CHLOROMETHYL PHENYL SULFIDE
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CHLOROMETHYL PHENYL SULFIDE ??
- ?? ?
- 66 °C/0.2 mmHg (lit.)
- ??
- 1.184 g/mL at 25 °C (lit.)
- ???
- n
20/D 1.594(lit.)
- ???
- 214 °F
- ?? ??
- 2-8°C
- ???
- sol most organic solvents; insol H2O
- ??? ??
- ??
- ??
- ??~??? ??
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- Stench
- BRN
- 1617369
- InChI
- 1S/C7H7ClS/c8-6-9-7-4-2-1-3-5-7/h1-5H,6H2
- InChIKey
- LLSMWLJPWFSMCP-UHFFFAOYSA-N
- SMILES
- ClCSc1ccccc1
- CAS ??????
- 7205-91-6(CAS DataBase Reference)
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- ?? ? ???? ?? (GHS)
| ????? | 23-24/25 | ||
|---|---|---|---|
| ????(UN No.) | UN 3334 | ||
| WGK ?? | 3 | ||
| F ?????? | 10-13 | ||
| ?? ?? ?? | Stench | ||
| ?? ?? | 4.1 | ||
| ???? | III | ||
| HS ?? | 29309099 | ||
| ???? ??? | 10 - Combustible liquids | ||
| ???? ?? | KE-05769 |
CHLOROMETHYL PHENYL SULFIDE C??? ??, ??, ??
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Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.1Synthesis
The two most convenient methods of chloromethyl phenyl sulfide are the reaction of Thioanisole with Sulfuryl Chloride and the reaction of Thiophenol with bromochloromethane using 1,8-Diazabicyclo[5.4.0]undec-7-ene or an alkali metal hydroxide as the base.??
Chloromethyl phenyl sulfideshould be handled in a well-ventilated fume hood and kept cooled. Freshly prepared material can be stored at 0-5 °C without any appreciable decomposition. It is advisable to use freshly prepared or distilled material for reactions.Purification Methods
Dissolve the sulfide in CH2Cl2 or CCl4 and dry it (CaCl2), or pass it through a tube of CaCl2 and distil it using a fractionating column. Harmful vapours. It gives the sulfone [7205-98-3] (b 130o/1mm and m 53o from EtOH) [Beilstein 6 IV 1507] on oxidation with permonophthalic acid. [B.hme et al. Justus Liebigs Ann Chem 563 54 64 1949.] [Beilstein 6 III 1002.]CHLOROMETHYL PHENYL SULFIDE ?? ?? ? ???
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CHLOROMETHYL PHENYL SULFIDE ?? ??
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CHLOROMETHYL PHENYL SULFIDE ?? ??:
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Chlorosulfonyl isocyanate
CHLOROMETHYL PHENYL SULFOXIDE
CHLOROMETHYL 4-CHLOROPHENYL SULFIDE
CHLOROMETHYL P-TOLYL SULFIDE
PHENYL CHLOROTHIOFORMATE
CHLOROMETHYL PHENYL SULFONE
CHLOROMETHYL PHENYL SULFIDE
P-CHLOROPHENYL TRICHLOROMETHYL SULFIDE
PHENYL CHLORODITHIOFORMATE
2-CHLORO-BENZO[E][1,3]THIAZIN-4-ONE
1-chloro-4-[(chloromethyl)sulphonyl]benzene
1-[(CHLOROMETHYL)SULFONYL]NAPHTHALENE
P-TOLUENESULFONYLMETHYL CHLORIDE
1-BENZYL-3-CHLORO-3-[(4-CHLOROPHENYL)SULFANYL]DIHYDRO-1H-PYRROLE-2,5-DIONE
3,5-BIS(TRIFLUOROMETHYL)PHENYL CHLOROMETHYL SULFONE
Thiazolo[4,5-h]isoquinoline, 2-chloro- (9CI)