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????? ??? ???
?? ??:
550-74-3
???:
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???(??):
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PICROLONIC ACID
???(??):
NSC 5049;PICROLIC ACID;PicrolonicAci;PICROLONIC ACID;Picrolonic acid,93%;Picrolonic acid, AR;Picrolonic acid, 98+%;LABOTEST-BB LT00233107;4-nitro-3-methyl-p-nitrophenyl-5-pyrazolone;3-methyl-4-nitro-1-p-nitrophenyl-5-pyrazolone
CBNumber:
CB1405992
???:
C10H8N4O5
??? ??:
264.19
MOL ??:
550-74-3.mol

????? ??

???
119 °C
?? ?
548.8±50.0 °C(Predicted)
??
1.65±0.1 g/cm3(Predicted)
?? ??
Sealed in dry,2-8°C
???
???? ?? 0.27%, ???? ?? ?????.
??? ??
??? ??? ??. ??? 116-120°C (???).
?? ?? (pKa)
2.44±0.40(Predicted)
???
?? ?? ?????. ???? ?????.
Merck
14,7412
BRN
623723
CAS ??????
550-74-3(CAS DataBase Reference)
EPA
Picrolonic acid (550-74-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,Xi
?? ???? ?? 68-36/37/38-22-36/38-7
????? 37/39-26-36
????(UN No.) 3224
RTECS ?? UQ9510000
TSCA TSCA listed
HS ?? 29339900
????(GHS): Exclamation Mark (GHS07)Health Hazard (GHS08)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
H341 ???? ??? ??? ??? ??? (????? ???? ????? ???? ???? ???? ??? ?? ????? ??? ???? ??) ???? ???? ?? ?? 2 ?? P201,P202, P281, P308+P313, P405,P501
??????:
P201 ?? ? ?? ???? ?????.
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
0
1 0

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beige to ochre-yellow powder

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Reagent for the isolation of amines as crystalline π-complexes.Picrolonic acid is an analytical reagent used for the estimation of calcium, magnesium, lead, strontium and thorium. It is also used for the analysis of alkaloids, tryptophan and phenylalanine.

Purification Methods

Crystallise picrolic acid from water or EtOH (solubility is 0.123% at 15o and 1.203% at 100o in H2O; and 1.107% at 0o and 11.68% at 81o in EtOH). It forms Ca, Cu Hg, Mg, Na, Sr, Pb and many other metal complexes [Maquestian et al Bull Soc Chim Belg 82 233 1973, Isaki et al. Chem Ber 74 1420 1941]. [Beilstein 24 H 51, 24 I 218, 24 II 25, 22 III/IV 105.]

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