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??? ?????????
??? ????????? ??? ???
?? ??:
21324-39-0
???:
??? ?????????
???(??):
????????????;????????????(SODIUMHEXAFLUOROPHOSPHATE)
???:
Sodium hexafluorophosphate
???(??):
NaPF6;10ppm H2O);10ppm H 2 O);Sodium hexafL;Sodium fluophosphate;Sodium hexafluoropho;SODIUM HEXAFLUOROPHOSPHATE;SodiumHexafluorophosphate>Sodiumhexafluorophosphate,99%;SODIUM HEXAFLUOROPHOSPHATE (V)
CBNumber:
CB0145930
???:
F6NaP
??? ??:
167.95
MOL ??:
21324-39-0.mol
MSDS ??:
SDS

??? ????????? ??

???
>200 °C (lit.)
??
2.369 g/mL at 25 °C (lit.)
?? ??
Store at room temperature, keep dry and cool
???
H2O: ??? 5%, ??, ??
??? ??
????
??
???? ?? ????
Specific Gravity
3.375
??????(pH)
2.0-4.0
???
??
??
Hygroscopic
???
????. ??? ???? ????.
?? ??
??? ??
InChI
InChI=1S/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1
InChIKey
KMADQUOCJBLXRP-UHFFFAOYSA-N
SMILES
[P+5]([F-])([F-])([F-])([F-])([F-])[F-].[Na+]
CAS ??????
21324-39-0(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C,Xi
?? ???? ?? 20/21/22-34
????? 26-36/37/39-45
????(UN No.) UN 3260 8/PG 2
WGK ?? 3
F ?????? 3-10
?? ?? ?? Irritant
?? ?? 6.1
???? III
HS ?? 28269090
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B
???? ?? KE-31464
????(GHS): Corrosion (GHS05)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
3 0

??? ????????? MSDS


Sodium hexafluorophosphate

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White solid, sensitive to air and carbon dioxide, highly soluble in water, decomposes at high temperatures.

??

Sodium hexafluorophosphate is used as an ion pairing agent for the determination of cobalt(II) in water samples. It is used as an important raw material in the preparation of 2-chloro-1,3-bis(dimethylamino)trimethinium hexafluorophosphate.

?? ??

Prepared by slowly adding PCl5 dropwise to an aqueous HF solution containing NaCl.

Purification Methods

Recrystallise it from acetonitrile and dry it in a vacuum for 2days at room temperature. It is an irritant and is hygroscopic. [Delville et al. J Am Chem Soc 109 7293 1987.]

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