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ChemicalBook >> CAS DataBase List >>Tetramethoxymethane

Tetramethoxymethane

CAS No.
1850-14-2
Chemical Name:
Tetramethoxymethane
Synonyms
TETRAMETHYL ORTHOCARBONATE;NSC 359558;Dimethoxymethylal;TETRAMETHOXYMETHANE;Methane, tetramethoxy-;Tetramethyl orthocarbonate 98%;Orthocarbonic acid, tetramethyl ester
CBNumber:
CB6746771
Molecular Formula:
C5H12O4
Molecular Weight:
136.15
MDL Number:
MFCD00008473
MOL File:
1850-14-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:44:31
Product description Number Pack Size Price
Tetramethyl orthocarbonate 98% 132624 5g $190
Tetramethyl orthocarbonate 98% 132624 25g $673
Tetramethoxymethane >97.0%(GC) T1045 5g $319
Tetramethoxymethane >97.0%(GC) T1045 25g $1275
Tetramethoxymethane TRC-T298860-5G 5g $179
More product size

Tetramethoxymethane Properties

Melting point -5 °C (lit.)
Boiling point 114 °C (lit.)
Density 1.023 g/mL at 25 °C (lit.)
refractive index n20/D 1.385(lit.)
Flash point 44 °F
storage temp. Refrigerator
solubility Chloroform, Ethyl Acetate, Methanol
form Liquid
color Colorless
Sensitive Moisture Sensitive
BRN 1737682
InChI InChI=1S/C5H12O4/c1-6-5(7-2,8-3)9-4/h1-4H3
InChIKey AHJWSRRHTXRLAQ-UHFFFAOYSA-N
SMILES C(OC)(OC)(OC)OC
CAS DataBase Reference 1850-14-2(CAS DataBase Reference)
FDA UNII FHC4GZ2SYJ
NIST Chemistry Reference Tetramethoxymethane(1850-14-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  26-37
RIDADR  UN 3272 3/PG 2
WGK Germany  3
21
HS Code  2909.19.6000
HazardClass  3.1
PackingGroup  II
Storage Class 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
3
2 0

Tetramethoxymethane price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 132624 Tetramethyl orthocarbonate 98% 1850-14-2 5g $190 2026-04-30 Buy
Sigma-Aldrich 132624 Tetramethyl orthocarbonate 98% 1850-14-2 25g $673 2026-04-30 Buy
TCI Chemical T1045 Tetramethoxymethane >97.0%(GC) 1850-14-2 5g $319 2026-04-30 Buy
TCI Chemical T1045 Tetramethoxymethane >97.0%(GC) 1850-14-2 25g $1275 2026-04-30 Buy
TRC TRC-T298860-5G Tetramethoxymethane 1850-14-2 5g $179 2026-06-03 Buy
Product number Packaging Price Buy
132624 5g $190 Buy
132624 25g $673 Buy
T1045 5g $319 Buy
T1045 25g $1275 Buy
TRC-T298860-5G 5g $179 Buy

Tetramethoxymethane Chemical Properties,Uses,Production

Description

Tetramethoxymethane can be usede in CO2 fixation, formation of orthocarbonates from diols and electrophilic introduction of an ester functionality.

Uses

Tetramethoxymethane has application within an electrolyte solution for the use of rechargeable lithium batteries. It has also been used as a reactant in the synthesis of novel anti-HIV-1 compounds.

Synthesis

Tetramethoxymethane has been prepared by heating a solution of Sodium Methoxide in methanol with chloropicrin, Trichloroacetonitrile, or thiocarbonyl perchlorate; the best yields have been obtained with the perchlorate. Alternatively, disodium hexamethoxystannate (prepared in situ from sodium methoxide and tetrachlorostannane) can be refluxed with Carbon Disulfide in methanol to form the orthocarbonate.

Purification Methods

Tetramethyl orthocarbonate (methyl orthocarbonate, tetramethoxy methane) [1850-14-2] M 136.2, m -5.6o, -5o, -2o, b 113.5o/760mm, 113.5 -114o/755mm, 112-114o/atm, d 4 1.0202, n D 1.3860. Purify it in the same way as for tetraethyl orthocarbonate. [Smith Acta Chem Scand 10 1006 1956, Tiekelmann & Post J Org Chem 13 266 1948, Kantlehner et al. Synthesis 73 1977, Beilstein 3 IV 4.]

67-56-1
1850-14-2
Synthesis of Tetramethoxymethane from Methanol
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View Lastest Price from Tetramethoxymethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetramethoxymethane pictures 2019-12-20 Tetramethoxymethane
1850-14-2
$7.00 1KG 99% Career Henan Chemical Co
Tetramethyl orthocarbonate 98% Dimethoxymethylal NSC 359558 Orthocarbonic acid, tetramethyl ester Methane, tetramethoxy- TETRAMETHOXYMETHANE TETRAMETHYL ORTHOCARBONATE 1850-14-2 COCH34 Acetals/Ketals/Ortho Esters Organic Building Blocks Building Blocks Oxygen Compounds Acetals/Ketals/Ortho Esters Building Blocks Chemical Synthesis Organic Building Blocks Oxygen Compounds Acetals/Ketals/Ortho Esters Organic Building Blocks Oxygen Compounds
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