ChemicalBook >?? ???? >tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ??? ???

?? ??:: 112741-49-8

???:: tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

???(??):: tert-butyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate;CIVENTICHEM CV-2654;CIVENTICHEM CV-2653;2-Oxo-7a-hydroxy Clopidogrel;(5S,6R)-N-BoC-5,6-diphenyl-2-morpholinone;(5S,6R)-N-Boc-5,6-diphenylmorpholin-2-one;(2R,3S)-(-)-N-Boc-6-oxo-2,3-diphenylMorpholine;tert-butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morph;(5R,6S)-(-)-4-Boc-5,6-diphenyl-2-Morpholinone, 98%;(2R,3S)-(-)-2,3-Diphenyl-6-oxomorpholine, N-BOC protected

CBNumber:: CB2424796

???:: C21H23NO4

??? ??:: 353.41

MOL ??:: 112741-49-8.mol

?? ?? 111

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ??

???: 206 °C (dec.)(lit.)

??: -87 º (c=5.5 in methylene chloride)

?? ?: 509.6±50.0 °C(Predicted)

??: 1.175±0.06 g/cm3(Predicted)

?? ??: 2-8°C

???: ???(?? ???, ??, ??? ??), ?????(?? ???), DMSO(?? ???, ??? ??)

?? ?? (pKa): -3.28±0.60(Predicted)

??? ??: ??

??? ??: ??? ??

??: ???? ?????

?? ??: [α]25/D 87°, c = 5.5 in methylene chloride

InChI: InChI=1S/C21H23NO4/c1-21(2,3)26-20(24)22-14-17(23)25-19(16-12-8-5-9-13-16)18(22)15-10-6-4-7-11-15/h4-13,18-19H,14H2,1-3H3/t18-,19+/m0/s1

InChIKey: MRUKRSQUUNYOFK-RBUKOAKNSA-N

SMILES: N1(C(OC(C)(C)C)=O)CC(=O)O[C@H](C2=CC=CC=C2)[C@@H]1C1=CC=CC=C1

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	Xi
?? ???? ??	36/37/38
?????	26-37/39
WGK ??	3
HS ??	2934999090
???? ???	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P264	?? ??? ?? ??? ????.
P264	?? ??? ?? ??? ????.
P271	?? ?? ??? ? ?? ???? ?????.
P280	????/???/???/?????? ?????.
P302+P352	??? ??? ??? ?? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

NFPA 704

	1
2		0

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate C??? ??, ??, ??

??? ??

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate is Off-white Solid

??

Tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate is a reactant used in the preparation of (-)-Jorumycin, (-)-Renieramycin G, 3-epi-Jorumycin, and 3-epi-Renieramycin G and colla gen cross-link pyridinolines.

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ?? ?? ? ???

???

N-(tert-Butyloxycarbonyl)-N-[(1S,2R)-2-hydroxy-1,2-diphenylethyl]-glycine Ethyl Ester p-??? ??? ???? ???

?? ??

(S)-N-Boc-????? (3S,5S,6R)-3-(3-Butenyl)-2-oxo-5,6-diphenyl-4-Morpholinecarboxylic Acid tert-Butyl Ester

tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ?? ??

???( 111)?? ??

???	??	???	??	?? ?	??
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tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ?? ??:

???? Carbamic acid, [(3S,4R)-tetrahydro-4-hydroxy-3-furanyl]-, 1,1-dimethylethyl 2-Methylmorpholine Phenylpropanolamine Ephedrine hemihydrate (5S)-N-(tert-Butoxycarbonyl)-3,4,5,6-tetrahydro-5-phenyl-4(H)-1,4-oxazin-2-one (-)-N-METHYLEPHEDRINE 2-(1-phenylethylamino)ethanol (R)-2-Methyl-morpholine (5R)-3,4,5,6-Tetrahydro-5-phenyl-4(H)-1,4-oxazin-2-one L-(-)-Ephedrine tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 1-N-BOC-2-METHYL MORPHOLINE BOC-L-Phenylglycinol (1R,2S)-2-Amino-1,2-diphenylethanol (S)-3-phenylmorpholine 5-Phenyl-2-morpholinone TERT-BUTYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE

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