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????(IV)?????

????(IV)?????
????(IV)????? ??? ???
?? ??:
3087-36-3
???:
????(IV)?????
???(??):
????(IV)?????;????(IV)?????(TITANIUM(IV)ETHOXIDE)
???:
Titanium ethoxide
???(??):
Ti(OEt)4;TITANIUM(IV) ETHOXIDE;TETRAETHYL TITANATE;TITANIUM TETRAETHOXIDE;Tetraethoxy titanium;ETHYL ORTHOTITANATE;TETRAETHYL ORTHOTITANATE;Titanium(IV) ethanolate;TitaniuM tetraethanolate;VERTEC(TM) ET
CBNumber:
CB5152902
???:
C8H20O4Ti
??? ??:
228.11
MOL ??:
3087-36-3.mol
MSDS ??:
SDS

????(IV)????? ??

???
54°C
?? ?
150-152 °C10 mm Hg(lit.)
??
1.088 g/mL at 25 °C(lit.)
???
57.26hPa at 19.6℃
???
n20/D 1.505(lit.)
???
84 °F
?? ??
2-8°C
???
?? ??? ?????.
??? ??
??
Specific Gravity
1.107 (20℃)
??
?? ??
???
?? ??
??
Moisture Sensitive
BRN
3678992
???
??? ????, ??? ??? ? ????. ??? ??? ???? ??? ? ????.
??? ?? ??
BINDING
InChI
1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
InChIKey
JMXKSZRRTHPKDL-UHFFFAOYSA-N
SMILES
CCO[Ti](OCC)(OCC)OCC
LogP
-0.3 at 25℃
CAS ??????
3087-36-3(CAS DataBase Reference)
NIST
Ti(OEt)4(3087-36-3)
EPA
Ethanol, titanium(4+) salt (3087-36-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 10-36/37/38-67
????? 26-37/39-16
????(UN No.) UN 1993 3/PG 3
WGK ?? 3
F ?????? 3-10-21
TSCA TSCA listed
?? ?? 4.1
???? III
HS ?? 29051900
???? ??? 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 3
???? ?? KE-13224
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P240 ??? ????? ?? ? ??????.
P241 ?? ??? ??[???/??/??/...]?(?) ?????.
P242 ???? ???? ?? ??? ?????
P243 ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P370+P378 ?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P403+P235 ??? ? ?? ?? ???? ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
2
2 0

????(IV)????? MSDS


Ethyl titanate

????(IV)????? C??? ??, ??, ??

??? ??

colourless liquid

??

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :

?? ??

Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Materials Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

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????(IV)????? ?? ??:

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