ChemicalBook >> CAS DataBase List >>3-FLUORO-4-NITROBENZYL BROMIDE
3-FLUORO-4-NITROBENZYL BROMIDE
- CAS No.
- 131858-37-2
- Chemical Name:
- 3-FLUORO-4-NITROBENZYL BROMIDE
- Synonyms
- 4-(BroMoMethyl)-2-fluoro-1-nitrobenzene;3-FLUORO-4-NITROBENZYL BROMIDE;4-(Bromomethyl)-2-fluoronitrobenzene;Benzene, 4-(bromomethyl)-2-fluoro-1-nitro-;4-(Bromomethyl)-2-fluoronitrobenzene, alpha-Bromo-3-fluoro-4-nitrotoluene
- CBNumber:
- CB4395597
- Molecular Formula:
- C7H5BrFNO2
- Molecular Weight:
- 234.02
- MDL Number:
- MFCD03094237
- MOL File:
- 131858-37-2.mol
- MSDS File:
- SDS
Last updated:2026-06-04 16:00:12
| Product description | Number | Pack Size | Price |
| 3-Fluoro-4-nitrobenzyl bromide Aldrich | VBP00031 | 1g | $114 |
| 3-Fluoro-4-nitrobenzyl bromide 97% | PC4404 | 1g | $24 |
| 3-Fluoro-4-nitrobenzyl bromide 97% | PC4404 | 5g | $90 |
| 3-Fluoro-4-nitrobenzyl bromide 97% | PC4404 | 1g | $24 |
| 3-Fluoro-4-nitrobenzyl bromide 97% | PC4404 | 5g | $90 |
| More product size | |||
| Melting point | 46-48°C |
|---|---|
| Boiling point | 311.6±27.0 °C(Predicted) |
| Density | 1.733±0.06 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | crystalline powder |
| color | Yellow |
| Sensitive | Lachrymatory |
| InChI | InChI=1S/C7H5BrFNO2/c8-4-5-1-2-7(10(11)12)6(9)3-5/h1-3H,4H2 |
| InChIKey | ZOZJSWIXPIVMRU-UHFFFAOYSA-N |
| SMILES | C1([N+]([O-])=O)=CC=C(CBr)C=C1F |
| CAS DataBase Reference | 131858-37-2(CAS DataBase Reference) |
| UNSPSC Code | 12352200 |
| NACRES | NA.21 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P280-P301+P312+P330-P304+P340+P312-P305+P351+P338-P337+P313 | |||||||||
| target organs | Respiratory system | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34-36/37/38 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| RIDADR | 1759 | |||||||||
| WGK Germany | WGK 3 | |||||||||
| Hazard Note | Corrosive/Lachrymatory | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2904990090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| Limited Quantities | 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
3-FLUORO-4-NITROBENZYL BROMIDE price More Price(34)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | VBP00031 | 3-Fluoro-4-nitrobenzyl bromide Aldrich | 131858-37-2 | 1g | $114 | 2026-04-30 | Buy |
| Apolloscientific | PC4404 | 3-Fluoro-4-nitrobenzyl bromide 97% | 131858-37-2 | 1g | $24 | 2026-06-04 | Buy |
| Apolloscientific | PC4404 | 3-Fluoro-4-nitrobenzyl bromide 97% | 131858-37-2 | 5g | $90 | 2026-06-04 | Buy |
| Apolloscientific | PC4404 | 3-Fluoro-4-nitrobenzyl bromide 97% | 131858-37-2 | 1g | $24 | 2026-06-04 | Buy |
| Apolloscientific | PC4404 | 3-Fluoro-4-nitrobenzyl bromide 97% | 131858-37-2 | 5g | $90 | 2026-06-04 | Buy |
3-FLUORO-4-NITROBENZYL BROMIDE Chemical Properties,Uses,Production
Chemical Reactivity
The reaction of 3-fluoro-4-nitrobenzyl bromide with lithium azaenolate of (S)-4-isopropyl-2,5-dimethoxy-2,5-dihydropyrazine gave only a poor yield (<10%) of alkylated product, presumably due to the high acidity of benzylic protons and more importantly, the presence of multi-electrophilic centers in 3-fluoro-4-nitrobenzyl bromide. 1
References
[1]BERGGREN, D. TOWARDS THE SYNTHESIS OF DIKETOPIPERAZINE-CONTAINING MACROCYCLES VERGOU MARIA, CHEMIST SUPERVISORS: ASST. PROF. A. ZOGRAFOS.
3-FLUORO-4-NITROBENZYL BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 117)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai 3S Technology Co., Ltd | +86-18221206281 +86-18221206281 | luqing@3s-tech.net | China | 59 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
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| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
131858-37-2(3-FLUORO-4-NITROBENZYL BROMIDE)Related Search:
4-(Bromomethyl)-2-fluoronitrobenzene
4-(Bromomethyl)-2-fluoronitrobenzene, alpha-Bromo-3-fluoro-4-nitrotoluene
3-FLUORO-4-NITROBENZYL BROMIDE
Benzene, 4-(bromomethyl)-2-fluoro-1-nitro-
4-(BroMoMethyl)-2-fluoro-1-nitrobenzene
131858-37-2
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