(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン
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- CAS番號.
- 5794-04-7
- 化學名:
- (1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン
- 別名:
- (1S,4R)-2,2-ジメチル-3-メチレンノルボルナン;(1R,4S)-3,3-ジメチル-2-メチレンビシクロ[2.2.1]ヘプタン;(1S,4R)-2,2-ジメチル-3-メチレンビシクロ[2.2.1]ヘプタン;(-)-カンフェン;(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン;(1β,4β)-2,2-ジメチル-3-メチレンビシクロ[2.2.1]ヘプタン;[1S,4R,(-)]-2,2-ジメチル-3-メチレンビシクロ[2.2.1]ヘプタン
- 英語名:
- (-)-CAMPHENE
- 英語別名:
- (1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE;2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane;Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-;[1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane;L-Camphene;(-)-Camphene;(-)-Camphene,95%;(+/-)-Camphene, sum of camphene + fenchene;(1S,4R)-2,2-Dimethyl-3-methylenenorbornane;2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
- CBNumber:
- CB8468970
- 化學式:
- C10H16
- 分子量:
- 136.23
- MOL File:
- 5794-04-7.mol
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(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン 物理性質(zhì)
- 融點 :
- 36-38 °C(lit.)
- 沸點 :
- 157.5-158.5 °C(lit.)
- 比重(密度) :
- 0.84 g/mL at 25 °C(lit.)
- 屈折率 :
- 1.4562 (estimate)
- 閃點 :
- 98 °F
- 溶解性:
- Benzene (Slightly), Chloroform (Sparingly)
- 外見 :
- Solid
- 色:
- White to Off-White Waxy
- 臭い (Odor):
- ジプロピレングリコール中10.00%。新鮮な木質(zhì)モミテルペン
- においのタイプ:
- 木質(zhì)の
- 旋光度（Optical Rotation）:
- [α]20/D -48°, c =4 in ethanol
[α]25/D -35 to -43°, c =4 in ethanol
- Merck :
- 14,1730
- 安定性：:
- Volatile
- InChI:
- 1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m1/s1
- InChIKey:
- CRPUJAZIXJMDBK-BDAKNGLRSA-N
- SMILES:
- CC1(C)[C@H]2CC[C@H](C2)C1=C
- LogP:
- 4.239 (est)
- EPAの化學物質(zhì)情報:
- Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (5794-04-7)
(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン 価格
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(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン 化學特性,用途語,生産方法
定義
ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has S configuration at position 1 and R configuration at position 4.
純化方法
Purify norbornane by fractionation through a Stedman column (see p. 11) at 100mm in a N2 atmosphere, crystallise it from EtOH and sublime it in a vacuum below its melting point. It is characterised by its camphenilone semicarbazone, m 217-218.5o, or camphor semicarbazone, m 236-238o. [NMR: Hana & Koch Chem Ber 111 2527 1978, Bartlett et al. Justus Liebigs Ann Chem 623 217 1959, Bain et al. J Am Chem Soc 72 3124 1950, Beilstein 5 IV 461.]
(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン 上流と下流の製品情報
原材料
準備製品
(1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン 生産企業(yè)
Global( 25)Suppliers
5794-04-7((1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン)キーワード:
- 5794-04-7
- 2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
- L-Camphene
- (1R,4S)-3,3-Dimethyl-2-methylenebicyclo[2.2.1]heptane
- (1S,4R)-2,2-Dimethyl-3-methylenenorbornane
- ()-Camphene,(1S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
- (+/-)-Camphene, sum of camphene + fenchene
- (-)-Camphene,95%
- (-)-Camphene
- [1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
- Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-
- (1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE
- 2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane
- (-)-CaMphene, tech. 80% (suM of caMphene + fenchene)
- (1S,4R)-6,6-Dimethyl-5-methylidenebicyclo[2.2.1]heptane
- (1S,4R)-2,2-ジメチル-3-メチレンノルボルナン
- (1R,4S)-3,3-ジメチル-2-メチレンビシクロ[2.2.1]ヘプタン
- (1S,4R)-2,2-ジメチル-3-メチレンビシクロ[2.2.1]ヘプタン
- (-)-カンフェン
- (1α,4α)-2-メチレン-3,3-ジメチルビシクロ[2.2.1]ヘプタン
- (1β,4β)-2,2-ジメチル-3-メチレンビシクロ[2.2.1]ヘプタン
- [1S,4R,(-)]-2,2-ジメチル-3-メチレンビシクロ[2.2.1]ヘプタン