ChemicalBook >> CAS DataBase List >>METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE structure

CAS No.: 6203-08-3

Chemical Name:: METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE

Synonyms: Bicycl;Methyl Bicyclo[2.2.;ate (endo- and exo- mixture);METHYL 5-NORBORNENE-2-CARBOXYLATE;5-NORBORNENE-2-CARBOXYLIC METHYL ESTER;Methyl 5-Norbornene-2-carboxylate 5-Norbonene-2-carboxylic acid Methyl ester;5-NORBORNENE-2-CARBOXYLIC ACID METHYL ESTER;Norborn-5-ene-2-carboxylic acid methyl ester;Norborna-2-ene-5-carboxylic acid methyl ester

CBNumber:: CB7431061

Molecular Formula:: C9H12O2

Molecular Weight:: 152.19

MDL Number:: MFCD00167592

MOL File:: 6203-08-3.mol

MSDS File:: SDS

Last updated:2026-05-28 03:29:31

Product description	Number	Pack Size	Price
Methyl 5-norbornene-2-carboxylate mixture of endo and exo, predominantly endo, 95%	764361	1g	$112
Methyl 5-Norbornene-2-carboxylate (endo- and exo- mixture) >96.0%(GC)	N0691	25g	$198
Methyl 5-norbormene-2-carboxylate Asreported	283237	5g	$359
Methyl 5-norbormene-2-carboxylate Asreported	283237	10g	$496
Methyl 5-norbormene-2-carboxylate Asreported	283237	25g	$761
More product size

Request For Quotation

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE Properties

Boiling point	70-71 °C(Press: 12 Torr)
Density	1.06
refractive index	1.4720 to 1.4770
Flash point	68°C
storage temp.	Storage temp. 2-8°C
form	clear liquid
color	Colorless to Light yellow to Light orange
InChI	InChI=1S/C9H12O2/c1-11-9(10)8-5-6-2-3-7(8)4-6/h2-3,6-8H,4-5H2,1H3
InChIKey	RMAZRAQKPTXZNL-UHFFFAOYSA-N
SMILES	C12CC(C=C1)CC2C(OC)=O
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H227

Precautionary statements

P501-P210-P264-P280-P302+P352-P370+P378-P337+P313-P305+P351+P338-P362+P364-P332+P313-P403+P235

Hazard Codes

Risk Statements

RIDADR

NA 1993 / PGIII

WGK Germany

HS Code

2917200090

Storage Class

10 - Combustible liquids

Hazard Classifications

Acute Tox. 4 Oral

NFPA 704

	0
1		0

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE price More Price(39)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	764361	Methyl 5-norbornene-2-carboxylate mixture of endo and exo, predominantly endo, 95%	6203-08-3	1g	$112	2023-06-20	Buy
TCI Chemical	N0691	Methyl 5-Norbornene-2-carboxylate (endo- and exo- mixture) >96.0%(GC)	6203-08-3	25g	$198	2026-04-30	Buy
Usbiological	283237	Methyl 5-norbormene-2-carboxylate Asreported	6203-08-3	5g	$359	2026-06-03	Buy
Usbiological	283237	Methyl 5-norbormene-2-carboxylate Asreported	6203-08-3	10g	$496	2026-06-03	Buy
Usbiological	283237	Methyl 5-norbormene-2-carboxylate Asreported	6203-08-3	25g	$761	2026-06-03	Buy

Product number	Packaging	Price	Buy
764361	1g	$112	Buy
N0691	25g	$198	Buy
283237	5g	$359	Buy
283237	10g	$496	Buy
283237	25g	$761	Buy

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE Chemical Properties,Uses,Production

Industrial uses

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE can be used in perfume compositions.

Synthesis

542-92-7

292638-85-8

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE

6203-08-3

0.510 mol (68.0 g) of anhydrous aluminum chloride was suspended in 660 mL of toluene. 0.600 mol (51.7 g) methyl acrylate was added to the suspension and stirred until the aluminum chloride was completely dissolved. A solution of 0.600 mol (39.7 g) of freshly cleaved cyclopentadiene dissolved in 340 mL of toluene was added dropwise to the solution over 45 minutes. The reaction mixture was stirred at room temperature for 90 minutes and subsequently poured into water. The toluene layer was separated, washed with water, dried over anhydrous sodium sulfate, filtered and concentrated to dryness under reduced pressure. Purification by vacuum distillation on a Vigreux column afforded methyl 5-norbornene-2-carboxylate in 66.3 g (74%) yield and 99% purity (GC). 5-Norbornene-2-carboxylic acid was prepared by mixing 164 mmol (25.0 g) of methyl ester with 85 g of 10% NaOH solution at 60°C until the ester layer disappeared. After cooling, it was washed with ether and acidified with 235 mL of 1 M hydrochloric acid at 60-70°C with stirring. The acid layer was separated, dissolved in ethyl acetate, washed with water, dried over anhydrous sodium sulfate, filtered and concentrated to dryness under reduced pressure to yield 18.2 g (80%).1H and 13C NMR confirmed the product as 5-norbornene-2-carboxylic acid. 132 mmol (18.2 g) of the acid was dissolved in 480 mL of dichloromethane and 2.66 mmol (0.205 mL) of N,N-dimethylformamide and 665 mmol (57.0 mL) of oxaloyl chloride were added dropwise over 1 hr. Stirred at room temperature for 1.5 h. The solvent and excess oxalyl chloride were removed by evaporation under reduced pressure to give a brown oil in a yield of 18.1 g (88%). 115 mmol (18.0 g) of chloroyl chloride was added to a mixture of diethylene glycol (57.5 mmol, 6.10 g) and pyridine (115 mmol, 9.09 g) and stirred at room temperature for 4 hours. 150 mL of dichloromethane and 100 mL of water were added, the organic layer was washed sequentially with water, sodium bicarbonate solution and hydrochloric acid solution, dried over anhydrous sodium sulfate, filtered, and concentrated to dryness to give a yellow oil in a yield of 18.9 g (95%).1H and 13C NMR showed that the product was predominantly a diester. Diethylene glycol di(5,6-epoxy-2-norbornanecarboxylate) was prepared by dissolving 54.5 mmol (18.9 g) of the diester in 260 mL of dichloromethane. Another 15.3 mmol (2.08 g) of sodium acetate trihydrate was dissolved in a 39% peracetic acid solution of acetic acid (153 mmol, 29.8 g) and added dropwise to the diester solution over 30 minutes. The reaction mixture was stirred at room temperature for 4 h. The reaction mixture was washed with water and sodium bicarbonate solution, the organic phase was dried over anhydrous sodium sulfate, filtered, and concentrated to dryness to give light yellow oily diethylene glycol bis(5,6-epoxy-2-norbornanecarboxylate) in a yield of 19.8 g (96%) and purity of 94% (GC). The structure of the product was confirmed by 1H and 13C NMR.

References

[1] European Journal of Inorganic Chemistry, 2005, # 4, p. 676 - 684
[2] Tetrahedron Letters, 2005, vol. 46, # 28, p. 4753 - 4756
[3] Tetrahedron Letters, 2004, vol. 45, # 25, p. 4943 - 4946
[4] Tetrahedron Letters, 2006, vol. 47, # 23, p. 3957 - 3958
[5] Tetrahedron Letters, 1990, vol. 31, # 44, p. 6303 - 6306

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

1,3-Cyclopentadiene acrylic acid methyl ester Toluene Aluminum chloride

Preparation Products

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE Suppliers

Global( 126)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569262 +86-15003564040	1056@dideu.com	China	3970	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20122	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14014	58
AB PharmaTech,LLC	323-480-4688	sales@acrospharmatech.com	United States	989	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29815	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Puyang Huicheng Electronic Materials Co., Ltd.	+86-0393-+86-0393-8910800 +8615839383373	info@huichengchem.com	China	530	58
Neostar United (Changzhou) Industrial Co., Ltd.	+86-0519-85551759 +8613506123987	marketing1@neostarunited.com	China	8828	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
AB PharmaTech,LLC	55
career henan chemical co	58
Alchem Pharmtech,Inc.	58
Puyang Huicheng Electronic Materials Co., Ltd.	58
Neostar United (Changzhou) Industrial Co., Ltd.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-06-04	Methyl 5-Norbornene-2-carboxylate(endo- and exo- mixture) 6203-08-3		1g	≥96%	500KG	Henan Research New Materials Co., Ltd.
2026-02-02	trans-2-methylcyclopropanecarboxylic acid 6203-08-3		1KG	99%	2000tons	Shaanxi Dideu Medichem Co. Ltd
2025-09-25	Methyl bicyclo[2.2.1]hept-5-ene-2-carboxylate 6203-08-3	$1.00-200.00	1KG	99%, 99.5% Sublimated		Henan Fengda Chemical Co., Ltd

Methyl 5-Norbornene-2-carboxylate(endo- and exo- mixture)
6203-08-3
$0.00
≥96%
Henan Research New Materials Co., Ltd.

trans-2-methylcyclopropanecarboxylic acid
6203-08-3
99%
Shaanxi Dideu Medichem Co. Ltd

Methyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
6203-08-3
$1.00-200.00
99%, 99.5% Sublimated
Henan Fengda Chemical Co., Ltd

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE Spectrum

METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE(6203-08-3)¹HNMR

6203-08-3(METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE)Related Search:

tert-Butyl 5-norbornene-2-carboxylate ETHYL 5-NORBORNENE-2-CARBOXYLATE (MIXTURE OF ENDO AND EXO) 5-Norbornene-2-carbonitrile Bicyclo[1.1.1]pentane-1,3-dicarboxamide Bicyclo[1.1.1]pentane-1-sulfonamide

Norcamphor, dehydro- bicyclo[1.1.1]pentane-1,3-dicarbonitrile 4-Hydroxymethylbenzocyclobutene Bicyclo[6.1.0]non-4-yne-9-methanol Bicyclo[1.1.1]pentane-1-carboxylic acid, methyl ester (9CI)

bicyclo[3.2.1]octane-2,4-dione 5-Norbornene-2-carboxamide Bicyclo[2.2.2]octane-1,4-dimethanol Bicyclo[1.1.1]pentane-1,3-dicarboxylic acid, MonoMethyl ester BICYCLO[2.2.1]HEPTANE-2-CARBOXYLIC ACID

2,3-NORBORNANEDICARBOXYLIC ACID Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride bicyclo[2.2.2]oct-5-ene-2,3-dicarboxylic anhydride

1of4

METHYL 8,9,10-TRINORBORNA-5-ENE-2-CARBOXYLATE METHYL BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLATE METHYL 5-NORBORNENE-2-CARBOXYLATE BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLIC ACID METHYL ESTER 8,9,10-TRINORBORNA-5-ENE-2-CARBOXYLIC ACID METHYL ESTER 5-NORBORNENE-2-CARBOXYLIC ACID METHYL ESTER 5-NORBORNENE-2-CARBOXYLIC METHYL ESTER Methyl 5-Norbornene-2-carboxylate (endo- and exo- mixture) Bicyclo[2.2.1]hepta-5-ene-2-carboxylic acid methyl ester Norborn-5-ene-2-carboxylic acid methyl ester Norborna-2-ene-5-carboxylic acid methyl ester Methyl Bicyclo[2.2. 5-Norbonene-2-carboxylic acid Methyl ester Bicyclo[2.2.1]hept-5-ene-2-carboxylic Acid Methyl Ester Methyl Bicyclo[2.2.1]hept-5-ene-2-carboxylate Methyl 8,9,10-Trinorborna-5-ene-2-carboxylate 5-Norbornene-2-carboxylic Acid Methyl Ester 8,9,10-Trinorborna-5-ene-2-carboxylic Acid Methyl Ester Methyl 5-Norbornene-2-carboxylate Methyl 5-Norbornene-2-carboxylate (endo- and exo- Mixture), 96.0%,(GC) 5-Norbornene-2-carboxylic methyl ester,mixture of endo and exo Bicycl Methyl5-Norbornene-2-carboxylate(endo-andexo-mixture)> ate (endo- and exo- mixture) biscyclo[2.2.1]heptyl-5-ene-2-carboxylic acidmethyl ester 6203-08-3 6203-8-3 Norbornene Derivatives

一二三四区视频,亚洲少妇熟女色,日本久热无码视频网,欧美国产日韩大尺度,亚洲a视频,久久少妇一区二区,日韩999无码视频,刺激久久久久久久,啊啊啊啊不要啊在线