エチレングリコール 化學(xué)特性,用途語,生産方法
外観
無色澄明の液體
定義
本品は、次の化學(xué)式で表される二価アルコールである。
溶解性
水、エタノール及びジエチルエーテルに極めて溶けやすい。水、エタノール、メタノール、アセトン、グリセリン、酢酸に易溶。エーテル、四塩化炭素、クロロホルムに不溶。
無機性値/有機性値
200/40
解説
C2H6O2(62.07)．HOCH2CH2OH．1,2-エタンジオール(1,2-ethanediol)ともいう．グリコール類のもっとも簡単なもの．エチレングリコール, 実験室的製法では，1,2-ジブロモエタンを塩基で加水分解する．工業(yè)的には，エチレンオキシドを無觸媒で大過剰の水存在下での水和によって製造する．甘味をもつ無色の粘ちゅうな液體．融點－13.0 ℃，沸點197.6 ℃．d2041.1088．n20D1.43178．水，エタノール，アセトンに易溶，エーテル，ベンゼンに難溶．二つのヒドロキシ基をもつので，おもにポリエステル繊維および樹脂の製造に用いられる．ほかにダイナマイト，セロハン，不凍液などの用途がある．[CAS 107-21-1]
森北出版「化學(xué)辭典（第2版）
用途
アミノ酸自動分析用緩衝液添加剤。
用途
ポリエチレンテレフタラート、ポリエステル、PETボトル、不凍液
モノエチレングリコールはポリエチレンテレフタラート（PET樹脂）の主原料の一つである。また、毒性が低く、水によくとけ、融點が低いため、自動車用不凍液としてよく用いられている。
用途
水分の混入を嫌う有機合成用、脫水剤。
用途
本物質(zhì)の主な用途は、ポリエステル繊維原料、不凍液、グリセリンの代用、溶剤(酢酸ビニル系樹脂)、耐寒潤滑油、有機合成(染料、香料、化粧品、ラッカー)、電解コンデンサー用ペースト、乾燥防止剤(にかわ)、醫(yī)薬品、不凍ダイナマイト、界面活性剤、不飽和ポリエステルである
用途
二つのヒドロキシ基をもつので，おもにポリエステル繊維および樹脂の製造に用いられる．ほかにダイナマイト，セロハン，不凍液などの用途がある．
アルキド樹脂や合成繊維，特にポリエチレンテレフタラートなどの原料，自動車エンジン不凍液に用いられる。またニトロ化してニトログリコールとし，ニトログリセリンと混合しダイナマイトの製造原料とする。
化粧品の成分用途
保水剤、減粘剤、溶剤、香料
特徴
エチレングリコール常溫で粘り気があり無色無臭で甘みのある液體
水に任意の割合で混和
主な用途／役割
天然物系接著剤の水分保持、エマルション系接著剤の可塑剤として使用される。ポリウレタン系接著剤原料としても使用される。
使用上の注意
吸濕性及び粘性あり
化學(xué)的特性
エチレングリコールは化學(xué)式がC2H6O2で表される有機化合物です無色の粘性のある液體で甘味を持ち水やアルコールに非常によく溶けます主に自動車の冷卻液や防寒液としてまたポリエステル繊維や樹脂製造の原料として広く使用されています
説明
Ethylene glycol was first synthesized in 1859; however, it did
not become a public health concern until after World War II. In
fact, the first published series of deaths from ethylene glycol
consumption involved 18 soldiers who drank antifreeze as
a substitute for ethanol. Despite the early recognition that
patients who drank ethanol in addition to ethylene glycol had
prolonged survival when compared to those drinking ethylene
glycol alone, antidotal treatment of ethylene glycol toxicity
with ethanol was not evaluated until the 1960s. Today,
ethylene glycol poisoning continues to be a public health
problem, particularly in the southeastern United States. In
2009, US poison control centers received 5282 calls about
possible ethylene glycol exposures, and the toxicology
community believes these exposures are underreported.
化學(xué)的特性
Ethylene glycol,CH20HCH20H, also known as glycol,ethylene alcohol, glycol alcohol, and dihydric alcohol, is a colorless liquid. It is soluble in water and in alcohol. Ethyleneglycol has a low freezing point,-25°C (-13 OF), and is widely used as an antifreeze in automobiles and in hydraulic fluids. It is used as a solvent for nitrocellulose and in the manufacture of acrylonitrile, dynamites, and resins.
使用
Ethylene glycol is used as an antifreeze inheating and cooling systems (e.g., automobileradiators and coolant for airplane motors).It is also used in the hydraulic brake fluids;as a solvent for paints, plastics, and inks; as a softening agent for cellophane; and in themanufacture of plasticizers, elastomers, alkydresins, and synthetic fibers and waxes.
調(diào)製方法
Historically, ethylene glycol has been manufactured by
hydrolyzing ethylene oxide. Presently, it is also produced
commercially by oxidizing ethylene in the presence of acetic
acid to form ethylene diacetate, which is hydrolyzed to the
glycol, and acetic acid is recycled in the process .
定義
ChEBI: A 1,2-glycol compound produced via reaction of ethylene oxide with water.
製造方法
Ethylene glycol is prepared by the hydration of ethylene oxide:
This reaction is carried out in a manner comparable to that described for the
preparation of propylene glycol from propylene oxide .
Ethylene glycol is a colourless liquid, b.p. 197C.
主な応用
Integrating CO2 capture with electrochemical conversion offers a promising pathway to reduce the energy penalty associated with conventional solvent regeneration. In this study, researchers develop a non-aqueous Monoethanolamine (MEA)-based solvent composed of Choline Chloride (ChCl) and Ethylene Glycol (EG), designed to function simultaneously as a CO2 absorbent and an electrolyte in an electrolyzer, thereby eliminating the need for intermediate solvent regeneration steps
[1].
反応性
Glycol reacts (1) with sodium to form sodium glycol, CH2OH · CH2ONa, and disodium glycol, CH2ONa·CH2ONa; (2) with phosphorus pentachloride to form ethylene dichloride, CH2Cl·CH2Cl (3) with carboxy acids to form mono- and disubstituted esters, e.g., glycol monoacetate, CH2OH·CH2OOCCH3, glycol diacetate, CH3COOCH2 · CH2OOCCH3; (4) with nitric acid (with sulfuric acid), to form glycol mononitrate, CH2OH·CH2ONO2, glycol dinitrate, CH2ONO2 · CH2ONO2; (5) with hydrogen chloride, heated, to form glycol chlorohydrin (ethylene chlorohydrin, CH2OH·CHCl); (6) upon regulated oxidation to form glycollic aldehyde, CH2OH·CHO, glyoxal, CHO · CHO, glycollic acid, CH2OH·COOH, glyoxalic acid, CHO·COOH, oxalic acid, COOH·COOH.
安全性
エチレングリコールは摂取すると非常に有害であり重篤な健康被害を引き起こす可能性がありますそのため取り扱いには特に注意が必要ですまた環(huán)境に放出されると水生生物に悪影響を與えることが知られており廃棄時には適切な処理が求められます
一般的な説明
Ethylene glycol is a clear, colorless syrupy liquid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since Ethylene glycol is a liquid Ethylene glycol can easily penetrate the soil and contaminate groundwater and nearby streams.
反応プロフィール
Mixing Ethylene glycol in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, sulfuric acid, [NFPA 1991].
危険性
Questionable carcinogen. Toxic by ingestion and inhalation. Lethal dose reported to be
100 cc.
健康ハザード
Inhalation of vapor is not hazardous. Ingestion causes stupor or coma, sometimes leading to fatal kidney injury.
火災(zāi)危険
Ethylene glycol is combustible.
化學(xué)性質(zhì)
多価アルコールの一つで，アルキド樹脂の合成に用いられる。
生産方法
エチレングリコールは主にエチレンオキサイドの水和反応によって製造されます具體的な化學(xué)反応式は次のとおりです
安全性プロファイル
Human poison by
ingestion. (Lethal dose for humans reported
to be 100 mL.) Moderately toxic to humans
by an unspecified route. Moderately toxic
experimentally by ingestion, subcutaneous,
intravenous, and intramuscular routes.
Human systemic effects by ingestion and
inhalation: eye lachrymation, general
anesthesia, headache, cough, respiratory
stimulation, nausea or vomiting, pulmonary,
kidney, and liver changes. If ingested it
causes initial central nervous system
stimulation followed by depression. Later, it
causes potentially lethal kidney damage.
Very toxic in particulate form upon
inhalation. An experimental teratogen.
Other experimental reproductive effects.
Human mutation data reported. A skin, eye,
and mucous membrane irritant.
Combustible when exposed to heat or
flame; can react vigorously with oxidants. Moderate explosion hazard when exposed
to flame. Iptes on contact with chromium
trioxide, potassium permanganate, and
sodium peroxide. Mixtures with ammonium
dichromate, silver chlorate, sodium chlorite,
and uranyl nitrate ipte when heated to
100°C. Can react violently with
chlorosulfonic acid, oleum, H2SO4, HClO4,
and Pass. Aqueous solutions may ignite
silvered copper wires that have an applied
D.C. voltage. To fight fire, use alcohol foam,
water, foam, CO2, dry chemical. When
heated to decomposition it emits acrid
smoke and irritating fumes.
職業(yè)ばく露
Ethylene glycol is used in antifreeze (especially as car radiator antifreeze) and in production of polyethylene terephthalate fibers and films; in hydraulic fluids; antifreeze and coolant mixtures for motor vehicles; electrolytic condensers; and heat exchangers. It is also used as a solvent and as a chemical intermediate for ethylene glycol dinitrate, glycol esters; resins, and for pharmaceuticals.
環(huán)境運命予測
Ethylene glycol is considered an inert ingredient in pesticides. It
typically enters the environment through waste streams after
use of deicing products, where it is highly mobile in soil and
contaminates groundwater. Ethylene glycol is considered
‘readily biodegradable.’ It biodegrades relatively quickly; its
half-life (t1/2) is 2–12 days in soil.
Ethylene glycol is biodegraded in water under both aerobic
and anaerobic conditions within a day to a few weeks. In the
atmosphere, ethylene glycol photochemically degrades with
a t1/2 of approximately 2 days.
Solubility in organics
Miscible
with water and alcohol, soluble in lower atifatic alcohols and ketones, Propylene glycol and
Glycerin, poorly soluble in Hydrocarbons such
as Terpenes as well as in Terpene alcohols,
esters, etc.
輸送方法
UN3082 Environmentally hazardous substances,
liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required
合成方法
エチレンオキシドの水和反応、エチレンカーボネートの水和反応、TeO2觸媒と臭化物イオンの存在下のエチレンと酢酸とO2との反応による方法
純化方法
It is very hygroscopic, and also likely to contain higher diols. Dry it with CaO, CaSO4, MgSO4 or NaOH and distil it under vacuum. Dry further by reaction with sodium under nitrogen, reflux for several hours and distil. The distillate is then passed through a column of Linde type 4A molecular sieves and finally distil under nitrogen, from more molecular sieves. Then fractionally distil it. [Beilstein 1 IV 2369.]
不和合性
Reacts with sulfuric acid, oleum, chlorosulfonic acid; strong oxidizing agents; strong bases; chromium trioxide; potassium permanganate; sodium peroxide.
Hygroscopic (i.e., absorbs moisture from the air)
廃棄物の処理
Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal,
state, and local environmental regulations must be
observed. Alternatively, ethylene glycol can be recovered
from polyester plant wastes
エチレングリコール 上流と下流の製品情報
原材料
準(zhǔn)備製品
2,4-DIAMINO-6-MERCAPTOPYRIMIDINE
2-(2-ブロモエチル)-1,3-ジオキソラン
tussah silk fabric aftertreatment finishing agent
ルミノール
エタン二酸·2水和物
2-エチル-5-メチルチオフェン
4-ホルミルフェニルボロン酸
5-クロロオキシインドール
Polyester Filament
PolyesterPolyol
3-BENZOYL PROPIOPHENONE
Dye-fixing agent,no formaldehyde
solid alcohol
1-ビニル-2-ピロリドン
6-アザチミン
21-Iodo-16-methylpregna-1,4,9(11)-trien-17-ol-3,20-dione
エチレングリコールジグリシジルエーテル
1-クロロ-2-メチル-1-プロペン
2,3-チオフェンジカルボキシアルデヒド
4-(ヒドロキシメチル)フェニルボロン酸
エチレングリコールブラシラート
2-(2,4-ジニトロフェノキシ)エタノール
Antifreeze
16,17-Epoxypregna-5,9(11)-diene-3,20-dione cyclic bis(1,2-ethanediyl acetal)
Saponified soluble oil
16-Methylpregna-1,4,9(11)-trien-17-ol-3,20-dione
9-Bromo-11,17,21-trihydroxy-16-methylpregna-1,4-diene-3,20-dione-21-acetate
16-Methylpregna-4,9(11)-dien-17-ol-3,20-dione
17-Ethinyl-17-hydroxy-18-methylestra-5(10),9(11)-dien-3-one-3-ethylene ketal
21-アセチルオキシ-17-ヒドロキシ-16β-メチルプレグナ-1,4,9(11)-トリエン-3,20-ジオン
4,5-ジメチル-チオフェン-2-カルボン酸
5-[(1,3-DIOXO-1,3-DIHYDRO-2H-ISOINDOL-2-YL)METHYL]-2-FURALDEHYDE
2,4-ジメチルチオフェン
2,3-ジメチルチオフェン
2-フェニルイミダゾリン
4,5-ジメチルチオフェン-2-カルボキシアルデヒド
2-フルオロエタノール
21-酢酸デキサメタゾン
21-アセチルオキシ-9β,11β-エポキシ-17-ヒドロキシ-16β-メチルプレグナ-1,4-ジエン-3,20-ジオン
2-シアノ-N-メチル-2-[3-(2,4,6-トリオキソヘキサヒドロピリミジン-5-イリデン)イソインドリン-1-イリデン]アセトアミド