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?? ??:
1667-99-8
???:
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???(??):
?????;?????S;?? ??? S
???:
Mordant Blue 29
???(??):
CHROME AZUROL S;Alberon;S NO 841;CI 43825;CI NO 43825;Mordantblue;CHROMAZUROL S;ChomeazurolS;S,ChroMeazurol;Chrome Azure S
CBNumber:
CB3724341
???:
C23H13Cl2Na3O9S
??? ??:
605.28
MOL ??:
1667-99-8.mol
MSDS ??:
SDS

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?? ??
room temp
???
water: 0.1%
?? ?? ??
43825
??? ??
??
?? ?? (pKa)
pK1:2.45;pK2:4.86;pK3:11.47 (25°C)
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??
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???
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?? ??(λmax)
458 nm
ε (????)
≥9000 at 424-436nm in H2O at 0.03g/L
≥9000 at 424-436nm in H2O
BRN
4110655
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InChIKey
FUIZKNBTOOKONL-NDOZRWCBSA-K
SMILES
C(=C1/C=C(C(=O)C(C([O-])=O)=C/1)C)(/C1=CC(=C(O)C(C([O-])=O)=C1)C)\C1C(Cl)=CC=C(S([O-])(=O)=O)C=1Cl.[Na+].[Na+].[Na+]
EPA
Benzoic acid, 5-[(3-carboxy-5-methyl-4-oxo-2,5-cyclohexadien-1-ylidene)(2,6-dichloro-3-sulfophenyl)methyl]-2-hydroxy-3-methyl-, trisodium salt (1667-99-8)
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  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 3
TSCA TSCA listed
HS ?? 29189900
???? ??? 11 - Combustible Solids
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
NFPA 704
0
1 0

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dark brown powder

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Chromeazurol S (cas# 1667-99-8) is a compound useful in organic synthesis.Dyes and metabolites.

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2,4-Dichloro-3-formylbenzenesulfonic acidand 2-Hydroxy-3-methylbenzoic acid condensation, its product oxidation and changed into sodium salt.

Purification Methods

The crude phenolic triphenylmethanecarboxysulfonic acid triNa salt (40g) is dissolved in water (250mL) and filtered. Then conc HCl (50mL) is added to the filtrate, with stirring. The precipitate is filtered off, washed with HCl (2M) and dried. It is redissolved in water (250mL), and precipitation is repeated twice more in a water bath at 70o. It is dried under vacuum over solid KOH (first), then P2O5 [Martynov et al. Zh Analyt Khim 32 519 1977]. It has also been purified by paper chromatography using n-butanol, acetic acid and water (7:3:1). First and second spots were extracted. It chelates Al and Be. It is used also for estimating fluoride. [Beilstein 11 IV 707.]

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