2-Methyl-3-nitroaniline
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2-Methyl-3-nitroaniline ??
- ???
- 88-90 °C (lit.)
- ?? ?
- 305 °C (lit.)
- ??
- 1.378
- ???
- 1.6394 (estimate)
- ???
- 305°C
- ?? ??
- Store below +30°C.
- ???
- <1mg/L
- ??? ??
- ??? ??
- ?? ?? (pKa)
- 2.31±0.10(Predicted)
- ??
- ????? ?????
- ???
- 23&C?? <0.1g/100mL
- BRN
- 388393
- InChI
- 1S/C7H8N2O2/c1-5-6(8)3-2-4-7(5)9(10)11/h2-4H,8H2,1H3
- InChIKey
- HFCFJYRLBAANKN-UHFFFAOYSA-N
- SMILES
- Cc1c(N)cccc1[N+]([O-])=O
- CAS ??????
- 603-83-8(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | T,N | ||
|---|---|---|---|
| ?? ???? ?? | 23/24/25-33-51/53 | ||
| ????? | 28-36/37-45-61-28A | ||
| ????(UN No.) | UN 2660 6.1/PG 3 | ||
| WGK ?? | 3 | ||
| RTECS ?? | XU8200000 | ||
| ?? ?? ?? | Toxic | ||
| ?? ?? | 6.1 | ||
| ???? | III | ||
| HS ?? | 29214300 | ||
| ???? ??? | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
||
| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 2 STOT RE 2 |
2-Methyl-3-nitroaniline C??? ??, ??, ??
??? ??
YELLOW TO GREENISH-YELLOW CRYSTALLINE POWDER??
2-Amino-6-nitrotoluene (2-Methyl-3-nitroaniline) has been used as a standard while evaluating the potential for degradation of nitroaromatic compounds by indigenous microorganisms.?? ??
6-Nitro-o-toluidine is produced by sulfide reduction of 2,6-dinitrotoluene in a process similar to that for 3-nitroaniline or by controlled hydrogenation of 2,6-dinitrotoluene with palladium on a carbon catalyst.?? ??
Yellow rhombic needles (from water) or bright yellow powder.??? ?? ??
2-Methyl-3-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.?? ???
2-Methyl-3-nitroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers.????
Flash point data for 2-Methyl-3-nitroaniline are not available; however, 2-Methyl-3-nitroaniline is probably combustible.Purification Methods
Crystallise the nitrotoluidine from EtOH or *C6H6. It is steam volatile. The acetyl derivative crystallises from aqueous EtOH and has m 164o. [Beilstein 12 I 395, 12 II 460, 12 III 1944, 2 IV 1811.]2-Methyl-3-nitroaniline ?? ?? ? ???
???
?? ??
1H-???-4-??
4-????????
4-???-1H-???
2-Fluoro-6-nitrobenzoic acid
2-???-6-??????
2-??-4-?????
1-???-2-(?????)-3-?????
1-(Benzyloxy)-2-methyl-3-nitrobenzene
4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-1H-INDAZOLE
4-????(1H)???
4-???-2-??-3-??????
5-(2-METHYL-3-NITROPHENYL)-2-FURALDEHYDE
2'-??-3'-?????????
2-Methyl-3-nitroaniline ?? ??
???( 359)?? ??
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