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TRI-M-TOLYLPHOSPHINE

TRI-M-TOLYLPHOSPHINE structure

CAS No.: 6224-63-1

Chemical Name:: TRI-M-TOLYLPHOSPHINE

Synonyms: TRIS(3-METHYLPHENYL)PHOSPHINE;Tri-M-tolyl;Tris(3-methyL;Tri-m-tolyphosphine;Tri-M-tolylphosphin;TRI-M-TOLYLPHOSPHINE;tri(3-Tolyl)phosphine;TRIS(M-TOLYL)PHOSPHINE;PHOSPHORUS TRI-M-TOLYL;TRIS(3-TOLYL)PHOSPHINE

CBNumber:: CB5401093

Molecular Formula:: C21H21P

Molecular Weight:: 304.37

MDL Number:: MFCD00008532

MOL File:: 6224-63-1.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 03:33:11

Product description	Number	Pack Size	Price
Tri(m-tolyl)phosphine >98.0%(GC)	T1025	5g	$41
Tri(m-tolyl)phosphine >98.0%(GC)	T1025	25g	$119
Tri-m-tolylphosphine, 98% 98%	15-8100	5g	$61
Tri-m-tolylphosphine, 98% 98%	15-8100	25g	$240
Tri-m-tolylphosphine, 98%	15-8100	5g	$58
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TRI-M-TOLYLPHOSPHINE Properties

Melting point	97-99 °C(lit.)
Boiling point	423.1±44.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
form	crystal
color	white
Water Solubility	Insoluble in water.
Sensitive	Air Sensitive
BRN	658863
InChI	InChI=1S/C21H21P/c1-16-7-4-10-19(13-16)22(20-11-5-8-17(2)14-20)21-12-6-9-18(3)15-21/h4-15H,1-3H3
InChIKey	LFNXCUNDYSYVJY-UHFFFAOYSA-N
SMILES	P(C1=CC=CC(C)=C1)(C1=CC=CC(C)=C1)C1=CC=CC(C)=C1
CAS DataBase Reference	6224-63-1(CAS DataBase Reference)
FDA UNII	SAQ9Z5ZSC8
EPA Substance Registry System	Phosphine, tris(3-methylphenyl)- (6224-63-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Hazard Codes

Risk Statements

36/37/38-38-37-36

Safety Statements

26-36

WGK Germany

10-23

TSCA

TSCA listed

HS Code

29319090

NFPA 704

	1
2		0

TRI-M-TOLYLPHOSPHINE price More Price(54)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	T1025	Tri(m-tolyl)phosphine >98.0%(GC)	6224-63-1	5g	$41	2026-04-30	Buy
TCI Chemical	T1025	Tri(m-tolyl)phosphine >98.0%(GC)	6224-63-1	25g	$119	2026-04-30	Buy
Strem Chemicals	15-8100	Tri-m-tolylphosphine, 98% 98%	6224-63-1	5g	$61	2026-04-30	Buy
Strem Chemicals	15-8100	Tri-m-tolylphosphine, 98% 98%	6224-63-1	25g	$240	2026-04-30	Buy
Strem Chemicals	15-8100	Tri-m-tolylphosphine, 98%	6224-63-1	5g	$58	2024-03-01	Buy

Product number	Packaging	Price	Buy
T1025	5g	$41	Buy
T1025	25g	$119	Buy
15-8100	5g	$61	Buy
15-8100	25g	$240	Buy
15-8100	5g	$58	Buy

TRI-M-TOLYLPHOSPHINE Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

suzuki reaction

Uses

Tri-m-tolylphosphine acts as a reagent for the preparation, crystal structure, multinuclear NMR, antitumor activity, photolysis of silver methylxanthate complexes against human adrenocarcinoma breast cancer cells.

Synthesis

6151-88-8

6224-63-1

The general procedure for the synthesis of tris(m-tolyl)phosphine from the compound (CAS: 6151-88-8) was as follows: magnesium powder (8 mmol, 4 eq.), trimethylchlorosilane (6 mmol, 3 eq.) and 1,3-dimethyl-2-imidazolidinone (DMI, 8 mL) were mixed and compound 2a (2 mmol) was added. The reaction mixture was stirred at room temperature for 2 hours. Upon completion of the reaction, the reaction was quenched by adding saturated aqueous ammonium carbonate to the mixture and extracted with ether (10 mL × 3). The organic layers were combined, washed with saturated aqueous sodium chloride, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The crude product was analyzed by 31P NMR, showing a 97:3 ratio of tris(m-tolyl)phosphine (1a) to the feedstock 2a. The crude product was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 5:1) to give the target product, tris(m-tolyl)phosphine (1a), in 96% yield (Table 1, entry 1).

