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ChemicalBook >> CAS DataBase List >>1,4-Bis(aminomethyl)benzene

1,4-Bis(aminomethyl)benzene

CAS No.
539-48-0
Chemical Name:
1,4-Bis(aminomethyl)benzene
Synonyms
1,4-Phenylenedimethanamine;P-XYLYLENEDIAMINE;PXDA;Xylenediamine;P-XYLENE DIAMINE;1,4-xylylenediamine;1,4-Benzenedimethanamine;p-Xylylendiamine;p-Xylilenediamine;RARECHEM AL BW 0024
CBNumber:
CB3424450
Molecular Formula:
C8H12N2
Molecular Weight:
136.19
MDL Number:
MFCD00009821
MOL File:
539-48-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-05 18:44:30
Product description Number Pack Size Price
1,4-Bis(aminomethyl)-benzene for synthesis 8.41656 10g $90.3
p-Xylylenediamine 99% 279633 5g $135
p-Xylylenediamine 99% 279633 25g $477
p-Xylylenediamine >99.0%(GC)(T) D1018 25g $87
p-Xylylenediamine >99.0%(GC)(T) D1018 100g $225
More product size

1,4-Bis(aminomethyl)benzene Properties

Melting point 60-63 °C(lit.)
Boiling point 230 °C10 mm Hg(lit.)
Density 0.9458 (rough estimate)
vapor pressure 0.26Pa at 25℃
refractive index 1.6210 (estimate)
Flash point 134°C
storage temp. Store below +30°C.
pka 9.46±0.10(Predicted)
form powder to lump
color White to Light yellow
Water Solubility Soluble in water.
Sensitive Air Sensitive
BRN 2206190
InChI 1S/C8H12N2/c9-5-7-1-2-8(6-10)4-3-7/h1-4H,5-6,9-10H2
InChIKey ISKQADXMHQSTHK-UHFFFAOYSA-N
SMILES NCc1ccc(CN)cc1
LogP -0.25 at 25℃
CAS DataBase Reference 539-48-0(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances XYLYLENEDIAMINE, P-
FDA 21 CFR 175.300(Resinous and polymeric coatings)
EWG's Food Scores 1
FDA UNII FJD90IO4NH
NIST Chemistry Reference p-Xylylenediamine(539-48-0)
EPA Substance Registry System 1,4-Benzenedimethanamine (539-48-0)
UNSPSC Code 12352116
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3259 8/PG 2
WGK Germany  3
RTECS  PF9000000
2-10
TSCA  TSCA listed
HS Code  2921 59 90
HazardClass  8
PackingGroup  II
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
REACH Registrations Active
Limited Quantities 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
0
3 0

1,4-Bis(aminomethyl)benzene price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.41656 1,4-Bis(aminomethyl)-benzene for synthesis 539-48-0 10g $90.3 2026-04-30 Buy
Sigma-Aldrich 279633 p-Xylylenediamine 99% 539-48-0 5g $135 2026-04-30 Buy
Sigma-Aldrich 279633 p-Xylylenediamine 99% 539-48-0 25g $477 2026-04-30 Buy
TCI Chemical D1018 p-Xylylenediamine >99.0%(GC)(T) 539-48-0 25g $87 2026-04-30 Buy
TCI Chemical D1018 p-Xylylenediamine >99.0%(GC)(T) 539-48-0 100g $225 2026-04-30 Buy
Product number Packaging Price Buy
8.41656 10g $90.3 Buy
279633 5g $135 Buy
279633 25g $477 Buy
D1018 25g $87 Buy
D1018 100g $225 Buy

