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ChemicalBook >> CAS DataBase List >>Sodium dodecylbenzenesulphonate

Sodium dodecylbenzenesulphonate

CAS No.
25155-30-0
Chemical Name:
Sodium dodecylbenzenesulphonate
Synonyms
sdbs;SODIUM DODECYLBENZENESULFONATE;SODIUM DODECYLBENZENESULFONATE;Sodium dodecyL;DODECYLBENZENESULFONIC ACID SODIUM SALT;DDBS;SODIUM ALKYLBENZENESULFONATE;DODECYLBENZENE SODIUM SULFONATE;LAS-C12;SODIUM LAURYLBENZENESULFONATE
CBNumber:
CB4852054
Molecular Formula:
C18H29NaO3S
Molecular Weight:
348.48
MDL Number:
MFCD00011508
MOL File:
25155-30-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-05 18:44:30
Product description Number Pack Size Price
Sodium dodecylbenzenesulfonate technical grade 289957 1kg $110
Sodium dodecylbenzenesulfonate technical grade 289957 10kg $371
Sodium Dodecylbenzenesulfonate (hard type) (mixture) D0990 500G $50
Dodecene-1 LAS D1428 1G $79
Dodecylbenzenesulfonic Acid Sodium Salt (Technical Grade) TRC-D525661-5G 5g $84
More product size

Sodium dodecylbenzenesulphonate Properties

Melting point >300 °C
Boiling point 660.62℃[at 101 325 Pa]
Density 1.02 g/cm3
vapor pressure 0Pa at 25℃
refractive index 1.359
storage temp. 2-30°C
solubility water: soluble 0,8  g/L °C
pka 0.7[at 20 ℃]
form powder
color light yellow
Odor Slight, characteristic odor
Water Solubility 800mg/L at 25℃
Merck 14,8612
BRN 4171051
Henry's Law Constant 1.6×102 mol/(m3Pa) at 25℃, HSDB (2015)
Stability Stable.
Cosmetics Ingredients Functions CLEANSING
SURFACTANT - CLEANSING
InChI 1S/C18H30O3S.Na/c1-2-3-4-5-6-7-8-9-10-11-12-17-13-15-18(16-14-17)22(19,20)21;/h13-16H,2-12H2,1H3,(H,19,20,21);/q;+1/p-1
InChIKey JHJUUEHSAZXEEO-UHFFFAOYSA-M
SMILES [Na+].CCCCCCCCCCCCc1ccc(cc1)S([O-])(=O)=O
LogP 1.96 at 25℃
CAS DataBase Reference 25155-30-0(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) SODIUM DODECYLBENZENESULFONATE
FDA 21 CFR 173.315(Chemicals used in washing or to assist in the peeling of fruits and vegetables); 175.300(Resinous and polymeric coatings); 175.320(Resinous and polymeric coatings for polyolefin films);
175.365(Vinylidene chloride copolymer coatings for polycarbonate film); 177.1010(Acrylic and modified acrylic plastics, semirigid and rigid); 177.1200(Cellophane);
177.1630(Polyethylene phthalate polymers); 177.2600(Rubber articles intended for repeated use); 177.2800(Textiles and textile fibers);
178.1010(Sanitizing solutions); 178.3120(Animal glue)
EWG's Food Scores 1
FDA UNII 554127163Y
EPA Substance Registry System Sodium dodecylbenzenesulfonate (25155-30-0)
Cosmetics Info Sodium Dodecylbenzenesulfonate
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P264-P270-P280-P301+P312-P302+P352-P305+P351+P338
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xn
Risk Statements  22-37/38-41
Safety Statements  26-27-36/37/39
RIDADR  3077
WGK Germany  2
RTECS  DB6825000
TSCA  TSCA listed
HazardClass  9
PackingGroup  III
HS Code  29041000
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
Hazardous Substances Data 25155-30-0(Hazardous Substances Data)
Toxicity LD50 in mice: 2 g/kg orally; 105 mg/kg i.v. (Hopper)
REACH Registrations Active
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
2 0

Sodium dodecylbenzenesulphonate price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 289957 Sodium dodecylbenzenesulfonate technical grade 25155-30-0 1kg $110 2026-04-30 Buy
Sigma-Aldrich 289957 Sodium dodecylbenzenesulfonate technical grade 25155-30-0 10kg $371 2026-04-30 Buy
TCI Chemical D0990 Sodium Dodecylbenzenesulfonate (hard type) (mixture) 25155-30-0 500G $50 2025-07-31 Buy
TCI Chemical D1428 Dodecene-1 LAS 25155-30-0 1G $79 2025-07-31 Buy
TRC TRC-D525661-5G Dodecylbenzenesulfonic Acid Sodium Salt (Technical Grade) 25155-30-0 5g $84 2026-06-03 Buy
Product number Packaging Price Buy
289957 1kg $110 Buy
289957 10kg $371 Buy
D0990 500G $50 Buy
D1428 1G $79 Buy
TRC-D525661-5G 5g $84 Buy

Sodium dodecylbenzenesulphonate Chemical Properties,Uses,Production

Description

Sodium dodecyl benzene sulfonate is a series of organic compounds with the formula C12H25C6H4SO3Na. It is a colourless salt with useful properties as a surfactant. It is usually produced as a mixture of related sulfonates. It is a major component of laundry detergent.

Chemical Properties

white or light yellow flakes

Uses

Sodium dodecylbenzenesulfonate has been used to stabilize dispersions of graphene nanoflakes (GNFs) during the preparation of the liquid phase of GNFs. It can also suspend single-walled carbon nanotubes as individuals in aqueous media and also give well-resolved spectral features.

Uses

A surfactant used in proteomics research.

Uses

Anionic detergent.

General Description

Sodium dodecylbenzenesulfonate is a white to light yellow flakes, granules or powder. Sodium dodecylbenzenesulphonate is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Sodium dodecylbenzenesulphonate is used as a synthetic detergent.

Air & Water Reactions

Sodium dodecylbenzenesulphonate is soluble in water.

Reactivity Profile

SODIUM DODECYLBENZENESULFONATE is incompatible with strong oxidizers.

Health Hazard

Minor skin and eye irritant. INGESTION: May cause vomiting, diarrhea, and intestinal distension.

Flammability and Explosibility

Non flammable

Industrial uses

These frothers are mixtures of alcohols containing 6–8 carbon atoms. They were at one time marketed by DuPont and they are tailored frothers for specific ore types. The bestknown frother from this group is methyl isobutyl carbinol (MIBC) and 2-ethyl hexanol.
Aliphatic alcohol frothers are used as mixtures of different carbon lengths and as a mixture of hydrocarbon oils.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A skin and severe eye irritant. When heated to decomposiuon it emits tomc fumes of NazO. See also SULFONATES

Synthesis

Sodium dodecylbenzenesulphonate is synthesised using 2-phenyldodecane as raw material by chemical reaction. The specific synthesis steps are as follows:
To a 5 L round bottom flask equipped with mechanical stirrer and an addition funnel was added octadecane and 2-phenyldodecane mixture ( 1.73 kg, 28%> 2-phenyldodecane). The reaction mixture was sparged with argon, warmed to 35°C and 1.25 weight % of oleum (632 g, 1.58 mol) was added dropwise, via addition funnel, to reaction mixture. The reaction mixture was stirred for 1.5 hours at room temperature. Upon completion, the reaction mixture was heated to 50°C and transferred to a separatory funnel and allowed to separate. The bottom layer was added slowly to a stirred solution of 15%> NaOH (aq) (2 L) at 10°C. Upon complete addition the resulting suspension was stirred for an additional 60 minutes. The solid was subsequently isolated by filtration and washed twice with ice-cold water. The solids were air dried for 16 hours and vacuum dried at 80°C to yield sodium, 4-(dodecan-2-yl) benzenesulfonate (555 g, 80.8% yield, 98.5% purity). lH NMR (400 MHz, (CD3)2S0/CDC13) δ 0.84 (t, J = 7.0 Hz, 3H), 0.95- 1.38 (m, 19H), 1.51 (pquart, J = 7.3 Hz, 2H), 2.65 (psext, J = 7.0 Hz, 1 H), 7.1 1 (d, J = 7.6 Hz, 2H), 7.56 (d, J = 8.4 Hz, 2H). 13C NMR (101 MHz, (CD3)2S0/CDC13) δ 13.8, 22.0, 22.1 , 27.0, 28.9, 28.9, 28.9, 28.9, 31.2, 37.6, 38.8, 125.4, 125.8, 145.3, 147.7.
Sodium dodecylbenzenesulphonate synthesis

Purification Methods

It crystallises from propan-2-ol or H2O. [Gray et al. J Org Chem 20 515 1955, Beilstein 11 IV 514.]

Environmental considerations

Biodegradability has been well studied , and is affected by the isomerization (branching). The salt has an LD50 of 2.3 mg / liter for fish , about 4x more toxic than the branched tetra propylene benzene sulfonate. It is however biodegraded more rapidly. Oxidative degradation initiates at the alkyl chain.

Alkyl benzene sulfonates

Most sodium dodecyl benzene sulfonates are a member of the linear alkyl benzene sulfonates, meaning that the dodecyl group (C12H25) is un branched. This dodecyl chain is attached at the 4- position of the benzene sulfonate group. Linear dodecyl-4-benzene sulfonate anions can exist in six isomers (ignoring optical isomers), depending on the carbon of the dodecyl group that is attached to the benzene ring. The isomer shown below left is 4-(5-dodecyl ) benzene sulfonate (4 indicating the position of the benzene ring, 5 indicating the position on the dodecane chain). Branched isomers, e.g. those derived from tetramerized propylene, are also known (below right) but are not as widely used because they biodegrade too slowly.
Production
Trillions of kilograms are produced annually. Given the large scale of the application, the alkyl benzene sulfonates have been prepared by many methods. In the most common route, benzene is alkylated by long chain mono alkenes (e.g. dodecene) using hydrogen fluoride as a catalyst. The purified dodecyl benzenes (and related derivatives) are then sulfonated with sulfur trioxide to give the sulfonic acid. The sulfonic acid is subsequently neutralized with sodium hydroxide.

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