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ChemicalBook >> CAS DataBase List >>2-Fluoro-3-nitrotoluene

2-Fluoro-3-nitrotoluene

CAS No.
437-86-5
Chemical Name:
2-Fluoro-3-nitrotoluene
Synonyms
2-FLUORO-1-METHYL-3-NITROBENZENE;2-fluoro-3-Nitrotoluol;2-Fluoro-3-nitrotluene;2-Fluoro-3-nitrotoluen;2-FLUORO-3-NITROTOLUENE;2-FLUORO-1-METHYL-3-NITR;2-Fluoro-3-nitrotoluene>2-fluoro-3-methylnitrobenzene;2-Fluoro-3-maethylnitrobenzene;2-Fluoro-1-methyl-3-nitrobenzece
CBNumber:
CB6402567
Molecular Formula:
C7H6FNO2
Molecular Weight:
155.13
MDL Number:
MFCD03412242
MOL File:
437-86-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:07:10
Product description Number Pack Size Price
2-Fluoro-3-nitrotoluene >98.0%(GC) F0661 5g $38
2-Fluoro-3-nitrotoluene >98.0%(GC) F0661 25g $150
2-Fluoro-3-nitrotoluene FF70504 25g $150
2-Fluoro-3-nitrotoluene FF70504 50g $150
2-Fluoro-3-nitrotoluene FF70504 100g $179
More product size

2-Fluoro-3-nitrotoluene Properties

Melting point 19℃
Boiling point 111℃/12mm
Density 1.276
Flash point 98°(208°F)
refractive index 1.5290
storage temp. Sealed in dry,Room Temperature
form Liquid
color Colorless to pale yellow
InChI InChI=1S/C7H6FNO2/c1-5-3-2-4-6(7(5)8)9(10)11/h2-4H,1H3
InChIKey NBCNUIXYBLFJMI-UHFFFAOYSA-N
SMILES C1(C)=CC=CC([N+]([O-])=O)=C1F
LogP 1.423
CAS DataBase Reference 437-86-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Skull and Crossbones (GHS06)
GHS07,GHS06
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H302-H331-H335
Precautionary statements  P280a-P304+P340-P305+P351+P338-P405-P501a-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
Hazard Codes  Xi,C
Risk Statements  34-36/37/38-20/22
Safety Statements  26-36/37/39-45-36/37
Hazard Note  Harmful/Irritant
HazardClass  IRRITANT
HazardClass  6.1
HS Code  29039990
REACH Registrations Active
NFPA 704
1
2 0

2-Fluoro-3-nitrotoluene price More Price(76)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical F0661 2-Fluoro-3-nitrotoluene >98.0%(GC) 437-86-5 5g $38 2026-04-30 Buy
TCI Chemical F0661 2-Fluoro-3-nitrotoluene >98.0%(GC) 437-86-5 25g $150 2026-04-30 Buy
Biosynth FF70504 2-Fluoro-3-nitrotoluene 437-86-5 25g $150 2026-06-04 Buy
Biosynth FF70504 2-Fluoro-3-nitrotoluene 437-86-5 50g $150 2026-06-04 Buy
Biosynth FF70504 2-Fluoro-3-nitrotoluene 437-86-5 100g $179 2026-06-04 Buy
Product number Packaging Price Buy
F0661 5g $38 Buy
F0661 25g $150 Buy
FF70504 25g $150 Buy
FF70504 50g $150 Buy
FF70504 100g $179 Buy

2-Fluoro-3-nitrotoluene Chemical Properties,Uses,Production

Chemical Properties

Clear light yellow to yellow liquid

Uses

2-Fluoro-3-nitrotoluene is a class of fluorinated aromatic compounds. Compared with fluorinated aromatic compounds, fluorinated aromatic compounds have excellent properties in the fields of medicine and pesticides, such as low dosage, low toxicity, high efficacy, and strong metabolic capacity, and are widely used.