1,4-Bis(aminomethyl)benzene Chemical Properties,Uses,Production

Uses

p-Xylylenediamine is

Flammability and Explosibility

Not classified

Synthesis

1,4-Dicyanobenzene

623-26-7

4-Cyanobenzylamine

10406-25-4

1,4-Bis(aminomethyl)benzene

539-48-0

Example 5: Hydrogenation of terephthalonitrile 1. 3.2 g of terephthalonitrile, 10.4 g of homotrimethylbenzene, 10.0 g of liquid ammonia, and 2.0 g of Pd-alumina pellets (manufactured by NE Chemcat Corporation; Pd content = 5% by weight) were added to a 100 ml autoclave. 2. the internal pressure was increased to 4.9 MPa using hydrogen. 3. The autoclave was shaken at 50 °C until the pressure no longer changed. 4. Upon completion of the reaction, the reaction product solution was analyzed and showed 94.8% conversion of terephthalonitrile, 88.8% yield of 4-cyanobenzylamine and 5.8% yield of p-phenylenediamine. 5. The isolated reaction solution was added to another 100 ml autoclave along with 10.0 g of liquid ammonia and 2.0 g of Catalyst A. The reaction solution was then added to another 100 ml autoclave. 6. The internal pressure was raised to 4.9 MPa using hydrogen again. 7. The autoclave was shaken at 50°C until the pressure no longer changed. 8. Upon completion of the reaction, the reaction product solution was analyzed and showed a conversion of 100 mol% for terephthalonitrile, a yield of 0.2 mol% for 4-cyanobenzylamine, and a yield of 92.1 mol% for p-xylene diamine.

References

[1] Patent: EP1449825, 2004, A1. Location in patent: Page 5

Global( 189)Suppliers
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Hebei Chuanghai Biotechnology Co., Ltd
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View Lastest Price from 1,4-Bis(aminomethyl)benzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
p-Xylylenediamine pictures 2026-06-11 p-Xylylenediamine
539-48-0
$62.00-233.00 25g 0.97 25kg Shanghai UCHEM Inc.
1,4-Bis(aminomethyl)benzene pictures 2026-03-20 1,4-Bis(aminomethyl)benzene
539-48-0
1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
 p-Xylylenediamine  1,4-Bis(aminomethyl)benzene    in stock Factory pictures 2020-06-02 p-Xylylenediamine 1,4-Bis(aminomethyl)benzene in stock Factory
539-48-0
$1.00 1KG TOP 3 Factory in China Chemwill Asia Co.,Ltd.
1,4-BIS(AMINOMETHYL)-BENZENE 1,4-BIS(AMINOMETHYL)XYLENE P-XYLYLENE-ALPHA,ALPHA'-DIAMINE RARECHEM AL BW 0024 1,4-Bis-aminomethylbenzen 4-(Aminomethyl)benzylamine 4-aminomethylbenzylamine Methylamine, p-phenylenebis- p-Phenylenebis(methylamine) p-phenylenebis-methylamin p-xylene-alpha,alpha’-diamine p-Xylylendiamine 1,4-Bis(aminomethyl)benzene~p-Phenylenebismethylamine 1,4-di(aminomethyl)benzene p-xylen-alpha,alpha-ylenediamine P-Xylenediamine (PXDA) 1,2-bis-(Aminomethyl)benzene p-Xylilenediamine P-XYLYLENEDIAMINE 96+% PARA-XYLYLENEDIAMINE 1,4-BIS(AMINOMETHYL)-BENZENE FOR SYNTHESIS 98+% 1,4-Bis(aminomethyl)benzene, α,αμ-Diamino-p-xylene α,α'-Diamino-p-xylene p-Xylylenediamine,99% alpha,alpha'-Diamino-p-xylene p-Xylene Diamine 4-(Aminomethyl)benzylamine p-XylylenediaMine 99% 1,4-Bis(aminomethyl)-benzene for synthesis p-Xylylenediamine 1,4-Bis(aminomethyl)benzene in stock Factory p-Xylylenediamine > 1,4-BIS(AMINOMETHYL)-BENZENE FOR SYNTHES 1-[4-(aminomethyl)phenyl]methanamine 1,4-xylylenediamine Xylenediamine alpha,alpha'-diamino-P-xylene p-Xylylenediamine 1,4-Phenylenedimethanamine , p-Xylylenediamine 1,4-Benzenedimethanamine 1,4-Phenylenedimethanamine P-XYLENE DIAMINE P-XYLYLENEDIAMINE PXDA 539-48-0 Nitrogen Compounds Organic Building Blocks Polyamines Building Blocks
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