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ChemicalBook >> CAS DataBase List >>1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE

1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE

CAS No.
121954-50-5
Chemical Name:
1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE
Synonyms
phosphino)methyL;1,2-Bis((di-tert-butyL;1,2-Dibutylphosphinomethyl-benzene;Bis(di-tert-butylphosphino)-o-xylene;α,α'-bis(di-t-butylphosphino)-o-xylene;α,α'-Bis(di-t-butylphosphino)-o-xylene,;1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BE&;α,α'-Bis(di-t-butylphosphino)-o-xylene,96%;,2-Bis(di-tert-butylphosphinomethyl)benzene;1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE
CBNumber:
CB7721803
Molecular Formula:
C24H44P2
Molecular Weight:
394.55
MDL Number:
MFCD03094573
MOL File:
121954-50-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:58:47
Product description Number Pack Size Price
1,2-Bis(di-tert-butylphosphinomethyl)benzene 631922 1g $149
1,2-Bis(di-tert-butylphosphinomethyl)benzene 631922 5g $533
α,α'-Bis(di-t-butylphosphino)-o-xylene, min. 97% min.97% 15-0072 500mg $98
α,α'-Bis(di-t-butylphosphino)-o-xylene, min. 97% min.97% 15-0072 2g $292
1,2-Bis((di-tert-butylphosphino)methyl)benzene 098741 250.00mg $175
More product size

1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Properties

Melting point 59-62°C
Boiling point 456.7±38.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color white
Sensitive air sensitive
InChI InChI=1S/C24H44P2/c1-21(2,3)25(22(4,5)6)17-19-15-13-14-16-20(19)18-26(23(7,8)9)24(10,11)12/h13-16H,17-18H2,1-12H3
InChIKey SFCNPIUDAIFHRD-UHFFFAOYSA-N
SMILES C1C=C(CP(C(C)(C)C)C(C)(C)C)C(CP(C(C)(C)C)C(C)(C)C)=CC=1
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
Storage Class 11 - Combustible Solids

1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 631922 1,2-Bis(di-tert-butylphosphinomethyl)benzene 121954-50-5 1g $149 2026-04-30 Buy
Sigma-Aldrich 631922 1,2-Bis(di-tert-butylphosphinomethyl)benzene 121954-50-5 5g $533 2026-04-30 Buy
Strem Chemicals 15-0072 α,α'-Bis(di-t-butylphosphino)-o-xylene, min. 97% min.97% 121954-50-5 500mg $98 2026-04-30 Buy
Strem Chemicals 15-0072 α,α'-Bis(di-t-butylphosphino)-o-xylene, min. 97% min.97% 121954-50-5 2g $292 2026-04-30 Buy
Matrix Scientific 098741 1,2-Bis((di-tert-butylphosphino)methyl)benzene 121954-50-5 250.00mg $175 2026-05-18 Buy
Product number Packaging Price Buy
631922 1g $149 Buy
631922 5g $533 Buy
15-0072 500mg $98 Buy
15-0072 2g $292 Buy
098741 250.00mg $175 Buy

1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Chemical Properties,Uses,Production

Uses

DTBPMB may be used as a ligand for the palladium-catalyzed hydroesterification of styrene and vinyl acetate to form branched esters in the presence of polymeric sulfonic acids promoters.

General Description

1,2-Bis(di-tert-butylphosphinomethyl)benzene (DTBPMB) is a bidentate phosphine ligand. DTBPMB in combination with Pd2(dba)3 (dba = trans,trans-dibenzylideneacetone) and a sulfonic acid can catalyze the methoxycarbonylation of ethane to form methyl propanoate.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 101)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +86-16627710726 sales@runvmat.com China 464 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21531 55
CONIER CHEM AND PHARMA LIMITED
sales@conier.com China 49906 58
career henan chemical co
+86-0371-86658258 factory@coreychem.com China 29780 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81139210 17389186172 1077@dideu.com China 3999 58
Shanghai UCHEM Inc.
+86-18930848214 +86-021-56762820 sales@myuchem.com China 8899 58
Xi'an MC Biotech, Co., Ltd.
029-89275612 +8618991951683 mcbio_sales@163.com China 2240 58
Henan Research New Materials Co., Ltd.
+86-18903931628 +86-18903931531 sales036@researchvip.com China 304 58
CD Chemical Group Limited
+86-13651442114 info@codchem.com China 17253 58
Henan Alfa Chemical Co., Ltd
+8618339805032 sale03@alfachem.cn China 9811 58

View Lastest Price from 1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,2-Bis(di-tert-butylphosphinomethyl)benzene  pictures 2026-08-07 1,2-Bis(di-tert-butylphosphinomethyl)benzene
121954-50-5
$1.00 1KG 99% 50 tons Shaanxi Dideu Medichem Co. Ltd
1,2-Bis(di-t-butylphosphinomethyl)benzene pictures 2025-12-23 1,2-Bis(di-t-butylphosphinomethyl)benzene
121954-50-5
1kg 98% 500kg XINXIANG RUNYU MATERIAL CO., LTD.
1,2-Bis(di-tert-butylphosphinomethyl)benzene pictures 2021-07-02 1,2-Bis(di-tert-butylphosphinomethyl)benzene
121954-50-5
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
alpha:,alpha:'-Bis(di-t-butylphosphino)-o-xylene, min. 97% α,α'-bis(di-t-butylphosphino)-o-xylene a,a'-Bis(di-t-butylphosphino)-o-xylene, min. 97% 1,2-Bis(di-t-butylphosphinoMethyl)benzene, 98% 1,2-Bis(di-t-butylphosphinoMethyl)benzene, 97+% α,α'-Bis(di-t-butylphosphino)-o-xylene, min. 97% α,α'-Bis(di-t-butylphosphino)-o-xylene,96% ALPHA, ALPHA'-BIS(DI-T-BUTYLPHOSPHINO)-O-XYLENE 1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Α,Α'-BIS(DI-T-BUTYLPHOSPHINO)-O-XYLENE,MIN.97% 1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BE& Bis(di-tert-butylphosphino)-o-xylene ALPHA, ALPHA'-BIS-(DI-TERT-BUTYLPHOSPHINO)-O-XYLENE alpha,alpha'-Bis(di-t-butylphosphino)-o-xylene,min.97% "DI-TERT-BUTYL({2-[(DI-TERT-BUTYLPHOSPHANYL)METHYL]PHENYL}METHYL)PHOSPHANE ,2-Bis(di-tert-butylphosphinomethyl)benzene 1,2-Bis(di-tert-butylphosphinomethyl)benzene,98% phosphino)methyL 1,2-Bis((di-tert-butyL 1,2-bis((di-tert-butylphosphanyl)methyl)benzene Phosphine, 1,1'-[1,2-phenylenebis(methylene)]bis[1,1-bis(1,1-dimethylethyl)- α,α'-Bis(di-t-butylphosphino)-o-xylene, itert-butyl-[[2-(ditert-butylphosphanylmethyl)phenyl]methyl]phosphane 1,2-Bis(di-tert-butylphosphinomethyl)benzene 1,2-Dibutylphosphinomethyl-benzene 121954-50-5 C6H4CH2PCCH322 C24H44P2 Polydentate Phosphine Ligands Phosphorus Compounds Catalysis and Inorganic Chemistry Polydentate Phosphine Ligands Phosphorus Compounds Catalysis and Inorganic Chemistry Aryl Phosphine Achiral Phosphine
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