5-PHENYL-2-THIENYLBORONIC ACID
- CAS No.
- 306934-95-2
- Chemical Name:
- 5-PHENYL-2-THIENYLBORONIC ACID
- Synonyms
- AKOS BRN-0521;5-phenyl-2-thinylboronic acid;5-PHENYL-2-THIENYLBORONIC ACID;2-Phenylthiophene-5-boronic acid;5-Phenylthiophene-2-boronic acid;2-Phenyl-5-thiopheneboronic acid;5-phenylthiophen-2 -boronic acid;5-Phenyl-2-thiopheneboronic acid;(5-Phenylthien-2-yl)boronic acid;(5-phenylthiophen-2-yl)boronic acid
- CBNumber:
- CB5766699
- Molecular Formula:
- C10H9BO2S
- Molecular Weight:
- 204.05
- MDL Number:
- MFCD01114643
- MOL File:
- 306934-95-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 5-Phenylthiophene-2-boronic acid | GMA93495 | 0.25g | $250 |
| 5-Phenylthiophene-2-boronic acid | GMA93495 | 2.5g | $855.5 |
| 5-Phenylthiophene-2-boronic acid ≥95% | OR23152 | 1g | $36 |
| 5-Phenylthiophene-2-boronic acid | 082006 | 1.00g | $34 |
| 5-Phenylthiophene-2-boronic acid | 082006 | 5.00g | $107 |
| Melting point | 140 °C |
|---|---|
| Boiling point | 412.9±47.0 °C(Predicted) |
| Density | 1.29±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Store in freezer, under -20°C |
| form | solid |
| pka | 8.49±0.53(Predicted) |
| Appearance | White to off-white Solid |
| InChI | 1S/C10H9BO2S/c12-11(13)10-7-6-9(14-10)8-4-2-1-3-5-8/h1-7,12-13H |
| InChIKey | RBSMKSPHBJFXCJ-UHFFFAOYSA-N |
| SMILES | OB(O)c1ccc(s1)-c2ccccc2 |
| UNSPSC Code | 12352200 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302 |
| Precautionary statements | P280-P305+P351+P338 |
| Hazard Codes | Xi,Xn |
| Risk Statements | 36/37/38-22 |
| Safety Statements | 26-36/37/39 |
| WGK Germany | WGK 3 |
| Hazard Note | Irritant |
| HS Code | 2934999090 |
| Storage Class | 13 - Non Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral |
5-PHENYL-2-THIENYLBORONIC ACID price More Price(55)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | GMA93495 | 5-Phenylthiophene-2-boronic acid | 306934-95-2 | 0.25g | $250 | 2026-06-04 | Buy |
| Biosynth | GMA93495 | 5-Phenylthiophene-2-boronic acid | 306934-95-2 | 2.5g | $855.5 | 2026-06-04 | Buy |
| Apolloscientific | OR23152 | 5-Phenylthiophene-2-boronic acid ≥95% | 306934-95-2 | 1g | $36 | 2026-06-04 | Buy |
| Matrix Scientific | 082006 | 5-Phenylthiophene-2-boronic acid | 306934-95-2 | 1.00g | $34 | 2026-05-18 | Buy |
| Matrix Scientific | 082006 | 5-Phenylthiophene-2-boronic acid | 306934-95-2 | 5.00g | $107 | 2026-05-18 | Buy |
5-PHENYL-2-THIENYLBORONIC ACID Chemical Properties,Uses,Production
Synthesis
29488-24-2
306934-95-2
Under nitrogen protection, 2-bromo-5-phenylthiophene (compound 111, 2.50 g, 10.4 mmol) was dissolved in anhydrous THF (50 mL) and cooled to -78 °C. Slowly n-butyllithium (n-BuLi, 8.4 mL of a 2.5 M hexane solution) was added dropwise. The reaction mixture was stirred at -78 °C for 1 h. Trimethyl borate (2.40 mL, 20.9 mmol) was slowly added. Stirring was continued at -78 °C for 30 min, followed by removal of the cooling bath to allow the reaction mixture to gradually warm to room temperature and stirring for 3 h at 37 °C. Upon completion of the reaction, the reaction was quenched with 1N HCl (100 mL) and subsequently extracted with ethyl acetate. The organic layers were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. The crude product was slurried with petroleum ether, filtered and dried to afford (5-phenylthiophen-2-yl)boronic acid (Compound 112, 1.04 g, 48.8% yield).
References
[1] Patent: US7485733, 2009, B2. Location in patent: Page/Page column 77
[2] Chemistry - A European Journal, 2002, vol. 8, # 10, p. 2384 - 2396
[3] Patent: US2008/108832, 2008, A1. Location in patent: Page/Page column 51
[4] Patent: EP2177516, 2010, A1. Location in patent: Page/Page column 46-47
5-PHENYL-2-THIENYLBORONIC ACID Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
5-PHENYL-2-THIENYLBORONIC ACID Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Shenzhen Excellent Biotech Co., Ltd. | 13480692018 | ramyan@ex-biotech.com | CHINA | 954 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24597 | 58 |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53803 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131956 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532; 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40228 | 62 |
View Lastest Price from 5-PHENYL-2-THIENYLBORONIC ACID manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-12-27 | 5-PHENYL-2-THIENYLBORONIC ACID
306934-95-2
|
$1.00 | 1g | 99% | 200kg | Career Henan Chemical Co |
-
- 5-PHENYL-2-THIENYLBORONIC ACID
306934-95-2
- $1.00
- 99%
- Career Henan Chemical Co
