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1314-96-1
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???(??):
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Strontium sulfide
???(??):
SrS;CI 77847;thioxostrontium;PIGMENT WHITE S;STRONTIUM SULFIDE;strontium sulphide;strontiummonosulfide;strontiumsulfide(srs);sulfanylidenestrontium;STRONTIUM (II) SULFIDE
CBNumber:
CB0386740
???:
SSr
??? ??:
119.68
MOL ??:
1314-96-1.mol

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>2000 °C(lit.)
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3,7 g/cm3
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slightly soluble in H2O; soluble in acid solutions
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Specific Gravity
3.7
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Crystal Structure
NaCl type
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Hygroscopic
Merck
14,8849
crystal system
Cube
Space group
Fm3m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.602030.602030.602039090900.2182
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DEPILATORY
InChI
1S/S.Sr
InChIKey
XXCMBPUMZXRBTN-UHFFFAOYSA-N
SMILES
S=[Sr]
CAS ??????
1314-96-1(CAS DataBase Reference)
EPA
Strontium sulfide (1314-96-1)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 31-34
????? 26-36/37/39-45
????(UN No.) UN 3262 8/PG 3
WGK ?? 3
TSCA TSCA listed
?? ?? 4.3
???? III
HS ?? 2830908500
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
???? ?? KE-32250
????(GHS): Exclamation Mark (GHS07)Corrosion (GHS05)
?? ?: Danger
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?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P310 ?? ????(??)? ??? ????. ???? ?? ????(??)? ??? ????.
P405 ???? ?????.
NFPA 704
0
3 1

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Strontium sulfide is a grey powder giving a hydrogen sulphide-like smell in the air. It is insoluble in cold water, and decomposes in hot water and acid. In the wet air can decompose to H2S, can also be oxidised to SrSO4. heating for 3 hours to light red, and water vapour contact with the formation of SrO, SrSO4, H2 and SO2. reaction with acid to produce H2S.

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Strontium sulfide (SrS) smells like rotten eggs. It is used as a depilatory to remove hair from skin and hides or In luminous paints.

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Strontium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio:
Sr+S+heat→SrS
SrS can also be produced by the “carbothermic reduction” of calcium sulfate, which entails the conversion of carbon, usually as charcoal, to CO2:
SrSO4+2C→SrS+ 2CO2
This can react further:
3SrSO4+SrS→4SrO+ 4SO2
A mixture of oxide-sulfide is the result. Thus, this type of preparation cannot be used to prepare a pure SrS salt.

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Strontium sulfide, grayish-white solid (thermodynamic Ksp 500) reactive with water to form strontium hydrosulfide, Sr(SH)2, solution. Strontium hydrosulfide is formed (1) by reaction of strontium sulfide and H2O, (2) by saturation of strontium hydroxide solution with H2S. Strontium polysulfides are formed by boiling strontium hydrosulfide with sulfur.

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Gray powder with an odor of H2S in moist air.

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Slowly releases H2S in moist air.

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STRONTIUM SULFIDE reacts vigorously with acids to release hydrogen sulfide gas. May react exothermically with oxidizing agents including inorganic oxoacids, organic peroxides and epoxides, and inorganic peroxides to generate toxic gases.

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Moderate fire and explosion risk. Irritant to skin and tissues.

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ACUTE/CHRONIC HAZARDS: Irritant to skin and tissue. Moderate fire hazard and explosion risk.

Safety Profile

Poison by inhalation and ingestion. Ready decomposes to yield H2S. Incompatible with lead(1V) oxide. When heated to decomposition it emits toxic fumes of SOx. See also SULFIDES and STRONTIUM COMPOUNDS.

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