(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ??
- ?? ?
- 73-76 °C9 mm Hg(lit.)
- ??
- 1.3 g/mL at 25 °C(lit.)
- ???
- n
20/D 1.462(lit.)
- ???
- 184 °F
- ?? ??
- Inert atmosphere,Room Temperature
- ??? ??
- ??
- ?? ?? (pKa)
- 11.91±0.10(Predicted)
- ??
- ??~??? ??
- ?? ??
- [α]20/D +31.3±0.5°, neat
- BRN
- 2327547
- InChI
- 1S/C8H7F3O/c9-8(10,11)7(12)6-4-2-1-3-5-6/h1-5,7,12H/t7-/m0/s1
- InChIKey
- VNOMEAQPOMDWSR-ZETCQYMHSA-N
- SMILES
- O[C@@H](c1ccccc1)C(F)(F)F
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- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi,C | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36 | ||
| ????(UN No.) | NA 1993 / PGIII | ||
| WGK ?? | 3 | ||
| F ?????? | 10-23 | ||
| HS ?? | 29062990 | ||
| ???? ??? | 10 - Combustible liquids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL C??? ??, ??, ??
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(S)-(+)-α-(Trifluoromethyl)benzyl Alcohol is used in the synthesis of metal-organic framework compounds which may have mesoporous properties.Purification Methods
Purify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.](S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ?? ?? ? ???
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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ?? ??
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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ?? ??:
1-??-2,2,2-????????? ?????????
(R)-1-(3-BROMOPHENYL)ETHANOL
(R)-(+)-alpha-Methoxy-alpha-trifluoromethylphenylacetic acid
(S)-(+)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL
1,4-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE
1,3-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE
4-(2-HYDROXYHEXAFLUOROISOPROPYL)BENZOIC ACID
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
(S)-(+)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE
HEXAFLUORO-2-(P-TOLYL)ISOPROPANOL
4-(HEXAFLUORO-2-HYDROXYISOPROPYL)ANILINE
1-PHENYL-2,2,2-TRIFLUOROETHANOL
BIS(4-FLUOROPHENYL)TRIFLUOROMETHYL CARBINOL
BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR
ALPHA-(TRIFLUOROMETHYL)BENZHYDROL
2-(2,5-Dimethylphenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol
4,4'-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BIPHENYL