4-Bromo-2-methyl-1-indanone
- CAS No.
- 174702-59-1
- Chemical Name:
- 4-Bromo-2-methyl-1-indanone
- Synonyms
- 4-Bromo-2-methyl-1-indanone;4-bromo-2-methyl-2,3-dihydro-1H--1-one;4-bromo-2-methyl-2,3-dihydroinden-1-one;4-broMo-2-Methyl-2,3-dihydro-1H-inden-1-one;1H-Inden-1-one,4-bromo-2,3-dihydro-2-methyl-
- CBNumber:
- CB92518476
- Molecular Formula:
- C10H9BrO
- Molecular Weight:
- 225.08
- MDL Number:
- MFCD09881709
- MOL File:
- 174702-59-1.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-Bromo-2-methyl-1-indanone >98.0%(GC) | B5096 | 1g | $85 |
| 4-Bromo-2-methyl-1-indanone >98.0%(GC) | B5096 | 5g | $256 |
| 4-Bromo-2-methylindan-1-one | 064689 | 1.00g | $27 |
| 4-Bromo-2-methylindan-1-one | 064689 | 5.00g | $70 |
| 4-Bromo-2-methylindan-1-one | 064689 | 25.00g | $278 |
| More product size | |||
| Melting point | 27 °C |
|---|---|
| Boiling point | 131-134℃ (2 Torr) |
| Density | 1.488±0.06 g/cm3 (20℃ 760 Torr) |
| Flash point | 99.4±12.2℃ |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | soluble in Toluene |
| form | powder to lump to clear liquid |
| color | White or Colorless to Light yellow |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| HS Code | 2914.79.4000 | |||||||||
| NFPA 704 |
|
4-Bromo-2-methyl-1-indanone price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B5096 | 4-Bromo-2-methyl-1-indanone >98.0%(GC) | 174702-59-1 | 1g | $85 | 2026-04-30 | Buy |
| TCI Chemical | B5096 | 4-Bromo-2-methyl-1-indanone >98.0%(GC) | 174702-59-1 | 5g | $256 | 2026-04-30 | Buy |
| Matrix Scientific | 064689 | 4-Bromo-2-methylindan-1-one | 174702-59-1 | 1.00g | $27 | 2026-05-18 | Buy |
| Matrix Scientific | 064689 | 4-Bromo-2-methylindan-1-one | 174702-59-1 | 5.00g | $70 | 2026-05-18 | Buy |
| Matrix Scientific | 064689 | 4-Bromo-2-methylindan-1-one | 174702-59-1 | 25.00g | $278 | 2026-05-18 | Buy |
4-Bromo-2-methyl-1-indanone Chemical Properties,Uses,Production
Synthesis
869063-66-1
174702-59-1
General procedure for the synthesis of 4-bromo-2-methyl-2,3-dihydro-1H-inden-1-one from the compound (CAS: 869063-66-1): a mixture of starting acid (unspecified amount) and 160 mL of thionyl chloride (SOCl2) was stirred for 24 hours at room temperature. Subsequently, the excess thionyl chloride was removed by distillation. Under vigorous stirring, crude 3-(2-bromophenyl)-2-methylpropionyl chloride (dissolved in 270 mL of dichloromethane) was added drop-wise to 1350 mL of dichloromethane suspension containing 136 g (1.02 mol) of aluminum trichloride (AlCl3), keeping the reaction temperature at 0 °C for 1 hour. After that, the reaction mixture was refluxed for 3 h, cooled to room temperature and poured into 500 mL of ice water. The organic layer was separated and the aqueous layer was extracted with methyl tert-butyl ether (3 x 300 mL). The organic phases were combined and dried over potassium carbonate (K2CO3) and subsequently evaporated to dryness. Purification by fractional distillation afforded 4-bromo-2-methyl-1-indanone with a boiling point of 131-134 °C/2 mmHg in a yield of 125.5 g (75% yield) as a colorless solid. Elemental analysis (calculated value C10H9BrO): C, 53.36; H, 4.03. measured value: C, 53.19; H, 3.98. 1H NMR (300 MHz, CDCl3) δ: 7.76 (d, J = 7.6 Hz, 1H, 7-H), 7.71 (d, J = 7.6 Hz, 1H, 5-H), 7.28 (t, J = 7.6 Hz, 1H, 5-H), 7.28 (t, J = 7.6 Hz, 1H, 5-H). 7.6 Hz, 1H, 6-H), 3.36 (dd, J = 17.5 Hz, J = 7.6 Hz, 1H, 3-H), 2.70-2.82 (m, 1H, 2-H), 2.67 (dd, J = 17.5 Hz, J = 3.8 Hz, 1H, 3'-H), 1.34 (d, J = 7.3 Hz, 3H, 2-Me).13C NMR (75 MHz, CDCl3) δ: 208.3, 152.9, 138.2, 137.2, 129.0, 122.6, 122.0, 41.8, 35.7, 16.0.
References
[1] Patent: US2007/135597, 2007, A1
[2] Patent: WO2007/70040, 2007, A1. Location in patent: Page/Page column 104-105
[3] Patent: WO2007/70041, 2007, A1. Location in patent: Page/Page column 95-96
4-Bromo-2-methyl-1-indanone Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 | jiuyitime@fdachem.com | China | 16512 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14014 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21586 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Alfa Chemistry | -- | info@alfa-chemistry.com | United States | 2344 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52704 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Coresyn Pharmatech Co., Ltd. | +86-571-86626709 +86-18157142896 | cbc@coresyn.com | China | 9984 | 58 |
View Lastest Price from 4-Bromo-2-methyl-1-indanone manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-04-17 | 4-Bromo-2-methyl-1-indanone
174702-59-1
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2025-04-04 | 4-Bromo-2-methyl-1-indanone
174702-59-1
|
1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
 |
2019-07-06 | 4-Bromo-2-methyl-1-indanone
174702-59-1
|
$1.00 | 1KG | 98% | 1ton | Career Henan Chemical Co |
-
- 4-Bromo-2-methyl-1-indanone
174702-59-1
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- 4-Bromo-2-methyl-1-indanone
174702-59-1
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- 4-Bromo-2-methyl-1-indanone
174702-59-1
- $1.00
- 98%
- Career Henan Chemical Co
