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Citronellyl tiglate

Citronellyl tiglate ??? ???
?? ??:
24717-85-9
???:
Citronellyl tiglate
???(??):
Rhodinyl tiglate;Einecs 246-426-2;Citronellyltiglat;CITRONELLYL TIGLATE;Citronellol tiglate;E-Citronellyl tiglate;CITRONELLYL-CROTONATE;D-Citronellyl tiglate;β-Citronellol tiglate;[R,(+)]-Citronellyl tiglate
CBNumber:
CB5394401
???:
C15H26O2
??? ??:
238.37
MOL ??:
24717-85-9.mol

Citronellyl tiglate ??

?? ?
144-145 °C9 mm Hg(lit.)
??
0.903 g/mL at 25 °C(lit.)
???
1.4Pa at 25℃
???
n20/D 1.465(lit.)
FEMA
4295 | CITRONELLYL TRANS-2-METHYL-2-BUTENOATE
???
>230 °F
??
?? ?? ?? ???? ??.
??
100.00%??. ?? ???? ?? ??? ??? ?? ?? ?
?? ??
???
???
385μg/L at 20℃
JECFA Number
1823
??? ?? ??
PERFUMING
InChI
1S/C15H26O2/c1-6-14(5)15(16)17-11-10-13(4)9-7-8-12(2)3/h6,8,13H,7,9-11H2,1-5H3/b14-6+
InChIKey
UCFQYMKLDPWFHZ-MKMNVTDBSA-N
SMILES
O(CCC(CCC=C(C)C)C)C(=O)\C(=C\C)\C
LogP
5.99 at 25℃
NIST
Citronellyl tiglate(24717-85-9)
EPA
2-Butenoic acid, 2-methyl-, 3,7-dimethyl-6-octenyl ester, (2E)- (24717-85-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
WGK ?? 2
TSCA TSCA listed
???? ??? 10 - Combustible liquids
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1
?? Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
????(GHS): Exclamation Mark (GHS07)Environment (GHS09)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
H412 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 3 P273, P501
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P272 ??? ??? ??? ??? ???? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P321 (…) ??? ???.
P330 ?? ?????.
P333+P313 ????? ?? ??? ???? ???? ??·??? ????.
P363 ?? ??? ??? ??? ?????.
P391 ???? ????.
P501 ...? ??? / ??? ?? ???.

Citronellyl tiglate C??? ??, ??, ??

??? ??

Citronellyl Tiglate is a liquid with a floral, rosy, fruity, mushroomlike odor. It is used in geranium oil reconstitutions.

??

Reported found in geranium petiole oil India (3.93%), geranium stem oil India (1.88%), geranium leaf oil Rwanda (0.14%) and geranium leaf oil India (1.40%).

??

Rarely offered commercially, Citronellyl tiglate has been suggested for use in floral and herbaceous fragrances, including better soap perfumes. It has considerable power and good effect in i soap, but there are many related chemicals, some less expensive, others more freely available, with similar effects.

?? ??

By direct esterification of citronellol with 2-butenoic acid under azeotropic conditions (Arctander. 1969).

Citronellyl tiglate ?? ?? ? ???

???

?? ??


Citronellyl tiglate ?? ??

???( 41)?? ??
??? ?? ??? ?? ?? ? ??
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Citronellyl tiglate ?? ??:

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