Synthesis

2-CHLORO-3-NITROTOLUENE

3970-40-9

2-Fluoro-3-nitrotoluene

437-86-5

Cesium fluoride (97.5 g, 642 mmol) was added to a solution of 2-chloro-1-methyl-3-nitrobenzene (73.4 g, 428 mmol) in dimethyl sulfoxide (DMSO, 185 mL) under nitrogen protection. The reaction mixture was stirred at 140 °C for 10 hours. Upon completion of the reaction, the mixture was slowly poured into 0.5 N hydrochloric acid and extracted twice with ethyl acetate. The organic phases were combined, washed with saturated brine and dried over anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give the crude product. The crude product was purified by reduced pressure distillation (boiling point: 118-122 °C/15 mmHg) to give 2-fluoro-3-nitrotoluene (54.4 g, 82% yield) as a yellow oil.1H NMR (DMSO-d6, 270 MHz) δ (ppm): 7.96 (m, 1H), 7.73 (m, 1H), 7.34 (t, J = 8.2 Hz, 1H), 2.35 (t, J = 8.2 Hz, 1H), 2.35 (t, J = 8.2 Hz, 1H), 2.35 (t, J = 8.2 Hz, 1H). 1H), 2.35 (d, J = 2.4 Hz, 3H). Intersil C18 (ODS, 5 μm, 4.6 mm ID × 50 mm, GL Sciences) or SunFire C18 (ODS, 5 μm, 4.6 mm ID × 50 mm, Waters); mobile phases: water (A) containing 0.05% trifluoroacetic acid and acetonitrile (B) containing 0.05% trifluoroacetic acid; elution method: gradient elution ( Solvent B was raised from 10% to 95% in 3.5 min, then lowered to 10% in 1 min, holding 10% B for 0.5 min); Flow rate: 4.0 mL/min.

References

[1] Patent: EP1982982, 2008, A1. Location in patent: Page/Page column 196
[2] Patent: EP2172198, 2010, A1
[3] ACS Medicinal Chemistry Letters, 2013, vol. 4, # 11, p. 1059 - 1063
[4] Patent: KR101511396, 2015, B1. Location in patent: Paragraph 2861-2865

3970-40-9
437-86-5
Synthesis of 2-Fluoro-3-nitrotoluene from 2-CHLORO-3-NITROTOLUENE

2-Fluoro-3-nitrotoluene Preparation Products And Raw materials

Global( 331)Suppliers
Supplier Tel Email Country ProdList Advantage
Fluoropharm Co., Ltd.
+86-0571-85586753 +86-13336034509 sales@fluoropharm.com China 1445 60
Aceschem Inc.
+1-817863-6948 +1-（817）863-6948 sales@aceschem.com United States 19632 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-81139210 +86-18192627656 1059@dideu.com China 3587 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20122 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29640 60
Hi-Tech Chemistry Corp 		0519-86626038 yuhh@hitechem.com CHINA 810 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Shenzhen Nexconn Pharmatechs Ltd 		+86-755-89396905 +86-15013857715 admin@nexconn.com China 10403 58
Jinan Finer Chemical Co., Ltd 		+86-531-88989536 +86-15508631887 sales@finerchem.com China 2950 58

View Lastest Price from 2-Fluoro-3-nitrotoluene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Fluoro-3-nitrotoluene pictures 2026-05-21 2-Fluoro-3-nitrotoluene
437-86-5
 $5.00 1kg ≥98% 100mt/year Jinan Finer Chemical Co., Ltd
2-Fluoro-3-nitrotoluene pictures 2025-12-12 2-Fluoro-3-nitrotoluene
437-86-5
 $1.00-100.00 1KG 99% 300KG Shaanxi Dideu Medichem Co. Ltd
2-Fluoro-3-nitrotoluene pictures 2025-09-25 2-Fluoro-3-nitrotoluene
437-86-5
 $1.00-200.00 1KG 99%, 99.5% Sublimated Henan Fengda Chemical Co., Ltd

2-Fluoro-3-nitrotoluene Spectrum

2-Fluoro-3-nitrotluene 2-fluoro-3-Nitrotoluol 2-Fluoro-3-methylnitrobenzene, 2-Fluoro-1-methyl-3-nitrobenzene 2-Fluoro-3-maethylnitrobenzene 2-fluoro-3-methylnitrobenzene 2-FLUORO-3-NITROTOLUENE 2-Fluoro-3-nitrotoluene> Benzene, 2-fluoro-1-methyl-3-nitro- 2-Fluoro-1-methyl-3-nitrobenzece 2-Fluoro-3-nitrotoluen 2-FLUORO-1-METHYL-3-NITR 2-Fluoro-3-methylnitrobenzene,2-Fluoro-1-methyl-3-nitroChemicalbookbenzene 2-FLUORO-1-METHYL-3-NITROBENZENE 437-86-5 Aromatic Hydrocarbons (substituted) & Derivatives Fluorinated benzene series Fluorin-contained toluene series Halogen toluene
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