buy
Usbiological 266240 1,4-Benzodioxan-6-yl methyl ketone Asreported 2879-20-1 25g $623 2026-06-03 Buy
Usbiological 266240 1,4-Benzodioxan-6-yl methyl ketone Asreported 2879-20-1 50g $878 2026-06-03 Buy
Product number Packaging Price Buy
179027 10g $128 Buy
A1629 5g $36 Buy
266240 10g $380 Buy
266240 25g $623 Buy
266240 50g $878 Buy

6-Acetyl-1,4-benzodioxane Chemical Properties,Uses,Production

Chemical Properties

ALMOST WHITE TO SLIGHTLY BLUE FINE CRYST. NEEDLES

Uses

1,4-Benzodioxan-6-yl methyl ketone may be used in the preparation of acetylenic alcohols.

Definition

ChEBI: 1-(2,3-Dihydro-1,4-benzodioxin-6-yl)ethan-1-one is a benzodioxine.

Synthesis

1,4-Benzodioxin-6-methanol, 2,3-dihydro-α-methyl-

7338-03-6

6-Acetyl-1,4-benzodioxane

2879-20-1

GENERAL METHODS: Method B: To a stirred solution of 1-(2,3-dihydrobenzo[B][1,4]dioxin-6-yl)ethan-1-ol (4a, 1.65 g, 9.94 mmol) in anhydrous dichloromethane (100 mL) was added Dess-Martin's reagent (5.06 g, 11.93 mmol) at 0 °C and under argon protection. After 10 minutes of reaction, the mixture was slowly warmed to room temperature and stirring was continued for 16 hours. After completion of the reaction, the reaction was quenched with saturated sodium bicarbonate solution and filtered to remove the insoluble salt. The filtrate was extracted with dichloromethane, the combined organic layers were dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. Finally, the target product 6-acetyl-1,4-benzodioxane (5a, 1.42 g, 87% yield) was purified by silica gel column chromatography with dichloromethane as eluent to give a light yellow solid.

References

[1] European Journal of Medicinal Chemistry, 2015, vol. 105, p. 80 - 105

6-Acetyl-1,4-benzodioxane Preparation Products And Raw materials

Global( 199)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
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View Lastest Price from 6-Acetyl-1,4-benzodioxane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-(2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)ethanone pictures 2026-04-17 1-(2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)ethanone
2879-20-1
$1.60-6.60 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
1,4-Benzodioxan-6-yl Methyl ketone pictures 2021-07-02 1,4-Benzodioxan-6-yl Methyl ketone
2879-20-1
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
6-Acetyl-1,4-benzodioxane pictures 2019-07-06 6-Acetyl-1,4-benzodioxane
2879-20-1
$1.00 1KG 98% 150KG Career Henan Chemical Co
AURORA 18707 ASISCHEM D29259 6-ACETYL-1,4-BENZODIOXANE AKOS BBS-00006494 3',4'-ETHYLENEDIOXYACETOPHENONE 1-(2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL)ETHAN-1-ONE 1-(2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL)ETHANONE 1-(2,3-DIHYDROBENZO[B][1,4]DIOXIN-7-YL)ETHANONE 1,4-BENZODIOXAN-6-YL METHYL KETONE 1,4-Benzodioxan-6-yl methyl ketone~3,4-Ethylenedioxyacetophenone 1-(2,3-Dihydro-benzo[1,4]dioxin-6-yl)-ethanone Ethanone, 1-(2,3-dihydro-1,4-benzodioxin-6-yl)- 6-Acetyl-2,3-dihydro-1,4-benzodioxin 1,4-Benzodioxan-6-yl methyl ketone,98% 1-(2,3-dihydro-1,4-benzodioxin-7-yl)ethanone 6-Acetyl-1,4-benzodixane 1-(2,3-dihydro-1,4-benzodioxin-6-yl)ethan-1-one 98% JRH-03502, 1-(2,3-Dihydrobenzo[b][1,4]dioxin-7-yl)ethanone, 97% 6-Acetyl-1,4-benzodioxane > 6-Acetylbenzodioxane 6-Acetyl-1,4-benzodioxane-98% 6-Acetyl-1,4-benzodioxane, ≥ 98.0% (E)-5-(4-hydroxystyryl)benzene-1,3-diol 2879-20-1 Benzodioxanes Building Blocks Heterocyclic Building Blocks BenzodioxanesCarbonyl Compounds Building Blocks C10 Heterocyclic Building Blocks Ketones
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