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3-Bromoquinoline

3-Bromoquinoline ??? ???
?? ??:
5332-24-1
???:
3-Bromoquinoline
???(??):
Bromoquinoline;Quinoline, 3-bromo-;NSC 3995;CETH-016;3-BromoquinoL;3-BROMOQUINOLINE;3-BROMOQUINLIINE;3-bromo-quinolin;3-Bromoquuinoline;1-3-Bromoquinoline
CBNumber:
CB4220082
???:
C9H6BrN
??? ??:
208.05
MOL ??:
5332-24-1.mol
MSDS ??:
SDS

3-Bromoquinoline ??

???
13-15 °C (lit.)
?? ?
274-276 °C (lit.)
??
1.533 g/mL at 25 °C (lit.)
???
0.196Pa at 25℃
???
n20/D 1.664(lit.)
???
>230 °F
?? ??
Keep in dark place,Inert atmosphere,Room temperature
??? ??
??
?? ?? (pKa)
2.69(at 25℃)
??
??~???? ???
???
103mg/L at 25℃
BRN
112939
InChI
1S/C9H6BrN/c10-8-5-7-3-1-2-4-9(7)11-6-8/h1-6H
InChIKey
ZGIKWINFUGEQEO-UHFFFAOYSA-N
SMILES
Brc1cnc2ccccc2c1
LogP
3.03
CAS ??????
5332-24-1(CAS DataBase Reference)
NIST
Quinoline, 3-bromo-(5332-24-1)
EPA
Quinoline, 3-bromo- (5332-24-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36-37/39
????(UN No.) UN2810
WGK ?? 3
TSCA TSCA listed
HS ?? 29334900
???? ??? 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

3-Bromoquinoline MSDS


3-Bromoquinoline

3-Bromoquinoline C??? ??, ??, ??

??? ??

colorless to light yellow liquid

Synthesis Reference(s)

The Journal of Organic Chemistry, 27, p. 1318, 1962 DOI: 10.1021/jo01051a047

?? ??

3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.

3-Bromoquinoline ?? ?? ? ???

???

?? ??


3-Bromoquinoline ?? ??

???( 425)?? ??
??? ?? ??? ?? ?? ? ??
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3-Bromoquinoline ?? ??:

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