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?????

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????? ??? ???
?? ??:
117-34-0
???:
?????
???(??):
?????;????????
???:
2,2-Diphenylacetic acid
???(??):
DIPHENYLACETIC ACID;DPAA;2,2-diphenylacetate;Biphenylacetic acid;'LGC' (2406);iphenylaceticaci;diphenyl-aceticaci;RARECHEM AL BO 1083;DiphenyleaceticAcid;diphenylethanoicacid
CBNumber:
CB0153782
???:
C14H12O2
??? ??:
212.24
MOL ??:
117-34-0.mol
MSDS ??:
SDS

????? ??

???
147-149 °C(lit.)
?? ?
195°C 25mm
??
1,257 g/cm3
???
0.001Pa at 25℃
???
1.6000 (estimate)
???
195°C/25mm
?? ??
Sealed in dry,Room Temperature
???
0.13g/L
?? ?? (pKa)
3.94(at 25℃)
??? ??
??? ??
??
???? ???? ?? ??
??????(pH)
3.8 (H2O, 20℃)(saturated solution)
???
?(0.13g/L)? ?? ?????.
Merck
14,3316
BRN
1910978
InChI
1S/C14H12O2/c15-14(16)13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H,(H,15,16)
InChIKey
PYHXGXCGESYPCW-UHFFFAOYSA-N
SMILES
OC(=O)C(c1ccccc1)c2ccccc2
LogP
3.17 at 25℃
CAS ??????
117-34-0(CAS DataBase Reference)
NIST
Benzeneacetic acid, «alpha»-phenyl-(117-34-0)
EPA
Benzeneacetic acid, .alpha.-phenyl- (117-34-0)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/38-36/37/38
????? 24/25-36/37-26
WGK ?? 2
RTECS ?? AH2515000
TSCA TSCA listed
?? ?? IRRITANT
HS ?? 29163900
???? ??? 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Irrit. 2
?? mouse,LD50,intraperitoneal,500mg/kg (500mg/kg),Farmaco, Edizione Scientifica. Vol. 13, Pg. 286, 1958.
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H412 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 3 P273, P501
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
2 0

????? MSDS


2,2-Diphenylacetic acid

????? C??? ??, ??, ??

??? ??

white to creamy-white crystalline powder

??

Kinetic resolution of racemic 1-heteroarylalkanols by asymmetric esterification using diphenylacetic acid with pivalic anhydride and a chiral acyl-transfer catalyst is described. Molecular crystal of acridine and diphenylacetic acid and its absolute asymmetric photodecarboxylating condensation generates chirality in a two-component. The activation parameters for the racemization of a series of ortho-alkyl-substituted diphenylacetic acids are determined.

??

ChEBI: A monocarboxylic acid that is acetic acid where the methyl hydrogens have been replaced by two phenyl groups respectively.

Purification Methods

Crystallise the acid from *benzene, H2O or aqueous 50% EtOH. [Beilstein 9 H 673, 9 IV 2492.]

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