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??? ????? ??? ???
?? ??:
96-49-1
???:
??? ?????
???(??):
1,3-??????-2-?;????????;?????;????????;????-2;???????????;?????;??;1,3-?????-2-?;?????;??? ?????;?????-2;??? ??? ?????;??? ?????
???:
Ethylene carbonate
???(??):
1,3-DIOXOLAN-2-ONE;ETHYLENE CARBONATE (EC);Ethylencarbonat;1,3-dioxalan-2-one;Ethyene Carbonate;Carbonic acid, cyclic ethylene ester;NSC 11801;NSC 16568;Jeffsol EC;Texacar EC
CBNumber:
CB3488966
???:
C3H4O3
??? ??:
88.06
MOL ??:
96-49-1.mol
MSDS ??:
SDS

??? ????? ??

???
35-38 °C(lit.)
?? ?
243-244 °C740 mm Hg(lit.)
??
1.321 g/mL at 25 °C(lit.)
?? ??
3.04 (vs air)
???
0.02 mm Hg ( 36.4 °C)
???
1.4199
???
320 °F
?? ??
Store below +30°C.
???
H2O: 1 M at 20 °C, ??, ??
?? ?? (pKa)
3.86[at 20 ℃]
??? ??
??? ??? ??
Specific Gravity
1.321
??
???? ?????
??????(pH)
7 (200g/l, H2O, 20℃)
??
?? ??
????
3.6-16.1%(V)
???
214g/L(20℃)
BRN
106249
Henry's Law Constant
3.6×10-2 mol/(m3Pa) at 25℃, HSDB (2015)
Dielectric constant
69.4(91℃)
???
????. ?? ???, ?, ??, ???? ???? ????.
??? ?? ??
??
InChI
1S/C3H4O3/c4-3-5-1-2-6-3/h1-2H2
InChIKey
KMTRUDSVKNLOMY-UHFFFAOYSA-N
SMILES
O=C1OCCO1
LogP
0.11 at 20℃
CAS ??????
96-49-1(CAS DataBase Reference)
NIST
Ethylene carbonate(96-49-1)
EPA
Ethylene carbonate (96-49-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38-41
????? 26-36-39
????(UN No.) UN 2265 3 / PGIII
WGK ?? 1
RTECS ?? FF9550000
?? ?? ?? 465 °C
TSCA TSCA listed
HS ?? 29209010
???? ??? 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
STOT RE 2 Oral
?? ?? ??? 96-49-1(Hazardous Substances Data)
?? LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
???? ?? KE-12028
????(GHS): Exclamation Mark (GHS07)Health Hazard (GHS08)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H373 ??? ?? ?? ???? ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ? ?? ?? ???? ?? - ?? ?? ?? 2 ?? P260, P314, P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P314 ???? ??? ???? ??·??? ????.
NFPA 704
1
1

??? ????? MSDS


1,3-Dioxolan-2-one

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??? ????? (EC)? ?? ?? 1,3- ?? ?? -2- ?; ??? ??? ?????; ??? ?? ????. ? ??? ???? ???? ??? ??? ????? ???? ?? ??? ?????.

??

??? ?? ? ??? (EC)? ??? ??, ? ??? ????? ???, ?? ?? ??? ??? ??, ?? ????? ??? ?? ??? ? ?? ??? ????? ??? ? ???? ??? ? ? ?? ??????.

??? ??

colourless crystals

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Ethylene carbonate is an ester of ethylene glycol and carbonic acid. Ethylene carbonate is used as a polar solvent with a molecular dipole moment of 4.9 D, only 0.1 D lower than that of propylene carb onate. It can be used as a high permittivity component of electrolytes in lithium batteries.

Purification Methods

Dry 1,3-dioxolan-2-one over P2O5, then fractionally distil it at low or atmospheric pressure. Recrystallise it from dry Et2O (plates, m 36.5o, 38.5-40o was also reported). It is soluble in H2O. [Beilstein 19 II 135,19 III/IV 1556, 19/4 V 6.]

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