References

[1] Synthesis, 2011, # 24, p. 4091 - 4098
[2] Tetrahedron Letters, 2015, vol. 56, # 7, p. 918 - 920
[3] Tetrahedron, 2011, vol. 67, # 32, p. 5825 - 5831

TRI-M-TOLYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Ethanol 5-Bromo-m-xylene Phosphorus trichloride Tetrahydrofuran Ethyl acetate

Hydrochloric acid Dichloromethane 3-Bromotoluene Petroleum ether Magnesium

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Preparation Products

TRI-M-TOLYLPHOSPHINE Suppliers

Global( 219)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13901	58
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1803	55
AB PharmaTech,LLC	323-480-4688	sales@acrospharmatech.com	United States	989	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29815	58
Wuhan Pengo Technology.,Ltd.	+86-27-81330736 +86-13628634921	sunny.w@boronicgroup.com	CHINA	171	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-81139210 +86-18192627656	1059@dideu.com	China	3587	58
Tangshan Moneide Trading Co., Ltd.	+86-315-8309571 +8615633399667	sales@moneidechem.com	China	574	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5742	58

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Shanghai Time Chemicals CO., Ltd.	55
AB PharmaTech,LLC	55
career henan chemical co	58
Wuhan Pengo Technology.,Ltd.	58
Shaanxi Dideu Medichem Co. Ltd	58
Tangshan Moneide Trading Co., Ltd.	58
Richest Group Ltd	58
Antai Fine Chemical Technology Co.,Limited	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58

View Lastest Price from TRI-M-TOLYLPHOSPHINE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-12-12	Tri(M-tolyl)phosphine 6224-63-1	$1.00	1KG	99%	20 Tons	Shaanxi Dideu Medichem Co. Ltd
2023-06-14	Tri(m-tolyl)phosphine 6224-63-1		1kg	99%		Wuhan Mayue Longteng Technology Development Co., Ltd.
2020-11-16	TRI-M-TOLYLPHOSPHINE 6224-63-1	$18.00	1KG	99%	10000KG	Longyan Tianhua Biological Technology Co., Ltd

Tri(M-tolyl)phosphine
6224-63-1
$1.00
99%
Shaanxi Dideu Medichem Co. Ltd

Tri(m-tolyl)phosphine
6224-63-1
$0.00
99%
Wuhan Mayue Longteng Technology Development Co., Ltd.

TRI-M-TOLYLPHOSPHINE
6224-63-1
$18.00
99%
Longyan Tianhua Biological Technology Co., Ltd

TRI-M-TOLYLPHOSPHINE Spectrum

TRI-M-TOLYLPHOSPHINE(6224-63-1)MS TRI-M-TOLYLPHOSPHINE(6224-63-1)¹HNMR TRI-M-TOLYLPHOSPHINE(6224-63-1)¹³CNMR TRI-M-TOLYLPHOSPHINE(6224-63-1)IR1 TRI-M-TOLYLPHOSPHINE(6224-63-1)IR2

6224-63-1(TRI-M-TOLYLPHOSPHINE)Related Search:

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DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (S)-(-)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL TRI-M-TOLYLPHOSPHINE (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE

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BIS(TRIS(3-(H4-PERFLUORODECYL)PHENYL)PH& BIS(TRIS(3-(HEPTADECAFLUOROOCTYL)PHE)PHO TRIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINE

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Tri-m-tolyphosphine Tris(m-tolyl)phosphine, 98+% Tri(m-tolyl)phosphine,98+% TRIS(M-TOLYL)PHOSPHINE (TMTP) Tris(m-methylphenyl)phosphine tris(3-Methylphenyl)phosphane Phosphine,tris(3-Methylphenyl)- Tri-M-tolylphosphin Tri(m-tolyl)phosphine PHOSPHORUS TRI-M-TOLYL TRIS(M-TOLYL)PHOSPHINE TRIS(3-TOLYL)PHOSPHINE TRI-M-TOLYLPHOSPHINE Phosphine, tri-m-tolyl- tri-(3-Methylphenyl)phosphine tri(3-Tolyl)phosphine tris(3-methylphenyl)-phosphin Tri-M-tolyl Tris(3-methyL TRIS(3-METHYLPHENYL)PHOSPHINE 6224-63-1 CH3C6H43P mCH3C6H43P Phosphine Ligands Catalysis and Inorganic Chemistry Phosphorus Compounds Phosphorus Compounds Achiral Phosphine Aryl Phosphine organophosphorus ligand Ligand Phosphine Ligands Synthetic Organic Chemistry Basic Phosphine LigandsCatalysis and Inorganic Chemistry Catalysis and Inorganic Chemistry Cross-Coupling Phosphine Ligands

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TRI-M-TOLYLPHOSPHINE

TRI-M-TOLYLPHOSPHINE Properties

SAFETY

Risk and Safety Statements

TRI-M-TOLYLPHOSPHINE price More Price(54)

TRI-M-TOLYLPHOSPHINE Chemical Properties,Uses,Production

Chemical Properties

Uses

Uses

Synthesis

References

TRI-M-TOLYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

TRI-M-TOLYLPHOSPHINE Suppliers

View Lastest Price from TRI-M-TOLYLPHOSPHINE manufacturers

TRI-M-TOLYLPHOSPHINE Spectrum

6224-63-1(TRI-M-TOLYLPHOSPHINE)Related Search: