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7789-23-3
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???(??):
??????????;????????(KF);???F;???????????(KF);?????????,???;???????;???????(????);???????;????;?????????;?????? ??;????;????? ??
???:
Potassium fluoride
???(??):
KF;SDKF;Fluorure de potassium;Potassiumfluoride,anhydrous;potassium fluoride spray dried;DG 18;Potassium fL;MANNITOL SALT;Kaliumfluorid;SUCROSE, MOLECUL
CBNumber:
CB4237549
???:
FK
??? ??:
58.1
MOL ??:
7789-23-3.mol
MSDS ??:
SDS

??????? ??

???
858 °C (lit.)
?? ?
1505 °C
??
2.48
?? ??
400kg/m3
?? ??
2 (vs air)
???
1.3 hPa (885 °C)
???
1.363
???
1505°C
?? ??
Store at +5°C to +30°C.
???
H2O: 1 M at 20 °C, ??, ??
??? ??
?? ???
Specific Gravity
2.481
??
???
??????(pH)
7.0-8.5 (25℃, 1M in H2O)
??
?? ??
???
92.3g/100mL(18℃)
????
7.113 W/(m·K)
??
Cp(crystal): 0.84 J/(g·K), at 25℃
Crystal Structure
NaCl type
??
Hygroscopic
?? ??(λmax)
λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01
Merck
14,7632
crystal system
Cube
Space group
Fm3m
BRN
3902818
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.5340.5340.5349090900.1526
?? ??
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
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????. ????? ??????. ??, ???? ???? ????.
??? ?? ??
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?? ??
InChI
1S/FH.K/h1H;/q;+1/p-1
InChIKey
NROKBHXJSPEDAR-UHFFFAOYSA-M
SMILES
[F-].[K+]
LogP
-0.77 at 25℃
CAS ??????
7789-23-3(CAS DataBase Reference)
NIST
Potassium fluoride(7789-23-3)
EPA
Potassium fluoride (7789-23-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T
?? ???? ?? 25-23/24/25
????? 45-26-36/37
????(UN No.) UN 1812 6.1/PG III (POTASSIUM FLUORIDE, SOLID)
????(UN No.) UN 3422 6.1/PG III (POTASSIUM FLUORIDE SOLUTION)
WGK ?? 3
RTECS ?? TT0700000
F ?????? 3
?? ?? ?? Harmful
TSCA TSCA listed
HS ?? 2826 19 90
?? ?? 6.1
???? III
???? ??? 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Eye Dam. 1
?? ?? ??? 7789-23-3(Hazardous Substances Data)
?? MLD in guinea pigs (mg/kg): 250 orally, 350 s.c.; in frogs (mg/kg): 375 s.c. (Simonin)
???? ?? KE-29114
?????? ??? 97-1-384
?? ? ???? ????: ????; ???(??)????: ????? ?? ? ?? 25% ?? ??? ???
????(GHS): Skull and Crossbones (GHS06)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H301 ??? ??? ?? ?? ?? - ?? ?? 3 ?? P264, P270, P301+P310, P321, P330,P405, P501
H311 ??? ???? ??? ?? ?? ?? - ?? ?? 3 ?? P280, P302+P352, P312, P322, P361,P363, P405, P501
H331 ???? ??? ?? ?? ?? ?? ?? 3 ?? P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P301+P310 ???? ?? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P311 ????(??)? ??? ????.
P312 ???? ??? ????(??)? ??? ????.
P330 ?? ?????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
3 0

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Potassium fluoride is a white crystalline solid.

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Potassium fluoride is used in metal finishing, batteries, coatings and photographic chemicals. It is utilized for the study of ion-specific swelling and de-swelling of ampholytic polymer gels as well as in the measurement of electronic polarizabilities of ions in polymers of alkali halides. It finds application in the electronic industry as a metal surface treatment product. It is used as a preservative, a food additive, a catalyzer and a water absorbing agent. In the Finkelstein reaction, it is actively involved in the conversion of chlorocarbons to fluorocarbons using polar solvents like dimethyl formamide and ethylene glycol.

?? ???

Potassium fluoride reacts with acids to evolve corrosive and toxic hydrogen fluoride. Aqueous solutions corrode glass and consequently are prepared and stored in polyethylene containers. The pure solid may be stored in glass containers. Reacts violently with (Pt + BrF3). [NTP 1992].

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Toxic by ingestion and inhalation, strong irritant to tissue.

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TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

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Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by subcutaneous route. Experimental teratogenic effects. A corrosive irritant to the eyes, skin, and mucous membranes. Mutation data reported. A very reactive material. When heated to decomposition it emits toxic fumes of K2O and F-. Used in etchmg glass, as a presewative, as an insecticide, and in organic synthesis. See also FLUORIDES and HYDROFLUORIC ACID.

??? ??

Potassium fluoride is used in etching glass; as a preservative and insecticide.

?? ??

UN1812 Potassium fluoride, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

? ???

Incompatible with strong acids; reacts releasing hydrogen fluoride. Aqueous solutions corrode glass and consequently are prepared and stored in polyeth- ylene containers. The pure solid may be stored in glass containers. Reacts violently with (Pt 1 BrF 3 )

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