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Bis(trimethylsilyl)methane

Bis(trimethylsilyl)methane ??? ???
?? ??:
2117-28-4
???:
Bis(trimethylsilyl)methane
???(??):
DK210;Di(trimethylsilyl)methane;BIS(TRIMETHYLSILYL)METHANE;di(trimethylsilicon)methane;methylenebis[trimethyl-silan;METHYLENEBIS(TRIMETHYLSILANE);bis(trimethylsilanyl)-methane;Bis(trimethylsilyl)methane,97%;Bis(trimethylsilyl)methane >silane,methylenebis[trimethyl]-
CBNumber:
CB5776849
???:
C7H20Si2
??? ??:
160.4
MOL ??:
2117-28-4.mol

Bis(trimethylsilyl)methane ??

???
-71 °C (lit.)
?? ?
133-134 °C (lit.)
??
0.751 g/mL at 25 °C (lit.)
???
n20/D 1.417(lit.)
???
55 °F
??? ??
??
Specific Gravity
0.752
??
???
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
BRN
1734530
InChI
1S/C7H20Si2/c1-8(2,3)7-9(4,5)6/h7H2,1-6H3
InChIKey
GYIODRUWWNNGPI-UHFFFAOYSA-N
SMILES
C[Si](C)(C)C[Si](C)(C)C
CAS ??????
2117-28-4(CAS DataBase Reference)
NIST
Silane, methylenebis[trimethyl-(2117-28-4)
EPA
Silane, methylenebis[trimethyl- (2117-28-4)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xi
?? ???? ?? 11-36/37/38
????? 9-16-29-33-36/37/39
????(UN No.) UN 1993 3/PG 2
WGK ?? 3
TSCA TSCA listed
?? ?? 3
???? II
HS ?? 29319000
???? ??? 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P210 ?·???·??·????? ????? - ?? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
3
2 0

Bis(trimethylsilyl)methane MSDS


Bis(trimethylsilyl)methane

Bis(trimethylsilyl)methane C??? ??, ??, ??

??? ??

clear colorless liquid

??

Bis(trimethylsilyl)methane is a precursor of (Me3Si)2CHLi and Me3SiCH2Li, which are useful in Peterson alkenation reactions[1].

??

Bis(trimethylsilyl)methane can be stored in a glass bottle.

?? ??

1. (a) Grōbel, B.-T.; Seebach, D. AG(E) 1974, 13, 83. (b) Cook, M. A.; Eaborn, C.; Jukes, A. E.; Walton, D. R. M. JOM, 1970, 24, 52.

Bis(trimethylsilyl)methane ?? ?? ? ???

???

?? ??


Bis(trimethylsilyl)methane ?? ??

???( 135)?? ??
??? ?? ??? ?? ?? ? ??
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Bis(trimethylsilyl)methane ?? ??:

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