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WILFORINE

WILFORINE ??? ???

?? ??:: 11088-09-8

???:: WILFORINE

???(??):: WILFORINE;Wilforine-RM;26-Deoxywilfordine;Wilforine (Standard);Wilforine, 10 mM in DMSO;(8α)-8-(Acetyloxy)-2-O-benzoyl-2-O-deacetyl-8-deoxoevonimine;Evonimine, 8-(acetyloxy)-O2-benzoyl-O2-deacetyl-8-deoxo-, (8α)-;(8R,9R,10R,11S,12S,13R,14R,15S,18S,21S,22S,23R)-10,13,22,23-Tetrakis(acetyloxy)-12-[(acetyloxy)methyl]-14-(benzoyloxy)-7,8,9,10,12,13,14,15,19,20-decahydro-21-hydroxy-8,18,21-trimethyl-8,11-epoxy-9,12-ethano-11,15-m;8,11-Epoxy-9,12-ethano-11,15-methano-5H,11H-[1,9]dioxacyclooctadecino[4,3-b]pyridine-5,17(18H)-dione,10,13,22,23-tetrakis(acetyloxy)-12-[(acetyloxy)methyl]-14-(benzoyloxy)-7,8,9,10,12,13,14,15,19,20-decahydro-21-hydroxy-8,18,21-trimethyl-,(8R,9R,10R,11S,1;(8R,9R,10R,11S,12S,13R,14R,15S,18S,21S,22S,23R)-10,13,22,23-Tetrakis(acetyloxy)-12-[(acetyloxy)methyl]-14-(benzoyloxy)-7,8,9,10,12,13,14,15,19,20-decahydro-21-hydroxy-8,18,21-trimethyl-8,11-epoxy-9,12-ethano-11,15-methano-5H,11H-[1,9]dioxacyclooctadecino[4,3-b]pyridine-5,17(18H)-dione

CBNumber:: CB1994119

???:: C43H49NO18

??? ??:: 867.85

MOL ??:: 11088-09-8.mol

?? ?? 162

WILFORINE ??

???: 158-163℃

?? ?: 871.5±65.0 °C(Predicted)

??: 1.41

???: Soluble in methan

??? ??: ??

?? ?? (pKa): 11.70±0.70(Predicted)

??: White-yellowish

InChIKey: ZOCKGJZEUVPPPI-UHFFFAOYSA-N

SMILES: C(C12C(C(OC(C3C=CC=CC=3)=O)C3OC(C(CCC4=NC=CC=C4C(=O)OCC4(C)C(C(OC(=O)C)C1OC(=O)C)C(OC(=O)C)C2(C3(O)C)O4)C)=O)OC(=O)C)OC(=O)C

?? ? ?? ??
?? ? ???? ?? (GHS)

??	LD50 intraperitoneal in mouse: 418mg/kg

????(GHS):

?? ?:

Danger

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H301	??? ???	?? ?? ?? - ??	?? 3	??	P264, P270, P301+P310, P321, P330,P405, P501
H311	??? ???? ???	?? ?? ?? - ??	?? 3	??	P280, P302+P352, P312, P322, P361,P363, P405, P501
H331	???? ???	?? ?? ?? ??	?? 3	??	P261, P271, P304+P340, P311, P321,P403+P233, P405, P501

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P264	?? ??? ?? ??? ????.
P264	?? ??? ?? ??? ????.
P270	? ??? ??? ??? ???, ???? ???? ???.
P271	?? ?? ??? ? ?? ???? ?????.
P280	????/???/???/?????? ?????.
P302+P352	??? ??? ??? ?? ????.
P304+P340	???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P310	?? ????(??)? ??? ????. ???? ?? ????(??)? ??? ????.
P330	?? ?????.
P361	?? ??? ??? ?? ?? ?
P403+P233	??? ??? ? ?? ?? ??? ???? ?????.
P405	???? ?????.
P501	...? ??? / ??? ?? ???.

WILFORINE C??? ??, ??, ??

??

Present in Tripterygiurn wilfordii Hook, this base forms colourless plates when crystallized from MeOH-Me2CO. It has [α]^{25/sup>_D + 30° (Me2CO).
??
Wilforine is a major bioactive sesquiterpene alkaloid extracted from Tripterygium wifordii Hook F. displaying anti-inflammatory activity.
??
ChEBI: An organic heteropentacyclic compound and pyridine alkaloid with formula C43H49NO18 originally isolated from the roots of Tripterygium wilfordii.
?? ??
Beroza.,J. Arner. Chern. Soc., 74,3656 (1952)
Beroza., ibid, 75,44 (1953)
WILFORINE ?? ?? ? ???
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WILFORINE ?? ??

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???	??	???	??	?? ?	??
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Aktin Chemicals, Inc.	028-85159085	info@aktinchem.com	CHINA	1025	58

WILFORINE ?? ??:

?????? ???? ???? 2-????-4-????-4-?????????? Triptolide Celastrol Sinomenine WITHANOLIDE B(P)(NEW) WITHANOLIDE A(P) 4-[2-[(1S,2R,4aS,7S,8aR)-4a-[(Acetyloxy)methyl]-1,2,3,4,4a,7,8,8a-octahydro-7-hydroxy-5-(hydroxymethyl)-1,2-dimethyl-1-naphthalenyl]ethyl]-2(5H)-furanone L-Lysine Progesterone Xanthine Triptonine B WILFORTRINE WILFORLIDE A Wilfornine A WILFORGINE

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