ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)
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- CAS番號.
- 38465-86-0
- 化學名:
- ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)
- 別名:
- ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I);ヘキサフルオロりん酸(1,5‐シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I);(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)ヘキサフルオロホスファート
- 英語名:
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- 英語別名:
- methyl(diphenyl)phosphane;(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
- CBNumber:
- CB8242424
- 化學式:
- C34H38F6IrP3
- 分子量:
- 845.79
- MOL File:
- 38465-86-0.mol
- MSDS File:
- SDS
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ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I) 物理性質(zhì)
- 融點 :
- 224 °C (dec.) (lit.)
- 貯蔵溫度 :
- under inert gas (nitrogen or Argon) at 2-8°C
- 溶解性:
- sol CH2Cl2; insol diethyl ether and hexanes.
- 外見 :
- 結(jié)晶性粉末
- 色:
- 赤
- 水溶解度 :
- アセトンに可溶。水に不溶。
- Sensitive :
- Air & Moisture Sensitive
- InChI:
- 1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;
- InChIKey:
- LXKHQEQLBSJJCO-JXNOXZOESA-N
- SMILES:
- [Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5
ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I) 価格
もっと(4)
| メーカー |
製品番號 |
製品説明 |
CAS番號 |
包裝 |
価格 |
更新時間 |
購入 |
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関東化學株式會社(KANTO)
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37794-2A |
ヘキサフルオロりん酸（１，５‐シクロオクタジエン）ビス（メチルジフェニルホスフィン）イリジウム（Ｉ） 97%
(1,5‐Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate 97% |
38465-86-0 |
1g |
￥47000 |
2021-03-23 |
購入 |
|
関東化學株式會社(KANTO)
|
37794-1A |
ヘキサフルオロりん酸（１，５‐シクロオクタジエン）ビス（メチルジフェニルホスフィン）イリジウム（Ｉ） 97%
(1,5‐Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate 97% |
38465-86-0 |
250mg |
￥16700 |
2021-03-23 |
購入 |
|
Sigma-Aldrich Japan
|
337455 |
(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)ヘキサフルオロホスファート 97%
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate 97% |
38465-86-0 |
50mg |
￥8020 |
2024-03-01 |
購入 |
|
Sigma-Aldrich Japan
|
337455 |
(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)ヘキサフルオロホスファート 97%
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate 97% |
38465-86-0 |
500mg |
￥38500 |
2024-03-01 |
購入 |
ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I) 化學特性,用途語,生産方法
化學的特性
red crystalline powder
使用
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh
2Me)
2]PF
6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH
2(solv)
2(PPh
2Me)
2]PF
6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (
E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.
使用
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) Hexafluorophosphate is used as a reagent for isomerization of allylic alcohols and ethers; hydrogenation catalyst.
製造方法
Preparative Methods of (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) Hexafluorophosphate: to a suspension of [Ir(μ-Cl)(1,5-cod)]2 (0.2 g) in 10 mL of ethanol is added methyldiphenylphosphine (0.2 g) in
ethanol. The mixture is stirred for ca. 10 min until the original suspension has dissolved. To this is added excess NH4PF6 in ethanol.
After cooling to 0 °C the precipitate is filtered, washed with ethanol and then ether to give the title reagent (0.36 g) as red prisms
[1].
ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I) 上流と下流の製品情報
原材料
準備製品
ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I) 生産企業(yè)
Global( 63)Suppliers
ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I) スペクトルデータ(FT-IR、IR、Raman)
38465-86-0(ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I))キーワード:
- 38465-86-0
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%
- Iridium(1+), (1,2,5,6-.eta.)-1,5-cyclooctadienebis(methyldiphenylphosphine)-, hexafluorophosphate(1-)
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i)
- (bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate
- methyl(diphenyl)phosphane
- 1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM
- (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH
- 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate, [Ir(COD)(PPh2Me)2]PF6
- ヘキサフルオロりん酸(1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)
- ヘキサフルオロりん酸(1,5‐シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)
- (1,5-シクロオクタジエン)ビス(メチルジフェニルホスフィン)イリジウム(I)ヘキサフルオロホスファート