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2,6-????-1,4-????

2,6-????-1,4-????
2,6-????-1,4-???? ??? ???
?? ??:
697-91-6
???:
2,6-????-1,4-????
???(??):
2,6-????-1,4-????
???:
2,6-DICHLORO-1,4-BENZOQUINONE
???(??):
2,6-Dichloroquinone;2,6-Dichlorobenzoquinone;2,6-DICHLORO-P-QUINONE;2,6-Dichloquinone;2,6-dichloro-p-quinon;LABOTEST-BB LT00159342;p-Quinone, 2,6-dichloro-;2,6-dichloro-p-benzoquinon;2,6-Dichoro-p-benzoquinone;benzoquinone,2,6-dichloro-
CBNumber:
CB4445591
???:
C6H2Cl2O2
??? ??:
176.98
MOL ??:
697-91-6.mol
MSDS ??:
SDS

2,6-????-1,4-???? ??

???
122-124 °C(lit.)
?? ?
251.81°C (rough estimate)
??
1.5138 (rough estimate)
???
1.4595 (estimate)
?? ??
Hygroscopic, -20°C Freezer, Under inert atmosphere
???
DMSO(?? ???), ???(?? ???)
??? ??
??
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??
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???
?? ???. ???? ?? ???(?? ???).
???
???
InChI
InChI=1S/C6H2Cl2O2/c7-4-1-3(9)2-5(8)6(4)10/h1-2H
InChIKey
JCARTGJGWCGSSU-UHFFFAOYSA-N
SMILES
C1(=O)C(Cl)=CC(=O)C=C1Cl
CAS ??????
697-91-6(CAS DataBase Reference)
EPA
2,5-Cyclohexadiene-1,4-dione, 2,6-dichloro- (697-91-6)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 3
RTECS ?? DK4000000
TSCA TSCA listed
HS ?? 2914698090
???? ??? 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
2 0

2,6-????-1,4-???? C??? ??, ??, ??

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yellow crystalline powder

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2,6-Dichloro-1,4-benzoquinone is the suitable reagent used to in a study to evaluate the diffusion coefficients (D) for a family of quinones, nitroaromatics, ferrocenes and aromatic hydrocarbon compounds, in acetonitrile by single potential step chronoamperometry.1 It may be used in the preparation of 2,3,5-Trichloro-1,4-dihydroquinone, 2,3,5-trichloro-1,4-benzoquinone and 2,6-Dichloro-1,4-dihydroquinone.

?? ??

2,6-Dichloro-1,4-benzoquinone (DCBQ, 2,6-DCBQ) is a halobenzoquinone. Halobenzoquinones are disinfection byproducts (DBPs) found in drinking water. They are capable of producing reactive oxygen species and causing oxidative damage to proteins and DNA in T24 human bladder carcinoma cells. UV-induced transformation of DCBQ in drinking water has been reported. Detection of DCBQ in drinking water by liquid chromatography-ESI tandem mass spectrometry has been reported.

Purification Methods

Recrystallise the quinone from pet ether (b 60-70o). It sublimes at 41o/17.6. [Carlson & Miller J Am Chem Soc 107 479 1985, Beilstein 7 II 580. 7 III 3376.]

2,6-????-1,4-???? ?? ?? ? ???

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