1-BROMO-2-(2,2-DIETHOXY-ETHYLSULFANYL)-BENZENE
- CAS No.
- 137105-52-3
- Chemical Name:
- 1-BROMO-2-(2,2-DIETHOXY-ETHYLSULFANYL)-BENZENE
- Synonyms
- (2-broMophenyl)(2,2-diethoxyethyl)sulfane;1-Bromo-2-[(2,2-diethoxyethyl)thio]benzene;Benzene, 1-broMo-2-[(2,2-diethoxyethyl)thio]-;1-BROMO-2-(2,2-DIETHOXY-ETHYLSULFANYL)-BENZENE;2-(2-bromophenylthio) acetaldehyde diethyl acetal
- CBNumber:
- CB7271636
- Molecular Formula:
- C12H17BrO2S
- Molecular Weight:
- 305.23
- MDL Number:
- MFCD06657717
- MOL File:
- 137105-52-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | AS49588 | 1g | $26 |
| (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | AS49588 | 5g | $111 |
| (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | B56182 | 1g | $146 |
| (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | B56182 | 5g | $190 |
| (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | B56182 | 10g | $380 |
| More product size | |||
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302 |
| Precautionary statements | P280-P305+P351+P338 |
1-BROMO-2-(2,2-DIETHOXY-ETHYLSULFANYL)-BENZENE price More Price(18)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Activate Scientific | AS49588 | (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | 137105-52-3 | 1g | $26 | 2026-06-04 | Buy |
| Activate Scientific | AS49588 | (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | 137105-52-3 | 5g | $111 | 2026-06-04 | Buy |
| Synthonix | B56182 | (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | 137105-52-3 | 1g | $146 | 2026-05-06 | Buy |
| Synthonix | B56182 | (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | 137105-52-3 | 5g | $190 | 2026-05-06 | Buy |
| Synthonix | B56182 | (2-Bromophenyl)(2,2-diethoxyethyl)sulfane 97% | 137105-52-3 | 10g | $380 | 2026-05-06 | Buy |
1-BROMO-2-(2,2-DIETHOXY-ETHYLSULFANYL)-BENZENE Chemical Properties,Uses,Production
Synthesis
6320-02-1
2032-35-1
137105-52-3
To a suspension of DMF (70 mL) containing K2CO3 (8.186 g, 59.23 mmol) was sequentially added 2-bromothiophenol (7.00 g, 37.02 mmol) and 2-bromoacetaldehyde diethyl acetal (7.821 g, 40.72 mmol). The reaction mixture was stirred at room temperature for 5 hours. After completion of the reaction, the mixture was partitioned between water (100 mL) and EtOAc (100 mL). The organic layer was separated and washed with distilled water (5 x 50 mL). The combined aqueous layers were back-extracted with EtOAc (100 mL). All organic layers were combined, dried with anhydrous MgSO4, filtered and concentrated under reduced pressure. The residue was purified by short-range vacuum distillation and the fractions were collected at 130-140 °C (0.2 mmHg) to afford (2-bromophenyl)(2,2-diethoxyethyl)thioalkane (10.42 g, 92% yield) as a colorless oil. The structure of the product was confirmed by 1H NMR (300 MHz, CDCl3) and 13C NMR (75 MHz, CDCl3).1H NMR (300 MHz, CDCl3) δ 7.51 (dd, J = 7.9,1.3 Hz, 1H), 7.34 (dd, J = 7.9,1.5 Hz, 1H), 7.26-7.20 (m, 1H) , 7.04-6.97 (m, 1H), 4.69 (t, J = 5.5 Hz), 3.69 (dq, J = 9.2,7.0 Hz, 2H), 3.56 (dq, J = 9.2,7.0 Hz, 2H), 3.14 (d, J = 5.5 Hz, 2H), 1.20 (t, J = 7.0 Hz, 6H).13C NMR ( 75 MHz, CDCl3) δ 137.7,133.0,128.8,127.7,126.8,123.8,101.63,62.4,37.0,15.5.
References
[1] Chemistry - A European Journal, 2015, vol. 21, # 35, p. 12303 - 12307
[2] Bioorganic and Medicinal Chemistry, 2015, vol. 23, # 14, p. 3933 - 3937
[3] Patent: US6436964, 2002, B1
[4] Patent: US6465453, 2002, B1
[5] Patent: US6353008, 2002, B1. Location in patent: Page column 25-26
1-BROMO-2-(2,2-DIETHOXY-ETHYLSULFANYL)-BENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131956 | 58 |
| Nanjing JinruiJiuAn Biotechnology Co., Ltd. | 025-58196018 800028039 | sales@fartop.net | China | 2229 | 55 |
| Nanjing River Chemical Co., Ltd. | 13951936332 18305166317 | info@serpharm.com | China | 493 | 55 |
| Aikon International Limited | 025-58851090 15955137747 | sales01@aikonchem.com | China | 15949 | 58 |
| 3A Chemicals | 400-668-9898 | service@3achem.com | China | 20557 | 58 |
| Shanghai Jizhi Biochemical Technology Co. Ltd. | 021-4009004166/18616739031 18616739031 | 3007523370@qq.com | China | 52678 | 58 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing@energy-chemical.com | China | 44918 | 58 |
| Shanghai Sunway Pharmaceutical Technology Co.,Ltd. | 13611835272 13611835272 | mmwang@sunwaypharm.com | China | 44107 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | 029-81024372 17792795018 | 1053@dideu.com | China | 9996 | 58 |
| Bide Pharmatech Ltd. | 400-6005915 | sales@picasso-e.com | China | 39653 | 58 |
