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ChemicalBook >> CAS DataBase List >>(R)-DTBM-SEGPHOS

(R)-DTBM-SEGPHOS

CAS No.
566940-03-2
Chemical Name:
(R)-DTBM-SEGPHOS
Synonyms
DTBM-SEGPHOS;(R)-(-)-DTBM-SEGPHOS(regR);(R)-DTBM-SEGPHOS;(R)-DTBM-SEGPHOS(R);(R)-(-)-5,5'-Bis[di(3,5-di-t-butyL;(R)-DTBM-SEGPHOS?;(R)-(-)-DTBM-SEGPHOS®(R)-(-)-DTBM-SEGPHOS(regR)(R)-(-)-DTBM-SEGPHOS(regR);(R)-5,5'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole;5,5'-bis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino)-4,4'-bibenzo[d][1,3]dioxole
CBNumber:
CB91180975
Molecular Formula:
C74H100O8P2
Molecular Weight:
1179.55
MDL Number:
MFCD09753003
MOL File:
566940-03-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:50:38
Product description Number Pack Size Price
(R)-DTBM-SEGPHOS? 692484 100mg $53
(R)-DTBM-SEGPHOS? 692484 50mg $33.1
(R)-(-)-DTBM-SEGPHOS[R] >99.0%(HPLC) D4501 200mg $63
(R)-(-)-DTBM-SEGPHOS[R] >99.0%(HPLC) D4501 1g $172
(R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(-)-DTBM-SEGPHOS? min.98% 15-0066 250mg $48
More product size

(R)-DTBM-SEGPHOS Properties

Melting point 126-128°C
Boiling point 987.3±65.0 °C(Predicted)
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
color off-white
InChIKey ZNORAFJUESSLTM-UHFFFAOYSA-N
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H335-H319
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
WGK Germany  3
HS Code  2932.99.7000
Storage Class 11 - Combustible Solids

(R)-DTBM-SEGPHOS price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692484 (R)-DTBM-SEGPHOS? 566940-03-2 100mg $53 2026-04-30 Buy
Sigma-Aldrich 692484 (R)-DTBM-SEGPHOS? 566940-03-2 50mg $33.1 2023-06-20 Buy
TCI Chemical D4501 (R)-(-)-DTBM-SEGPHOS[R] >99.0%(HPLC) 566940-03-2 200mg $63 2026-04-30 Buy
TCI Chemical D4501 (R)-(-)-DTBM-SEGPHOS[R] >99.0%(HPLC) 566940-03-2 1g $172 2026-04-30 Buy
Strem Chemicals 15-0066 (R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(-)-DTBM-SEGPHOS? min.98% 566940-03-2 250mg $48 2026-04-30 Buy
Product number Packaging Price Buy
692484 100mg $53 Buy
692484 50mg $33.1 Buy
D4501 200mg $63 Buy
D4501 1g $172 Buy
15-0066 250mg $48 Buy

(R)-DTBM-SEGPHOS Chemical Properties,Uses,Production

Reaction

  1. Rhodium catalyzed chemo-, regio, and entantioselective [2 + 2 + 2] cycloaddition of alkynes with isocyanates.
  2. With copper, enantioselective cross Aldol-type reaction of acetonitrile.
  3. With copper, enantioselective vinylsilane alkenylation of aldehydes.
  4. Gold carbene mediated stereoselective cyclopropanation of propargyl esters.
  5. With copper, enantioselective 1,2-reduction of ketones, and 1,4-reduction of a α,β-usaturated esters.
  6. With copper, catalytic enantioselective Mannich-type reaction.
  7. Enantioselective fluorination of b β-keto esters, tert-butoxycarbonyl lactones and lactmes with Sodeoka's Pd-aqua complex and a fluorinating reagent.
  8. Rh-catalyzed intramolecular olefin or carbonyl hydroacylation.
  9. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
  10. Involved in numerous conjugate alkynylation, and ring-opening alkynylation of azabenzonorbornadienes.
  11. Involved in asymmetric hydroamination of bicyclic alkenes/dienes,13a diamination of conjugated dienes,13b and hydroalkoxylation/hydrosulfenylation of allenes.
The actions in the following figures are corresponding to the above ones in sequence. Reactions of 566940-03-2_1
Reactions of 566940-03-2_2
Reactions of 566940-03-2_3

Uses

Catalyst involved in:

  • [3,3]-Sigmatropic rearrangements using cyclopropane probes
  • Asymmetric intramolecular hydroacylation of ketoaldehydes

Reactant involved in:
  • The synthesis of gold-diphosphine complexes for use as catalysts
  • Cycloaddition of allenenes to yield alkylidenecyclobutanes

(R)-DTBM-SEGPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 78)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 459 58
Shenzhen Nexcon Pharmatechs Ltd.
+86-0755-89396905 +86-18025329037 admin@nexconn.com China 5281 58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16512 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13901 58
Labnetwork lnc.
+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418684 +8618949823763 sales@tnjchem.com China 25356 58
Weifang Wehibest Supply Chain Co.,Ltd
+8613583620690 hotspotbiotech@163.com China 926 58
Protheragen-ING
+16313385890 info@protheragen-ing.com United States 3868 58
Aladdin Scientific
tp@aladdinsci.com United States 57505 58
Wuhan Fortuna Chemical Co.,Ltd
+86-2759207851; +8618007136271 hk@fortunachem.com China 6008 58

View Lastest Price from (R)-DTBM-SEGPHOS manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-PHENYL-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)ISOXAZOLE pictures 2026-04-17 3-PHENYL-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)ISOXAZOLE
566940-03-2
$2.00-5.00 99% ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
(R)-DTBM-SEGPHOS pictures 2026-03-30 (R)-DTBM-SEGPHOS
566940-03-2
1KG 98% 2000 Shenzhen Nexcon Pharmatechs Ltd.
(R)-DTBM-Segphos pictures 2025-12-23 (R)-DTBM-Segphos
566940-03-2
1kg 98%, ee>99 200kg XINXIANG RUNYU MATERIAL CO., LTD.
(R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DTBM-SEGPHOS (R)-DTBM-SEGPHOS(R) [(4R)-(4,4μ-bi-1,3-benzodioxole)-5,5μ-diyl]bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine], (R)-(-)-5,5μ-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole (R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-Methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole (4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diylbis[bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine (R)-()-5,5′-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4′-bi-1,3-benzodioxole (R)-DTBM-SEGPHOS [(4R)-(4,4′-bi-1,3-benzodioxole)-5,5′-diyl]bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] (R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(-)-DTBM-SEGPHOS(R) 1,1'-(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis[3,5-bis(tert-butyl)-4-methoxyphenyl]phosphine] (R)-(-)-DTBM-SEGPHOS(regR)(R)-(-)-DTBM-SEGPHOS(regR) (R)-(-)-5,5'-Bis[di(3,5-di-t-butyL Phosphine, 1,1'-(4R)-[4,4'-bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]- (R)-(-)-4,4'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-3,3'-bi(1,2-methylenedioxybenzene) (R)-5,5'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bibenzo[d][1,3]dioxole (R)-DTBM-SEGPHOS/(R)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole (R)-5,5'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole 1,1′-(4R)-[4,4′-Bi-1,3-benzodioxole]-5,5′-diylbis[1,1-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine (ACI) (R)-5,5’-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4’-bibenzo[d][1,3]dioxole 5,5'-bis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino)-4,4'-bibenzo[d][1,3]dioxole 1,1'-(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis[3,5-bis(tert-butyl)-4-methoxyphenyl]phosphine (R)-(-)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole (R)-DTBM-SEGPHOS? (R)-(-)-DTBM-SEGPHOS® 1,1'-(4R)-[4,4'-Bi-Benzo[d][1,3]dioxole]-5,5'-diylbis[1,1-bis[3,5-bis(tert-butyl)-4-methoxy-phenyl]phosphine (R)-(-)-DTBM-SEGPHOS(regR) DTBM-SEGPHOS 566940-03-2 C74H100O8P2 Segphos Series Chiral Phosphine
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