ChemicalBook >> CAS DataBase List >>(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
![(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Structure](CAS/GIF/850444-36-9.gif)
- CAS No.
- 850444-36-9
- Chemical Name:
- (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
- Synonyms
- 97% TANIAPHOS;(SP)-1-[(S)-aL;(S,Sp)-Taniaphos;(2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(2Sp)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(SP)-1-[(S)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane;(S)-1-Diphenylphosphino-2-[(S)-(N,N-dimethylamino) [2-(diphenylphosphino)phenyl]methyl]ferrocene;(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
- CBNumber:
- CB52129553
- Molecular Formula:
- C38H34NP2.C5H5.Fe
- Molecular Weight:
- 687.581
- MDL Number:
- MFCD08561147
- MOL File:
- 850444-36-9.mol
- MSDS File:
- SDS
Last updated:2026-05-28 01:25:32
| Product description | Number | Pack Size | Price |
| (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene ≥97%, optical purity ee: ≥99% | 73476 | 1g | $802 |
| (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene ≥97%, optical purity ee: ≥99% | 73476 | 5g | $3690 |
| (S)-(-)-[(S)-2-Diphenyl-phosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphino-phenyl)methane, min. 97% TANIAPHOS min.97% | 26-1155 | 100mg | $99 |
| (S)-(-)-[(S)-2-Diphenyl-phosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphino-phenyl)methane, min. 97% TANIAPHOS min.97% | 26-1155 | 500mg | $366 |
| (S)-(-)-[(S)-2-Diphenyl-phosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphino-phenyl)methane, min. 97% TANIAPHOS min.97% | 26-1155 | 2g | $1244 |
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Properties
| alpha | -312° ±15° (c 0.5, CHCl3) |
|---|---|
| storage temp. | 2-8°C |
| form | Powder |
| color | orange |
| Stability | store cold |
| InChIKey | DEHRMLQYTSYVBC-ZCLNGFLVSA-N |
| SMILES | [Fe].[CH]1[CH][CH][CH][CH]1.CN(C)[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7 |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| PPE | Eyeshields, Gloves, type N95 (US) |
| WGK Germany | 3 |
| HS Code | 29319090 |
| Storage Class | 11 - Combustible Solids |
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 73476 | (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene ≥97%, optical purity ee: ≥99% | 850444-36-9 | 1g | $802 | 2026-04-30 | Buy |
| Sigma-Aldrich | 73476 | (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene ≥97%, optical purity ee: ≥99% | 850444-36-9 | 5g | $3690 | 2026-04-30 | Buy |
| Strem Chemicals | 26-1155 | (S)-(-)-[(S)-2-Diphenyl-phosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphino-phenyl)methane, min. 97% TANIAPHOS min.97% | 850444-36-9 | 100mg | $99 | 2026-04-30 | Buy |
| Strem Chemicals | 26-1155 | (S)-(-)-[(S)-2-Diphenyl-phosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphino-phenyl)methane, min. 97% TANIAPHOS min.97% | 850444-36-9 | 500mg | $366 | 2026-04-30 | Buy |
| Strem Chemicals | 26-1155 | (S)-(-)-[(S)-2-Diphenyl-phosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphino-phenyl)methane, min. 97% TANIAPHOS min.97% | 850444-36-9 | 2g | $1244 | 2026-04-30 | Buy |
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Chemical Properties,Uses,Production
Reactions
- Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
- Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
- AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates.
Chemical Properties
Orange powder
General Description
sold in collaboration with Solvias AG
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Suppliers
Global( 34)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9996 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52923 | 58 | |
| J & K SCIENTIFIC LTD. | 18210857532; 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9416 | 55 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44816 | 61 |
| Shanghai Incat Chemtech Co.,Ltd. | 021-57603038 13601791340 | 307593986@qq.com | China | 475 | 58 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51395 | 80 |
| Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. | 0371-65511006 18737115891;18625597674 | info@kingorgchem.com;sales@kingorgchem.com | China | 812 | 55 |
| Panjin Infinity Scientific CO. LTD | 400-1062016 18612996721 | hao@infsci.com | China | 327 | 58 |
| LaaJoo | 021-60702684 18516024827 | huang.jiayi@sinocompound.com | China | 2280 | 58 |
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Spectrum
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-
diphenylphosphinophenyl)methane, min. 97% TANIAPHOS (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane 97% TANIAPHOS (S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS (SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99% Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS) (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS (SP)-1-[(S)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (SP)-1-[(S)-aL (2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (S)-1-Diphenylphosphino-2-[(S)-(N,N-dimethylamino) [2-(diphenylphosphino)phenyl]methyl]ferrocene (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS ISO 9001：2015 REACH (S,Sp)-Taniaphos (2Sp)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane,97% TANIAPHOS (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene 850444-36-9 Chiral Phosphine Ferrocene Series Taniaphos Series metallocene
diphenylphosphinophenyl)methane, min. 97% TANIAPHOS (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane 97% TANIAPHOS (S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS (SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99% Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS) (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS (SP)-1-[(S)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (SP)-1-[(S)-aL (2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (S)-1-Diphenylphosphino-2-[(S)-(N,N-dimethylamino) [2-(diphenylphosphino)phenyl]methyl]ferrocene (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS ISO 9001：2015 REACH (S,Sp)-Taniaphos (2Sp)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane,97% TANIAPHOS (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene 850444-36-9 Chiral Phosphine Ferrocene Series Taniaphos Series metallocene
