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134098-61-6
???:
???????
???(??):
??-??(E)-??-(1,3-????-5-??????-4-????;????????(???????);???????;(E)-4-[[[[(1,3-????-5-???-1H-???-4-?)???]???]??]??]???, 1,1-?????? ???;4-[[[(E)-[(1,3-????-5-???-1H-???-4-?)???]???]??]??]???, 1,1-?????? ???;tert-?? (E)-a-(1,3-????-5-??????-4-?????????)-p-?????
???:
tert-Butyl 4-[[[(E)-[(1,3-Dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]benzoate
???(??):
Fenpyroximate;(E)-Fenpyroximate;(E)-Fenpyroximate Solution in Methanol, 100μg/mL;uate;ORTUS;KIRON;nni850;PAMANRIN;DANITRON;DANITORON
CBNumber:
CB6156260
???:
C24H27N3O4
??? ??:
421.49
MOL ??:
134098-61-6.mol
MSDS ??:
SDS

??????? ??

???
101.1-102.4°
?? ?
546.2±60.0 °C(Predicted)
??
1.25g/cm3
?? ??
Store at -20°C
???
?? ???
???
Chloroform: Slightly soluble,Methanol: Slightly soluble
??? ??
powder to crystal
?? ?? (pKa)
1.58±0.10(Predicted)
??
White to Light yellow to Light orange
Henry's Law Constant
4.6×100 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
???
???
?? ??
agriculture
environmental
InChI
1S/C24H27N3O4/c1-17-21(22(27(5)26-17)30-20-9-7-6-8-10-20)15-25-29-16-18-11-13-19(14-12-18)23(28)31-24(2,3)4/h6-15H,16H2,1-5H3/b25-15+
InChIKey
YYJNOYZRYGDPNH-MFKUBSTISA-N
SMILES
Cc1nn(C)c(Oc2ccccc2)c1\C=N\OCc3ccc(cc3)C(=O)OC(C)(C)C
LogP
6.443 (est)
CAS ??????
134098-61-6(CAS DataBase Reference)
EPA
Fenpyroximate (134098-61-6)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????(UN No.) UN3082 (liquid)
WGK ?? WGK 3
HS ?? 29331990
???? ??? 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 2 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1B
?? ?? ??? 134098-61-6(Hazardous Substances Data)
?? LD50 in male, female rats (mg/kg): 480, 245 orally; >2000, >2000 dermally; LC50 (48hr) in carp: 6.1 mg/l; LC50 (3hr) in daphnia pulex: 85 mg/l (Konno)
???? ?? KE-05-0263
?????? ??? 97-1-342;06-4-50
?? ? ???? ????: ????; ???(??)????: ??????? ? ?? 25% ?? ??? ???
????(GHS): Skull and Crossbones (GHS06)Environment (GHS09)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H301 ??? ??? ?? ?? ?? - ?? ?? 3 ?? P264, P270, P301+P310, P321, P330,P405, P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H330 ???? ???? ?? ?? ?? ?? ?? 1, 2 ?? P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P272 ??? ??? ??? ??? ???? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P284 ?? ???? ?????.
P301+P310 ???? ?? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P310 ?? ????(??)? ??? ????. ???? ?? ????(??)? ??? ????.
P320 ??? (…) ??? ???.
P321 (…) ??? ???.
P330 ?? ?????.
P333+P313 ????? ?? ??? ???? ???? ??·??? ????.
P363 ?? ??? ??? ??? ?????.
P391 ???? ????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
0
4 0

??????? C??? ??, ??, ??

??

Acaricide.

???

Acaricide, Miticide, Insecticide: Used to control spider mites in greenhouses.

???

AKARI®; HOE® 555-02A; NNI®-850; SEQUEL®

?? ?? ??

When fenpyroximate is administered orally to rats, radiocarbons from 14C-fenpyroximate are rapidly and almost completely excreted in the urine and feces within 72 h, and fenyproximate seems to be metabolized via oxidation of the tert-butyl group and methyl group at the 3-position in the pyrazole ring, p- hydroxylation in the phenoxy moiety, N-demethylation, hydrolysis of the tert-butyl ester, cleavage of the oxime ether bond, and/or E/Z isomerization. In soils, 12 degradation products are identified, and in sterilized soils the degradation of fenpyroximate and CO2, evolution are negligible. Fenpyroximate degrades through hydrolysis of tert-butyl ester, isomerization or cleavage of the oxime ether, N-demethylation, oxidation of the methyl group at the 3-position on the pyrazole ring, and hydroxylation of the phenoxy ring, and is finally mineralized to CO2 and/or bound to soil organic matter.

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???( 196)?? ??
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