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Tris(3-methoxyphenyl)phosphine

Tris(3-methoxyphenyl)phosphine ??? ???
?? ??:
29949-84-6
???:
Tris(3-methoxyphenyl)phosphine
???(??):
Tris(3-methoxyphenyl);tri(m-anisyl)phosphine;TRIS(M-ANISYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSP;ris(3-methoxyphenyl)phosphane;tris(3-Methoxyphenyl)phosphane;TRIS(M-METHOXYPHENYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSPHINE;Phosphine,tris(3-methoxyphenyl)-;Phosphine,tris(3-METHOXYBENZYL)-
CBNumber:
CB2490360
???:
C21H21O3P
??? ??:
352.36
MOL ??:
29949-84-6.mol

Tris(3-methoxyphenyl)phosphine ??

???
113-115 °C(lit.)
?? ?
476.3±40.0 °C(Predicted)
?? ??
Inert atmosphere,Room Temperature
??? ??
??? ??
??
???? ?? ??
InChI
InChI=1S/C21H21O3P/c1-22-16-7-4-10-19(13-16)25(20-11-5-8-17(14-20)23-2)21-12-6-9-18(15-21)24-3/h4-15H,1-3H3
InChIKey
CCXTYQMZVYIQRP-UHFFFAOYSA-N
SMILES
P(C1=CC=CC(OC)=C1)(C1=CC=CC(OC)=C1)C1=CC=CC(OC)=C1
CAS ??????
29949-84-6(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-37/39
WGK ?? 3
TSCA No
HS ?? 29310099
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
1
2 0

Tris(3-methoxyphenyl)phosphine C??? ??, ??, ??

??? ??

White to almost white crystalline powder

??

suzuki reaction

Synthesis

1-iodo-3-methoxybenzene could be used to synthesize Tri(o-anisole)phosphine (Tris(3-methoxyphenyl)phosphine). Reactions performed using 0.1mmol NaPH2, 2mol% PF6, 11equiv 1-iodo-3-methoxybenzene, 15equiv Et3N in 2.0mL MeCN under blue LED irradiation and N2 atmosphere for 24h[1]. 
TRIS(3-METHOXYPHENYL)PHOSPHINE

Tris(3-methoxyphenyl)phosphine ?? ?? ? ???

???

?? ??


Tris(3-methoxyphenyl)phosphine ?? ??

???( 186)?? ??
??? ?? ??? ?? ?? ? ??
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Tris(3-methoxyphenyl)phosphine ?? ??:

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