ChemicalBook >?? ???? >?? ???>??? ?? ?? ???>?? ???>4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ??? ???

?? ??:: 51325-91-8

???:: 4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN

???(??):: 4-(DICYANOMETHYLENE)-2-METHYL-6-(P-DIMETHYLAMINOSTYRYL)-4H-PYRAN;lidene]-;initrile;DCM (merocyanine);(dicyanomethylene)-methyl-(4-dimethylaminostyryl)-4H-pyran;DCM1 , 4-(DicyanoMethylene)-2-Methyl-6-(p-diMethylaMinostyry;E)-2-(2-(4-(dimethylamino)styryl)-6-methyl-4H-pyran-4-ylidene);[2-[2-[4-(dimethylamino)phenyl]vinyl]-6-methyl-4H-pyran-4-yl...;4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN;4-(Dicyanomethylene)-6-[4-(dimethylamino)styryl]-2-methyl-4H-pyran

CBNumber:: CB5273409

???:: C19H17N3O

??? ??:: 303.36

MOL ??:: 51325-91-8.mol

MSDS ??:: SDS

?? ?? 136

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ??

???: 215-220 °C(lit.)

?? ?: 444.29°C (rough estimate)

??: 1.239

???: 1.5900 (estimate)

???: 110 °F

?? ??: Sealed in dry,Room Temperature

?? ?? (pKa): 5.46±0.24(Predicted)

??? ??: ?? ?? ?? ???

??: ?? ???

??: Dark red to Brown powder to crystal

?? ??(λmax): 468 nm

Merck: 14,2838

InChI: InChI=1S/C19H17N3O/c1-14-10-16(17(12-20)13-21)11-19(23-14)9-6-15-4-7-18(8-5-15)22(2)3/h4-11H,1-3H3

InChIKey: YLYPIBBGWLKELC-UHFFFAOYSA-N

SMILES: C(#N)/C(=C1/C=C(C)OC(C=CC2=CC=C(N(C)C)C=C2)=C/1)/C#N

EPA: Propanedinitrile, [2-[2-[4-(dimethylamino)phenyl]ethenyl]-6-methyl-4H-pyran-4-ylidene]- (51325-91-8)

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	F,Xn
?? ???? ??	11-20-36/37/38-20/21/22-10
?????	16-26-36-7/9-36/37
????(UN No.)	UN 3175 4.1/PG 2
WGK ??	3
RTECS ??	OO3746100
TSCA	TSCA listed
?? ??	4.1
????	III
HS ??	29329990
???? ???	4.1B - Flammable solid hazardous materials
Hazard Classifications	Acute Tox. 4 Inhalation Eye Irrit. 2 Flam. Sol. 1 Skin Irrit. 2 STOT SE 3

????(GHS):

?? ?:

Danger

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H228	??? ??	??? ??	?? 1 ?? 2	?? ??	P210, P240,P241, P280, P370+P378
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H332	???? ???	?? ?? ?? ??	?? 4	??	P261, P271, P304+P340, P312
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P210	?·???·??·????? ????? - ?? ???.
P240	??? ????? ?? ? ??????.
P241	?? ??? ??[???/??/??/...]?(?) ?????.
P302+P352	??? ??? ??? ?? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

NFPA 704

	2
1		0

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN C??? ??, ??, ??

??? ??

red/brown crystals

??

Laser dye.

?? ??

4-(Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) is a red laser dye that consists of dicyanomethylene as an electron acceptor and dimethylaniline group as an electron donor. It has a π-conjugated 4H-pyran-4-ylidiene which bridges both the acceptor/donor groups. It can be used as a dopant and also in organic solid state lasers.

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ?? ?? ? ???

???

?? ??

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ?? ??

???( 136)?? ??

???	??	???	??	?? ?	??
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4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ?? ??:

??? ??? ??? ?????? Tris(acetylacetonato)(1,10-phenanthroline)europium(III) Ir(piq)3, Tris[1-phenylisoquinolinato-C2,N]iridium(III) 4-(Dicyanomethylene)-2-methyl-6-(julolidin-4-ylvinyl)-4H-pyran TRIS(DIBENZOYLMETHANE)MONO(PHENANTHROLINE)EUROPIUM (III) 4-(Dicyanomethylene)-2-methyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (2,6-Dimethyl-4H-pyran-4-ylidene)malononitrile 4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN 4-(Dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran ALLYL VINYL ETHER Vinyl ether 2,4-HEXADIENENITRILE ISOPROPYLIDENEMALONONITRILE 1,3,6-HEPTATRIENE 4-Dicyanomethylene-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) DCC/DCM

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4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ??

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN C??? ??, ??, ??

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4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ?? ?? ? ???

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4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ?? ??

4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN ?? ??: