Benzylchlorodimethylsilane
Benzylchlorodimethylsilane ??
- ???
- <0°C
- ?? ?
- 101-103 °C/18 mmHg (lit.)
- ??
- 1.018 g/mL at 25 °C (lit.)
- ???
- n20/D 1.511(lit.)
- ???
- 194 °F
- ?? ??
- Store at room temperature, keep dry and cool
- ??? ??
- ??? ??
- Specific Gravity
- 1.016
- ??
- ?? ?? ?? ??
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- InChI
- 1S/C9H13ClSi/c1-11(2,10)8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
- InChIKey
- ABHNFDUSOVXXOA-UHFFFAOYSA-N
- SMILES
- C[Si](C)(Cl)Cc1ccccc1
- CAS ??????
- 1833-31-4(CAS DataBase Reference)
- EPA
- Silane, chlorodimethyl(phenylmethyl)- (1833-31-4)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? |
C |
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| ?? ???? ?? |
34 |
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| ????? |
26-36/37/39-45 |
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| ????(UN No.) |
UN 2987 8/PG 2 |
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| WGK ?? |
3 |
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| RTECS ?? |
VV1810000 |
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| TSCA |
TSCA listed |
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| HS ?? |
2931.90.6000 |
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| ?? ?? |
8 |
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| ???? |
II |
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| ???? ??? |
8A - Combustible corrosive hazardous materials |
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| Hazard Classifications |
Skin Corr. 1B |
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|
| ?? |
LD50 ivn-mus: 56 mg/kg CSLNX* NX#04165 |
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| ????(GHS): |
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| ?? ?: |
Danger |
| ??·?? ??: |
| ?? |
??·?? ?? |
?? ?? |
?? |
?? ? |
?? ?? |
P- ?? |
| H314 |
??? ?? ??? ?? ??? ??? |
????? ?? ????? |
?? 1A, B, C |
?? |
|
P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501 |
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| ??????: |
| P280 |
????/???/???/?????? ?????. |
| P303+P361+P353 |
??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????. |
| P305+P351+P338 |
?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????. |
| P363 |
?? ??? ??? ??? ?????. |
| P405 |
???? ?????. |
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| NFPA 704 |
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Benzylchlorodimethylsilane C??? ??, ??, ??
??
Benzylchlorodimethylsilane can be used to prepare:
- A ferrocene based mesoporous catalyst, applicable in the oxidation of styrene.
- Silylbissulfide named 3-(benzyldimethylsilyl)-1,3-bis(phenylthio)-1-propene.
- Silyl enyne by reacting with 6-hept-1-yne and nBu-Li, for further use in the intramolecular cross-metathesis to yield silicon substituted diene.
Safety Profile
Poison by intravenous route.When heated to decomposition it emits toxic vapors ofCl
- .
Benzylchlorodimethylsilane ?? ?? ? ???
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Benzylchlorodimethylsilane ?? ??
???( 119)?? ??
Benzylchlorodimethylsilane ?? ??:
