ChemicalBook >> CAS DataBase List >>1,1'-Bis(diisopropylphosphino)ferrocene
1,1'-Bis(diisopropylphosphino)ferrocene
- CAS No.
- 97239-80-0
- Chemical Name:
- 1,1'-Bis(diisopropylphosphino)ferrocene
- Synonyms
- DIPPF;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(diisopropylphosphino)ferrocene,98%
- CBNumber:
- CB8105732
- Molecular Formula:
- C22H36FeP210*
- Molecular Weight:
- 418.31
- MDL Number:
- MFCD02684559
- MOL File:
- 97239-80-0.mol
- MSDS File:
- SDS
Last updated:2026-05-28 04:31:13
| Product description | Number | Pack Size | Price |
| 1,1′-Bis(diisopropylphosphino)ferrocene 97% | 578266 | 500mg | $209 |
| 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) | B2710 | 1g | $144 |
| 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) | B2710 | 100mg | $38 |
| 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF min.98% | 26-0275 | 500mg | $62 |
| 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF min.98% | 26-0275 | 2g | $181 |
| More product size | |||
| Melting point | 50-52 °C(lit.) |
|---|---|
| Flash point | >230 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder |
| color | orange-yellow |
| Water Solubility | Insoluble in water. |
| InChI | InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3; |
| InChIKey | LPBBEMRSRONKMN-UHFFFAOYSA-N |
| SMILES | P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23| |
| CAS DataBase Reference | 97239-80-0(CAS DataBase Reference) |
| UNSPSC Code | 12350000 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P305+P351+P338-P304+P340-P405-P501A | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
1,1'-Bis(diisopropylphosphino)ferrocene price More Price(58)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 578266 | 1,1′-Bis(diisopropylphosphino)ferrocene 97% | 97239-80-0 | 500mg | $209 | 2026-04-30 | Buy |
| TCI Chemical | B2710 | 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) | 97239-80-0 | 1g | $144 | 2026-04-30 | Buy |
| TCI Chemical | B2710 | 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) | 97239-80-0 | 100mg | $38 | 2026-04-30 | Buy |
| Strem Chemicals | 26-0275 | 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF min.98% | 97239-80-0 | 500mg | $62 | 2026-04-30 | Buy |
| Strem Chemicals | 26-0275 | 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF min.98% | 97239-80-0 | 2g | $181 | 2026-04-30 | Buy |
1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties,Uses,Production
Reaction
- Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
- Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
- Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
- Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
- Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
- Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
- Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
Description
1,1′-Bis(diisopropylphosphino)ferrocene (DiPPF) is a ferrocene-based phosphine ligand frequently is used in electrochemical reaction studies. DiPPF can help support high oxidation states of metal atoms by forming iron interactions and donating electrons via low-energy charge transfer from iron to nickel atoms.
Chemical Properties
orange crystalline powder
Uses
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 182)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Research New Materials Co., Ltd. | +86-18903931628 +86-18903931531 | sales036@researchvip.com | China | 302 | 58 |
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 459 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 | jiuyitime@fdachem.com | China | 16512 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5742 | 58 |
| Longyan Tianhua Biological Technology Co., Ltd | 0086 18039857276 18039857276 | CHINA | 2783 | 58 |
View Lastest Price from 1,1'-Bis(diisopropylphosphino)ferrocene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-06-08 | 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
|
1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
 |
2026-06-04 | 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
|
1Kg | 98％ | 100kg | Henan Research New Materials Co., Ltd. | ||
 |
2026-04-17 | 1,1'-bis-(di-Isopropylphosphino)ferrocene
97239-80-0
|
$2.00-6.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD |
-
- 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
- $0.00
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
- 98％
- Henan Research New Materials Co., Ltd.
-
- 1,1'-bis-(di-Isopropylphosphino)ferrocene
97239-80-0
- $2.00-6.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
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1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF
1,1'-Bis(di-i-propylphosphino)f
1,1'-Bis(diisopropylphosphino)ferrocene>
1,1'-Bis(diisopropyL
1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE ISO 9001：2015 REACH
bis(2-diisopropylphosphanylcyclopenta-1,3-dien-1-yl)iron
1,1'-bis-(di-Isopropylphosphino)ferrocene
1,1′-Bis(diisopropylphosphino)ferrocene, CAS 97239-80-0
1,1'-Bis(di-i-propylphosphino)ferrocene
DIPPF
97239-80-0
97239-80-8
C22H36FeP210
C22H36FeP2
2C11H18PFe
Phosphine Ligands
Ferrocenes
Metallocenes
Polydentate Phosphine Ligands
Phosphorus Compounds
Catalysis and Inorganic Chemistry
Achiral Phosphine
Aryl Phosphine
Ligand
Ferrocenes
Metallocenes
Phosphine Ligands
Synthetic Organic Chemistry
Catalysis and Inorganic Chemistry
Phosphorus Compounds
Polydentate Phosphine Ligands
