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ChemicalBook >> CAS DataBase List >>Pinacol vinylboronate

Pinacol vinylboronate

CAS No.
75927-49-0
Chemical Name:
Pinacol vinylboronate
Synonyms
4,4,5,5-TETRAMETHYL-2-VINYL-1,3,2-DIOXABOROLANE;VINYLBORONIC ACID PINACOL ESTER;2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Picol vinylborote;boronic acid pinacoL;Vinylboronic acid pinacol cyclic ester;AKOS BRN-0470;inacol vinylboronate;PINACOL VINYLBORONATE;VINYLBORONIC ACID PINACOL ESTE
CBNumber:
CB8399917
Molecular Formula:
C8H15BO2
Molecular Weight:
154.01
MDL Number:
MFCD00192492
MOL File:
75927-49-0.mol
MSDS File:
SDS
Last updated:2026-05-28 04:54:46
Product description Number Pack Size Price
Vinylboronic acid pinacol ester contains phenothiazine as stabilizer, 95% 633348 1g $77.1
Vinylboronic acid pinacol ester contains phenothiazine as stabilizer, 95% 633348 10g $367
4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >93.0%(GC) T2297 1g $37
4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >93.0%(GC) T2297 5g $108
Pinacol vinylboronate Asreported 286629 1g $315
More product size

Pinacol vinylboronate Properties

Boiling point 52-54°C 24mm
Density 0.908 g/mL at 25 °C (lit.)
refractive index n20/D 1.4300(lit.)
Flash point 94 °F
storage temp. -20°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form Powder or Low Melting Solid
color White to yellow
Sensitive Air Sensitive
Stability Light Sensitive, Volatile
InChI InChI=1S/C8H15BO2/c1-6-9-10-7(2,3)8(4,5)11-9/h6H,1H2,2-5H3
InChIKey DPGSPRJLAZGUBQ-UHFFFAOYSA-N
SMILES O1C(C)(C)C(C)(C)OB1C=C
CAS DataBase Reference 75927-49-0(CAS DataBase Reference)
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)Environment (GHS09)
GHS02,GHS07,GHS09
Signal word  Warning
Hazard statements  H226-H317-H411
Precautionary statements  P210-P233-P240-P273-P280-P303+P361+P353
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  10-43
Safety Statements  16-36/37
RIDADR  UN 3272 3/PG 3
WGK Germany  3
TSCA  No
HazardClass  3
PackingGroup  III
HS Code  29319090
Storage Class 3 - Flammable liquids
Hazard Classifications Aquatic Chronic 2
Flam. Liq. 3
Skin Sens. 1
Limited Quantities 5.0 L (1.3 gallons) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
3
2 0

Pinacol vinylboronate price More Price(75)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 633348 Vinylboronic acid pinacol ester contains phenothiazine as stabilizer, 95% 75927-49-0 1g $77.1 2026-04-30 Buy
Sigma-Aldrich 633348 Vinylboronic acid pinacol ester contains phenothiazine as stabilizer, 95% 75927-49-0 10g $367 2026-04-30 Buy
TCI Chemical T2297 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >93.0%(GC) 75927-49-0 1g $37 2026-04-30 Buy
TCI Chemical T2297 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >93.0%(GC) 75927-49-0 5g $108 2026-04-30 Buy
Usbiological 286629 Pinacol vinylboronate Asreported 75927-49-0 1g $315 2026-06-03 Buy
Product number Packaging Price Buy
633348 1g $77.1 Buy
633348 10g $367 Buy
T2297 1g $37 Buy
T2297 5g $108 Buy
286629 1g $315 Buy

Pinacol vinylboronate Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to amber liquid

Uses

Reagent used for

  • Suzuki-Miyaura coupling reactions
  • Mizoroki-Heck reactions (cascade reaction)
  • Intramolecular Nozaki-Hiyama-Kishi reactions
  • Stereoselective Cu-catalyzed γ-selective and stereospecific coupling
  • Control of stereoselectivity and mechanistic portrait on intramolecular (4+1)-cycloaddition of dialkoxycarbenes
  • Regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes followed by Pd-catalyzed consecutive cross-coupling reactions
  • Asymmetric Birch reductive alkylation

Reagent used in Preparation of
  • Molecular tubes for lipid sensing
  • Enzymatic inhibitors, antibiotics, receptor analogs, and other biologically significant compounds (including total syntheses)

Uses

suzuki reaction

Synthesis

Pinacol

76-09-5

Boranediamine, 1-ethenyl-N,N,N',N'-tetrakis(1-methylethyl)- (9CI)

151293-63-9

Pinacol vinylboronate

75927-49-0

Under nitrogen protection, 193 g of pinacol and 14 g of 2,6-di-tert-butyl-4-methylphenol were added to a 1 L reaction flask and heated to 85-90 °C until the pinacol was completely melted. The intermediate reactants were added slowly dropwise, taking care to control the rate of dropwise acceleration. Subsequently, diisopropylamine was isolated by distillation using an atmospheric pressure steam distillation apparatus. Upon completion of the reaction, a colorless and transparent vinylboronic acid pinacol ester liquid product containing 225 g of the target product was obtained, which was analyzed by gas chromatography (GC) with a purity of 99.1% (excluding polymerization inhibitors).

References

[1] Patent: CN105503926, 2016, A. Location in patent: Paragraph 0018

74-85-1
25015-63-8
82954-89-0
75927-49-0
Synthesis of Pinacol vinylboronate from Ethylene and Pinacolborane
Global( 253)Suppliers
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Henan Fengda Chemical Co., Ltd
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Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
sales@conier.com China 49979 58

View Lastest Price from Pinacol vinylboronate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Pinacol vinylboronate pictures 2026-07-09 Pinacol vinylboronate
75927-49-0
$6.00-8.00 1kg 99% Henan Fengda Chemical Co., Ltd
Pinacol vinylboronate pictures 2021-07-13 Pinacol vinylboronate
75927-49-0
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
Pinacol vinylboronate pictures 2021-07-10 Pinacol vinylboronate
75927-49-0
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
2-Ethenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane Vinylboronic acid pinacolester, 10 wt.% solution in hexanes Pinacol vinylboronate Vinylboronic acid pinacol ester 2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaoborolane Vinylboronic acid pinacol ester(contains phenothiazine as stabilizer) 1,3,2-DIOXABOROLANE,2-ETHENYL-4,4,5,5-TETRAMETHYL- Vinylboronic acid pinacol ester, 97+%, stabilized with 0.05% BHT AKOS BRN-0470 PINACOL VINYLBORONATE 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, stabilized with 0.05% BHT, 97+% Vinylboronic acid pinacol ester, stabilized with 0.05% BHT, 97+% 2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,97+%,stabilized with 0.05% BHT inacol vinylboronate VINYLBORONIC ACID PINACOL ESTE 2-Ethenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolan Vinylboronic Acid Pinacol Ester (stabilized with Phenothiazine) Pinacol vinylboronate(stablized with PTZ) Vinylboronic acid pinacol ester (2.5-5% Phenothiozene stablizer) big discount Pinacol vinylboronate Picol vinylborote 2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Vinylboronic acid pinacol cyclic ester boronic acid pinacoL Vinylboronic acid picol cyclic ester 4,4,5,5-TETRAMETHYL-2-VINYL-1,3,2-DIOXABOROLANE VINYLBORONIC ACID PINACOL ESTER 75927-49-0 75957-49-0 C8H16BO3 B (Classes of Boron Compounds) Boronic Acids Esters B (Classes of Boron Compounds) Boronic Acids Esters CHIRAL CHEMICALS
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