???(??????)??
|
|
???(??????)?? ??
- ?? ?
- 73 °C/5 mmHg (lit.)
- ??
- 0.806 g/mL at 25 °C (lit.)
- ???
- n
20/D 1.489(lit.)
- ???
- 55 °C
- ?? ??
- Flammables area
- ??? ??
- ??
- ??
- Clear, colourless
- Specific Gravity
- 0.806
- ???
- ??, ???, ???, ????????? ?? ??. ??? ? ??????? ?? ??? ????. ?? ??? ????.
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- ??
- Light Sensitive
- Merck
- 14,9757
- BRN
- 1923953
- InChI
- InChI=1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
- InChIKey
- SQMFULTZZQBFBM-UHFFFAOYSA-N
- SMILES
- [Si](C)(C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C
- CAS ??????
- 1873-77-4(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 10-36/37/38 | ||
| ????? | 16-26-36 | ||
| ????(UN No.) | UN 1993 3/PG 3 | ||
| WGK ?? | 3 | ||
| F ?????? | 10-23 | ||
| TSCA | No | ||
| ?? ?? | 3 | ||
| ???? | II | ||
| HS ?? | 29319090 | ||
| ???? ??? | 3 - Flammable liquids | ||
| Hazard Classifications | Flam. Liq. 3 |
???(??????)?? C??? ??, ??, ??
??? ??
clear colorless to pale yellow liquid??
Tris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.?? ??
Tris(trimethylsilyl)silane is an organosilicon generally used as a radical reducing agent for xanthates, organic halides, isocyanides, selenides, and acid chlorides. It is also used for hydrosilylation of alkenes, alkynes, and dialkyl ketones.Purification Methods
Purify it by fractional distillation and taking the middle cut. Store it under N2 or Ar as it is PYROPHORIC and is an IRRITANT. [Chatgilialoglu et al. J Org Chem 53 3641 1988, Balestri et al. J Org Chem 56 678 1991, Chatgilialoglu Acc Chem Res 25 188 1992, NMR: Gilman et al. J Organomet Chem 4 163 1965.]???(??????)?? ?? ?? ? ???
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?? ??
???(??????)?? ?? ??
???( 180)?? ??
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|---|---|---|---|---|---|
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???(??????)?? ?? ??:
???(??????)??
TRIS(TRIMETHYLSILYL)METHANE
TRIS(TRIMETHYLSILYL)GERMANIUM HYDRIDE
Triphenylmethyl Chloride
Trifluoromethyl iodide
TRIBUTYLPROPYNYLSTANNANE
Tris(trimethylsilyl)phosphate
[TRIS(TRIMETHYLSILOXY)SILYLETHYL]DIMETHYLCHLOROSILANE
TETRAKIS(TRIMETHYLSILYL)SILANE
CHLOROTRIS(TRIMETHYLSILYL)SILANE
SALOR-INT L170593-1EA
SALOR-INT L170410-1EA
SALOR-INT L170399-1EA
SALOR-INT L170615-1EA
SALOR-INT L170429-1EA
SALOR-INT L170437-1EA
(2,4,6-Trimethylphenyl)tris(trimethylsilyl)silane
Trifluoroacetyl-tris(trimethylsilyl)silane