1-Adamantanecarbonyl chloride
1-Adamantanecarbonyl chloride ??
???
49-51 °C(lit.)
?? ?
135-136 °C10 mm Hg(lit.)
??
1.0490 (rough estimate)
???
1.5364 (estimate)
???
>230 °F
?? ??
Inert atmosphere,2-8°C
???
???? ???
??? ??
??? ??
??
???? ?? ??
???
??? ? ??
??
Moisture Sensitive
BRN
389960
InChI
1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11-
InChIKey
MIBQYWIOHFTKHD-KJZNFTALSA-N
SMILES
ClC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2
CAS ??????
2094-72-6(CAS DataBase Reference)
NIST
1-Adamantanecarboxlic acid chloride(2094-72-6)
??
?? ? ?? ??
?? ? ???? ?? (GHS)
??? ??
C
?? ???? ??
14-34-37
?????
26-36/37/39-45-24/25
????(UN No.)
UN 3261 8/PG 2
WGK ??
3
F ??????
10-21
?? ??
8
????
III
HS ??
29162090
???? ???
8A - Combustible corrosive hazardous materials
Hazard Classifications
Skin Corr. 1B
????(GHS):
?? ?:
Danger
??·?? ??:
??
??·?? ??
?? ??
??
?? ?
?? ??
P- ??
H314 ??? ?? ??? ?? ??? ???
????? ?? ?????
?? 1A, B, C
??
P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P330+P331 ???? ?? ?????. ??? ?? ?? ???.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1-Adamantanecarbonyl chloride C??? ??, ??, ??
??? ??
White to almost white crystalline solid
??
1-Adamantanecarbonyl chloride was used in the preparation of efficient amine-modified oligodeoxynucleotides for fabrication of DNA microarrays.
?? ??
1-Adamantanecarbonyl chloride on reaction with triethylammonium isopropylphosphite forms mixed anhydride, an efficient capping reagent for the hydrogen-phosphonate DNA synthesis. It is a good substrate for Friedel–Crafts acylation of anisole in the presence of indium metal.
1-Adamantanecarbonyl chloride ?? ?? ? ???
???
?? ??
1-Adamantanecarbonyl chloride ?? ??
???( 241)?? ??
Americas 1
Belgium 1
China 182
Europe 2
France 1
Germany 5
India 4
Japan 6
Slovakia 1
Switzerland 2
Ukraine 1
United Kingdom 14
United States 21
Global 241
1-Adamantanecarbonyl chloride ?? ??:
