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???(IV)???

???(IV)???
???(IV)??? ??? ???
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12034-59-2
???:
???(IV)???
???(??):
???(IV)???
???:
NIOBIUM (IV) OXIDE
???(??):
NbO2;dioxoniobium;niobium dioxide;NIOBIUM OXIDE S;NIOBIUM (IV) OXIDE;niobiumoxide(nbo2);Niobium(IV)dioxide;Niobium oxide (NbO2);Niobium(IV)oxide,99+%;Niobium(IV) oxide, 99.9%
CBNumber:
CB1240335
???:
NbO2
??? ??:
124.91
MOL ??:
12034-59-2.mol
MSDS ??:
SDS

???(IV)??? ??

???
1901°C
??
5.9 g/mL at 25 °C(lit.)
?? ??
Store at room temperature, keep dry and cool
??? ??
??
??
white tetragonal crystals, crystalline or powder
Specific Gravity
5.9
???
?? ???.
??
Cp(crystal): 0.46 J/(g·K), at 25℃
crystal system
square
Space group
I41/a
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.3711.3710.59859090901.125
InChI
1S/Nb.2O
InChIKey
HFLAMWCKUFHSAZ-UHFFFAOYSA-N
SMILES
O=[Nb]=O
CAS ??????
12034-59-2(CAS DataBase Reference)
EPA
Niobium oxide (NbO2) (12034-59-2)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-37/39
WGK ?? 3
TSCA TSCA listed
HS ?? 2825908590
???? ??? 11 - Combustible Solids
???? ?? KE-25899
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
NFPA 704
0
0 0

???(IV)??? C??? ??, ??, ??

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black powder

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Niobium(IV) oxide is used as a reducing agent, which reduces carbon dioxide and sulfur dioxide to carbon and sulfur respectively. It finds application in dielectric material for electronic capacitors. It is also used for manufacturing metal niobium metal, in optical glass and in electronic industry.

Synthesis

In this procedure, pure Nb2O5 is reduced in an H2 stream at1000-1200°C. The reduction time for 1 g. of oxide (contained in a boat) is 1-2hours. Weight control is necessary, since prolonged heating athigh temperatures produces some further reduction to NbO.

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