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ChemicalBook >> CAS DataBase List >>N,N-dimethyl-m-phenylenediamine

N,N-dimethyl-m-phenylenediamine

CAS No.
2836-04-6
Chemical Name:
N,N-dimethyl-m-phenylenediamine
Synonyms
N1,N1-dimethylbenzene-1,3-diamine;m-Aminodimethylaniline;3-Amino-N,N-dimethylaniline;N-dimethyl-m-phenylenediamine;N,N-dimethylbenzene-1,3-diamine;N,N-dimethyl-3-phenylenediamine;N,N-DIMETHYL-1,3-BENZENEDIAMINE);N,N-Dimethyl-1,3-phenylenediamine;N,N-DIMETHYLMETA-PHENYLENEDIAMINE;1,3-Benzenediamine, N1,N1-dimethyl-
CBNumber:
CB4875208
Molecular Formula:
C8H12N2
Molecular Weight:
136.19
MDL Number:
MFCD00040473
MOL File:
2836-04-6.mol
MSDS File:
SDS
Last updated:2026-05-28 01:29:23
Product description Number Pack Size Price
N1,N1-Dimethyl-1,3-benzenediamine 95% AS92977 1g $42
N1,N1-Dimethyl-1,3-benzenediamine 95% AS92977 5g $120
N1,N1-Dimethylbenzene-1,3-Diamine 97% AA00BFFJ 100mg $11
N1,N1-Dimethylbenzene-1,3-Diamine ≥97% AA00BFFJ 250mg $12
N1,N1-Dimethylbenzene-1,3-Diamine 97% AA00BFFJ 1g $29
More product size

N,N-dimethyl-m-phenylenediamine Properties

Melting point <-20 °C
Boiling point 240.49°C (rough estimate)
Density 0.9950
refractive index 1.5914 (estimate)
storage temp. 2-8°C(protect from light)
pka 5.11±0.10(Predicted)
Appearance Brown to black Liquid
EPA Substance Registry System 1,3-Benzenediamine, N,N-dimethyl- (2836-04-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H311+H331-H302-H318-H361-H373-H317
Precautionary statements  P501-P273-P272-P260-P270-P202-P201-P271-P264-P280-P391-P308+P311-P361+P364-P333+P313-P301+P312+P330-P302+P352+P312-P304+P340+P311-P305+P351+P338+P310-P403+P233-P405
Risk Statements  25-36/37/38-43
Safety Statements  36/37/39-45
RIDADR  2810
TSCA  TSCA listed
HS Code  29215900

N,N-dimethyl-m-phenylenediamine price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Activate Scientific AS92977 N1,N1-Dimethyl-1,3-benzenediamine 95% 2836-04-6 1g $42 2026-06-04 Buy
Activate Scientific AS92977 N1,N1-Dimethyl-1,3-benzenediamine 95% 2836-04-6 5g $120 2026-06-04 Buy
aablocks AA00BFFJ N1,N1-Dimethylbenzene-1,3-Diamine 97% 2836-04-6 100mg $11 2026-05-28 Buy
aablocks AA00BFFJ N1,N1-Dimethylbenzene-1,3-Diamine ≥97% 2836-04-6 250mg $12 2026-05-28 Buy
aablocks AA00BFFJ N1,N1-Dimethylbenzene-1,3-Diamine 97% 2836-04-6 1g $29 2026-05-28 Buy
Product number Packaging Price Buy
AS92977 1g $42 Buy
AS92977 5g $120 Buy
AA00BFFJ 100mg $11 Buy
AA00BFFJ 250mg $12 Buy
AA00BFFJ 1g $29 Buy

N,N-dimethyl-m-phenylenediamine Chemical Properties,Uses,Production

Chemical Properties

Light yellow to black liquid

Synthesis

N,N-DIMETHYL-3-NITROANILINE

619-31-8

N,N-dimethyl-m-phenylenediamine

2836-04-6

Step 2: Synthesis of N1,N1-dimethylbenzene-1,3-diamine N,N-dimethyl-3-nitroaniline (1.0 g, 6.08 mmol) prepared in Step 1 was dissolved in methanol (25 mL) and 10% palladium carbon (Pd/C, 100 mg) was added. The reaction mixture was hydrogenated in a hydrogen atmosphere for 15 hours at room temperature. Upon completion of the reaction, the palladium carbon catalyst was removed by diatomaceous earth filtration and the filtrate was concentrated to dryness under reduced pressure. The resulting residue was purified by fast column chromatography (eluent: hexane/ethyl acetate=1:1, v/v) to afford N1,N1-dimethylbenzene-1,3-diamine (700 mg, yield: 90%, colorless liquid). 1H NMR (400MHz, CDCl3) δ: 7.04 (t, J=7.6Hz, 1H), 6.2 (d, J=8.0Hz, 1H), 6.11-6.08 (m, 1H), 3.60 (br s, 2H), 2.92 (s, 6H).

References

[1] Journal of Organic Chemistry, 1992, vol. 57, # 19, p. 5254 - 5255
[2] Patent: EP2364983, 2011, A2. Location in patent: Page/Page column 51-52
[3] Patent: US2011/218193, 2011, A1. Location in patent: Page/Page column 42
[4] Journal fuer Praktische Chemie (Leipzig), 1986, vol. 328, # 4, p. 497 - 514
[5] Patent: WO2010/67078, 2010, A2. Location in patent: Page/Page column 79

N,N-dimethyl-m-phenylenediamine Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N-dimethyl-m-phenylenediamine Spectrum

N,N-dimethylbenzene-1,3-diamine N,N-Dimethyl-1,3-phenylenediamine N,N-dimethyl-3-phenylenediamine N,N-DIMETHYLMETA-PHENYLENEDIAMINE N,N-DIMETHYL-1,3-BENZENEDIAMINE) 3-Amino-N,N-dimethylaniline m-Aminodimethylaniline 3-N,3-N-dimethylbenzene-1,3-diamine 1,3-Benzenediamine, N1,N1-dimethyl- N-dimethyl-m-phenylenediamine N1,N1-dimethylbenzene-1,3-diamine 2836-04-6 836-04-6
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