[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
- CAS No.
- 15629-92-2
- Chemical Name:
- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
- Synonyms
- NiCl2(dppp);Ni(dppp)Cl2;(1,3-dppp)NiCl2;NiCl2(DPPP)NiCl2(DPPP);[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II);1.3-Bis(dipheny phosphine) propane nickel(II)chloride;Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II);1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE;1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride;1,3-B
- CBNumber:
- CB3416370
- Molecular Formula:
- C27H26Cl2NiP2
- Molecular Weight:
- 542.04
- MDL Number:
- MFCD00015318
- MOL File:
- 15629-92-2.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) | 335363 | 5g | $90.1 |
| [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) | 335363 | 25g | $167 |
| [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride >98.0%(T) | B1313 | 5g | $35 |
| [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride >98.0%(T) | B1313 | 25g | $118 |
| 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99% 99% | 28-0080 | 5g | $76 |
| More product size | |||
| Melting point | 213 °C (dec.)(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | crystal |
| color | red |
| Water Solubility | insoluble |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| InChI | InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2 |
| InChIKey | ZBQUMMFUJLOTQC-UHFFFAOYSA-L |
| SMILES | P(C1=CC=CC=C1)(CCCP(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl |
| CAS DataBase Reference | 15629-92-2(CAS DataBase Reference) |
| REACH Annex XVII Substances List | Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]- (15629-92-2) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H317-H319-H334-H335-H350 | |||||||||
| Precautionary statements | P201-P280-P302+P352-P305+P351+P338-P308+P313 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T,Xn | |||||||||
| Risk Statements | 49-36/37/38-42/43-40 | |||||||||
| Safety Statements | 53-26-36/37/39-45-24-22 | |||||||||
| RIDADR | 3282 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Carc. 1A Eye Irrit. 2 Resp. Sens. 1 Skin Irrit. 2 Skin Sens. 1 STOT SE 3 |
|||||||||
| NFPA 704 |
|
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride price More Price(114)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 335363 | [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) | 15629-92-2 | 5g | $90.1 | 2026-04-30 | Buy |
| Sigma-Aldrich | 335363 | [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) | 15629-92-2 | 25g | $167 | 2026-04-30 | Buy |
| TCI Chemical | B1313 | [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride >98.0%(T) | 15629-92-2 | 5g | $35 | 2026-04-30 | Buy |
| TCI Chemical | B1313 | [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride >98.0%(T) | 15629-92-2 | 25g | $118 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0080 | 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99% 99% | 15629-92-2 | 5g | $76 | 2026-04-30 | Buy |
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Chemical Properties,Uses,Production
Reaction
- Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents.
- Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes.
- Nickel catalyst used in the borylation of halides and pseudohalides.
Chemical Properties
red to red-brown powder or crystals
Uses
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
Application
Catalyst for:
Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Puyang Huicheng Electronic Materials Co., Ltd. | +86-0393-+86-0393-8910800 +8615839383373 | info@huichengchem.com | China | 530 | 58 |
| Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13901 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21587 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| AB PharmaTech,LLC | 323-480-4688 | sales@acrospharmatech.com | United States | 989 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2950 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 | sunny.w@boronicgroup.com | CHINA | 171 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
Related articles
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- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is a catalyst mainly applied in C-C, C-N, and C-O coupling reactions in....
- Apr 17,2025
Related Qustion
Ask a questionView Lastest Price from [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2022-11-11 | [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
|
$28.00-30.00 | 1Kg | 99.0% up | 50 tons per month | Xinxiang Hongqi District Houyuan Trading Co.,Ltd | |
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2022-09-24 | [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
|
1kg | 99% | 1000kg | henan kanbei chemical co.,ltd | ||
![]() |
2021-07-13 | [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
![[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride pictures](/ProductImageEN/2022-11/Small/27571b25-bf21-4217-ac35-f343cacf2a10.jpg)
- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
- $28.00-30.00
- 99.0% up
- Xinxiang Hongqi District Houyuan Trading Co.,Ltd
-
![[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride pictures](/ProductImageEN/2022-09/Small/4bff8dab-797b-48c2-8cc1-b699855f374d.png)
- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
- $0.00
- 99%
- henan kanbei chemical co.,ltd
-
![[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride pictures](/ProductImageEN/2021-07/Small/9bb77757-ae09-4bb4-9440-2fa5c4cbc55e.jpg)
- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd






